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Diffusive exchange of trace elements between alkaline melts: Implications for element fractionation and timescale estimations during magma mixing

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Authors

  • Diego González-Garcia
  • Maurizio Petrelli
  • Harald Behrens
  • Francesco Vetere
  • Lennart A. Fischer

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  • University of Perugia
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Original languageEnglish
Pages (from-to)95-114
Number of pages20
JournalGeochimica et Cosmochimica Acta
Volume233
Early online date29 May 2018
Publication statusPublished - 15 Jul 2018

Abstract

The diffusive exchange of 30 trace elements (Cs, Rb, Ba, Sr, Co, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ta, V, Cr, Pb, Th, U, Zr, Hf, Sn and Nb) during the interaction of natural mafic and silicic alkaline melts was experimentally studied at conditions relevant to shallow magmatic systems. In detail, a set of 12 diffusion couple experiments have been performed between natural shoshonitic and rhyolitic melts from the Vulcano Island (Aeolian archipelago, Italy) at a temperature of 1200 °C, pressures from 50 to 500 MPa, and water contents ranging from nominally dry to ca. 2 wt.%. Concentration-distance profiles, measured by Laser Ablation ICP-MS, highlight different behaviours, and trace elements were divided into two groups: (1) elements with normal diffusion profiles (13 elements, mainly low field strength and transition elements), and (2) elements showing uphill diffusion (17 elements including Y, Zr, Nb, Pb and rare earth elements, except Eu). For the elements showing normal diffusion profiles, chemical diffusion coefficients were estimated using a concentration-dependent evaluation method, and values are given at four intermediate compositions (SiO2 equal to 58, 62, 66 and 70 wt.%, respectively). A general coupling of diffusion coefficients to silica diffusivity is observed, and variations in systematics are observed between mafic and silicic compositions. Results show that water plays a decisive role on diffusive rates in the studied conditions, producing an enhancement between 0.4 and 0.7 log units per 1 wt.% of added H2O. Particularly notable is the behaviour of the trivalent-only REEs (La to Nd and Gd to Lu), with strong uphill diffusion minima, diminishing from light to heavy REEs. Modelling of REE profiles by a modified effective binary diffusion model indicates that activity gradients induced by the SiO2 concentration contrast are responsible for their development, inducing a transient partitioning of REEs towards the shoshonitic melt. These results indicate that diffusive fractionation of trace elements is possible during magma mixing events, especially in the more silicic melts, and that the presence of water in such events can lead to enhanced chemical diffusive mixing efficiency, affecting also the estimation of mixing to eruption timescales.

Keywords

    Diffusion, Magma mixing, Rhyolite, Shoshonite, Trace elements

ASJC Scopus subject areas

Cite this

Diffusive exchange of trace elements between alkaline melts: Implications for element fractionation and timescale estimations during magma mixing. / González-Garcia, Diego; Petrelli, Maurizio; Behrens, Harald et al.
In: Geochimica et Cosmochimica Acta, Vol. 233, 15.07.2018, p. 95-114.

Research output: Contribution to journalArticleResearchpeer review

González-Garcia D, Petrelli M, Behrens H, Vetere F, Fischer LA, Morgavi D et al. Diffusive exchange of trace elements between alkaline melts: Implications for element fractionation and timescale estimations during magma mixing. Geochimica et Cosmochimica Acta. 2018 Jul 15;233:95-114. Epub 2018 May 29. doi: 10.1016/j.gca.2018.05.003
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title = "Diffusive exchange of trace elements between alkaline melts: Implications for element fractionation and timescale estimations during magma mixing",
abstract = "The diffusive exchange of 30 trace elements (Cs, Rb, Ba, Sr, Co, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ta, V, Cr, Pb, Th, U, Zr, Hf, Sn and Nb) during the interaction of natural mafic and silicic alkaline melts was experimentally studied at conditions relevant to shallow magmatic systems. In detail, a set of 12 diffusion couple experiments have been performed between natural shoshonitic and rhyolitic melts from the Vulcano Island (Aeolian archipelago, Italy) at a temperature of 1200 °C, pressures from 50 to 500 MPa, and water contents ranging from nominally dry to ca. 2 wt.%. Concentration-distance profiles, measured by Laser Ablation ICP-MS, highlight different behaviours, and trace elements were divided into two groups: (1) elements with normal diffusion profiles (13 elements, mainly low field strength and transition elements), and (2) elements showing uphill diffusion (17 elements including Y, Zr, Nb, Pb and rare earth elements, except Eu). For the elements showing normal diffusion profiles, chemical diffusion coefficients were estimated using a concentration-dependent evaluation method, and values are given at four intermediate compositions (SiO2 equal to 58, 62, 66 and 70 wt.%, respectively). A general coupling of diffusion coefficients to silica diffusivity is observed, and variations in systematics are observed between mafic and silicic compositions. Results show that water plays a decisive role on diffusive rates in the studied conditions, producing an enhancement between 0.4 and 0.7 log units per 1 wt.% of added H2O. Particularly notable is the behaviour of the trivalent-only REEs (La to Nd and Gd to Lu), with strong uphill diffusion minima, diminishing from light to heavy REEs. Modelling of REE profiles by a modified effective binary diffusion model indicates that activity gradients induced by the SiO2 concentration contrast are responsible for their development, inducing a transient partitioning of REEs towards the shoshonitic melt. These results indicate that diffusive fractionation of trace elements is possible during magma mixing events, especially in the more silicic melts, and that the presence of water in such events can lead to enhanced chemical diffusive mixing efficiency, affecting also the estimation of mixing to eruption timescales.",
keywords = "Diffusion, Magma mixing, Rhyolite, Shoshonite, Trace elements",
author = "Diego Gonz{\'a}lez-Garcia and Maurizio Petrelli and Harald Behrens and Francesco Vetere and Fischer, {Lennart A.} and Daniele Morgavi and Diego Perugini",
note = "Funding Information: This research was funded by the European Research Council Consolidator Grant ERC-2013-COG No. 612776 (CHRONOS project) to D. Perugini and by the MIUR-DAAD joint mobility Project No. 57262582 to F. Vetere and H. Behrens. We wish to acknowledge the assistance received from R. Balzer during experiment run and J. Feige for the careful preparation of experiment sections, both of them at the Insitut f{\"u}r Mineralogie, Leibniz Universt{\"a}t Hannover; and also A. Zezza for completing the first diffusion experiment. Constructive comments by E.B. Watson, Y. Liang and an anonymous reviewer significantly improved the final version of this manuscript. ",
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Download

TY - JOUR

T1 - Diffusive exchange of trace elements between alkaline melts

T2 - Implications for element fractionation and timescale estimations during magma mixing

AU - González-Garcia, Diego

AU - Petrelli, Maurizio

AU - Behrens, Harald

AU - Vetere, Francesco

AU - Fischer, Lennart A.

AU - Morgavi, Daniele

AU - Perugini, Diego

N1 - Funding Information: This research was funded by the European Research Council Consolidator Grant ERC-2013-COG No. 612776 (CHRONOS project) to D. Perugini and by the MIUR-DAAD joint mobility Project No. 57262582 to F. Vetere and H. Behrens. We wish to acknowledge the assistance received from R. Balzer during experiment run and J. Feige for the careful preparation of experiment sections, both of them at the Insitut für Mineralogie, Leibniz Universtät Hannover; and also A. Zezza for completing the first diffusion experiment. Constructive comments by E.B. Watson, Y. Liang and an anonymous reviewer significantly improved the final version of this manuscript.

PY - 2018/7/15

Y1 - 2018/7/15

N2 - The diffusive exchange of 30 trace elements (Cs, Rb, Ba, Sr, Co, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ta, V, Cr, Pb, Th, U, Zr, Hf, Sn and Nb) during the interaction of natural mafic and silicic alkaline melts was experimentally studied at conditions relevant to shallow magmatic systems. In detail, a set of 12 diffusion couple experiments have been performed between natural shoshonitic and rhyolitic melts from the Vulcano Island (Aeolian archipelago, Italy) at a temperature of 1200 °C, pressures from 50 to 500 MPa, and water contents ranging from nominally dry to ca. 2 wt.%. Concentration-distance profiles, measured by Laser Ablation ICP-MS, highlight different behaviours, and trace elements were divided into two groups: (1) elements with normal diffusion profiles (13 elements, mainly low field strength and transition elements), and (2) elements showing uphill diffusion (17 elements including Y, Zr, Nb, Pb and rare earth elements, except Eu). For the elements showing normal diffusion profiles, chemical diffusion coefficients were estimated using a concentration-dependent evaluation method, and values are given at four intermediate compositions (SiO2 equal to 58, 62, 66 and 70 wt.%, respectively). A general coupling of diffusion coefficients to silica diffusivity is observed, and variations in systematics are observed between mafic and silicic compositions. Results show that water plays a decisive role on diffusive rates in the studied conditions, producing an enhancement between 0.4 and 0.7 log units per 1 wt.% of added H2O. Particularly notable is the behaviour of the trivalent-only REEs (La to Nd and Gd to Lu), with strong uphill diffusion minima, diminishing from light to heavy REEs. Modelling of REE profiles by a modified effective binary diffusion model indicates that activity gradients induced by the SiO2 concentration contrast are responsible for their development, inducing a transient partitioning of REEs towards the shoshonitic melt. These results indicate that diffusive fractionation of trace elements is possible during magma mixing events, especially in the more silicic melts, and that the presence of water in such events can lead to enhanced chemical diffusive mixing efficiency, affecting also the estimation of mixing to eruption timescales.

AB - The diffusive exchange of 30 trace elements (Cs, Rb, Ba, Sr, Co, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ta, V, Cr, Pb, Th, U, Zr, Hf, Sn and Nb) during the interaction of natural mafic and silicic alkaline melts was experimentally studied at conditions relevant to shallow magmatic systems. In detail, a set of 12 diffusion couple experiments have been performed between natural shoshonitic and rhyolitic melts from the Vulcano Island (Aeolian archipelago, Italy) at a temperature of 1200 °C, pressures from 50 to 500 MPa, and water contents ranging from nominally dry to ca. 2 wt.%. Concentration-distance profiles, measured by Laser Ablation ICP-MS, highlight different behaviours, and trace elements were divided into two groups: (1) elements with normal diffusion profiles (13 elements, mainly low field strength and transition elements), and (2) elements showing uphill diffusion (17 elements including Y, Zr, Nb, Pb and rare earth elements, except Eu). For the elements showing normal diffusion profiles, chemical diffusion coefficients were estimated using a concentration-dependent evaluation method, and values are given at four intermediate compositions (SiO2 equal to 58, 62, 66 and 70 wt.%, respectively). A general coupling of diffusion coefficients to silica diffusivity is observed, and variations in systematics are observed between mafic and silicic compositions. Results show that water plays a decisive role on diffusive rates in the studied conditions, producing an enhancement between 0.4 and 0.7 log units per 1 wt.% of added H2O. Particularly notable is the behaviour of the trivalent-only REEs (La to Nd and Gd to Lu), with strong uphill diffusion minima, diminishing from light to heavy REEs. Modelling of REE profiles by a modified effective binary diffusion model indicates that activity gradients induced by the SiO2 concentration contrast are responsible for their development, inducing a transient partitioning of REEs towards the shoshonitic melt. These results indicate that diffusive fractionation of trace elements is possible during magma mixing events, especially in the more silicic melts, and that the presence of water in such events can lead to enhanced chemical diffusive mixing efficiency, affecting also the estimation of mixing to eruption timescales.

KW - Diffusion

KW - Magma mixing

KW - Rhyolite

KW - Shoshonite

KW - Trace elements

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JO - Geochimica et Cosmochimica Acta

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