Details
| Translated title of the contribution | Dihydroacepentalendiid, das Dianion des Acepentalens |
|---|---|
| Original language | English |
| Pages (from-to) | 719-720 |
| Number of pages | 2 |
| Journal | Angewandte Chemie International Edition in English |
| Volume | 25 |
| Issue number | 8 |
| Publication status | Published - Aug 1986 |
| Externally published | Yes |
Abstract
The long‐sought dianion of the still unknown acepentalene 2 is formed surprisingly easily upon reaction of triquinacene 1 with n‐butylithium and potassium tert‐amyl alkoxide in hexane at room temperature. 22⊖ reacts with chlorotrimethylsilane to give a mixture of 1,4‐ and 1,10‐bis(trimethylsilyl)dihydroacepentalenes. (Figure Presented.)
ASJC Scopus subject areas
- Chemical Engineering(all)
- Catalysis
- Chemistry(all)
- General Chemistry
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In: Angewandte Chemie International Edition in English, Vol. 25, No. 8, 08.1986, p. 719-720.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Dihydroacepentalenediide, the Dianion of Acepentalene
AU - Lendvai, Thomas
AU - Friedl, Thomas
AU - Butenschön, Holger
AU - Clark, Timothy
AU - de Meijere, Armin
PY - 1986/8
Y1 - 1986/8
N2 - The long‐sought dianion of the still unknown acepentalene 2 is formed surprisingly easily upon reaction of triquinacene 1 with n‐butylithium and potassium tert‐amyl alkoxide in hexane at room temperature. 22⊖ reacts with chlorotrimethylsilane to give a mixture of 1,4‐ and 1,10‐bis(trimethylsilyl)dihydroacepentalenes. (Figure Presented.)
AB - The long‐sought dianion of the still unknown acepentalene 2 is formed surprisingly easily upon reaction of triquinacene 1 with n‐butylithium and potassium tert‐amyl alkoxide in hexane at room temperature. 22⊖ reacts with chlorotrimethylsilane to give a mixture of 1,4‐ and 1,10‐bis(trimethylsilyl)dihydroacepentalenes. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=84985627323&partnerID=8YFLogxK
U2 - 10.1002/anie.198607191
DO - 10.1002/anie.198607191
M3 - Article
AN - SCOPUS:84985627323
VL - 25
SP - 719
EP - 720
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
SN - 0570-0833
IS - 8
ER -