Diffusive Spreading of Molecules in Nanoporous Materials

Research output: Chapter in book/report/conference proceedingContribution to book/anthologyResearchpeer review

Authors

  • Christian Chmelik
  • Jürgen Caro
  • Dieter Freude
  • Jürgen Haase
  • Rustem Valiullin
  • Jörg Kärger

External Research Organisations

  • Leipzig University
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Details

Original languageEnglish
Title of host publicationDiffusive Spreading in Nature, Technology and Society
EditorsArmin Bunde, Jürgen Caro, Jörg Kärger, Christian Chmelik, Gero Vogl
PublisherSpringer International Publishing AG
Pages179-214
Number of pages36
Edition2
ISBN (electronic)9783031059469
ISBN (print)9783031059452, 9783031059483
Publication statusPublished - 2023

Abstract

Nanoporous materials are employed in numerous technologies of matter upgrading by mass separation and conversion (heterogeneous catalysis). The chapter deals with the measurement of guest diffusion in such materials and, thus, with the determination of a key parameter for performance enhancement of these technologies. The introduction of two “microscopic” measuring techniques (PFG NMR and microimaging), which are the focus of this chapter, gave rise to a paradigm shift in our understanding of mass transfer in such materials. Nanoporous host–guest systems are, moreover, shown to serve as an ideal model system for investigating spreading phenomena quite in general. Ample options of investigation range from the comparison of equilibrium and non-equilibrium phenomena towards the investigation of conversions of both the spreading individuals and their environment.

Cite this

Diffusive Spreading of Molecules in Nanoporous Materials. / Chmelik, Christian; Caro, Jürgen; Freude, Dieter et al.
Diffusive Spreading in Nature, Technology and Society. ed. / Armin Bunde; Jürgen Caro; Jörg Kärger; Christian Chmelik; Gero Vogl. 2. ed. Springer International Publishing AG, 2023. p. 179-214.

Research output: Chapter in book/report/conference proceedingContribution to book/anthologyResearchpeer review

Chmelik, C, Caro, J, Freude, D, Haase, J, Valiullin, R & Kärger, J 2023, Diffusive Spreading of Molecules in Nanoporous Materials. in A Bunde, J Caro, J Kärger, C Chmelik & G Vogl (eds), Diffusive Spreading in Nature, Technology and Society. 2 edn, Springer International Publishing AG, pp. 179-214. https://doi.org/10.1007/978-3-031-05946-9_10
Chmelik, C., Caro, J., Freude, D., Haase, J., Valiullin, R., & Kärger, J. (2023). Diffusive Spreading of Molecules in Nanoporous Materials. In A. Bunde, J. Caro, J. Kärger, C. Chmelik, & G. Vogl (Eds.), Diffusive Spreading in Nature, Technology and Society (2 ed., pp. 179-214). Springer International Publishing AG. https://doi.org/10.1007/978-3-031-05946-9_10
Chmelik C, Caro J, Freude D, Haase J, Valiullin R, Kärger J. Diffusive Spreading of Molecules in Nanoporous Materials. In Bunde A, Caro J, Kärger J, Chmelik C, Vogl G, editors, Diffusive Spreading in Nature, Technology and Society. 2 ed. Springer International Publishing AG. 2023. p. 179-214 Epub 2023 May 9. doi: 10.1007/978-3-031-05946-9_10
Chmelik, Christian ; Caro, Jürgen ; Freude, Dieter et al. / Diffusive Spreading of Molecules in Nanoporous Materials. Diffusive Spreading in Nature, Technology and Society. editor / Armin Bunde ; Jürgen Caro ; Jörg Kärger ; Christian Chmelik ; Gero Vogl. 2. ed. Springer International Publishing AG, 2023. pp. 179-214
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