Depths of partial crystallization of H2O-bearing MORB: Phase equilibria simulations of basalts at the MAR near Ascension Island (7-11°S)

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  • Aarhus University
  • GEOMAR Helmholtz Centre for Ocean Research Kiel
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Original languageEnglish
Pages (from-to)25-45
Number of pages21
JournalJournal of Petrology
Volume49
Issue number1
Publication statusPublished - 27 Nov 2007

Abstract

Phase equilibria simulations were performed on naturally quenched basaltic glasses to determine crystallization conditions prior to eruption of magmas at the Mid-Atlantic Ridge (MAR) east of Ascension Island (7-11°S). The results indicate that mid-ocean ridge basalt (MORB) magmas beneath different segments of the MAR have crystallized over a wide range of pressures (100-900 MPa). However, each segment seems to have a specific crystallization history. Nearly isobaric crystallization conditions (100-300 MPa) were obtained for the geochemically enriched MORB magmas of the central segments, whereas normal (N)-MORB magmas of the bounding segments are characterized by polybaric crystallization conditions (200-900 MPa). In addition, our results demonstrate close to anhydrous crystallization conditions of N-MORBs, whereas geochemically enriched MORBs were successfully modeled in the presence of 0.4-1 wt% H2O in the parental melts. These estimates are in agreement with direct (Fourier transform IR) measurements of H2O abundances in basaltic glasses and melt inclusions for selected samples. Water contents determined in the parental melts are in the range 0.04-0.09 and 0.30-0.55 wt% H2O for depleted and enriched MORBs, respectively. Our results are in general agreement (within ±200 MPa) with previous approaches used to evaluate pressure estimates in MORB. However, the determination of pre-eruptive conditions of MORBs, including temperature and water content in addition to pressure, requires the improvement of magma crystallization models to simulate liquid lines of descent in the presence of small amounts of water.

Keywords

    Cotectic crystallization, Depth of crystallization, Mid-Atlantic Ridge, MORB, Phase equilibria calculations, Polybaric fractionation, Pressure estimates, Water abundances

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Depths of partial crystallization of H2O-bearing MORB: Phase equilibria simulations of basalts at the MAR near Ascension Island (7-11°S). / Almeev, Renat; Holtz, François; Koepke, Jürgen et al.
In: Journal of Petrology, Vol. 49, No. 1, 27.11.2007, p. 25-45.

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title = "Depths of partial crystallization of H2O-bearing MORB: Phase equilibria simulations of basalts at the MAR near Ascension Island (7-11°S)",
abstract = "Phase equilibria simulations were performed on naturally quenched basaltic glasses to determine crystallization conditions prior to eruption of magmas at the Mid-Atlantic Ridge (MAR) east of Ascension Island (7-11°S). The results indicate that mid-ocean ridge basalt (MORB) magmas beneath different segments of the MAR have crystallized over a wide range of pressures (100-900 MPa). However, each segment seems to have a specific crystallization history. Nearly isobaric crystallization conditions (100-300 MPa) were obtained for the geochemically enriched MORB magmas of the central segments, whereas normal (N)-MORB magmas of the bounding segments are characterized by polybaric crystallization conditions (200-900 MPa). In addition, our results demonstrate close to anhydrous crystallization conditions of N-MORBs, whereas geochemically enriched MORBs were successfully modeled in the presence of 0.4-1 wt% H2O in the parental melts. These estimates are in agreement with direct (Fourier transform IR) measurements of H2O abundances in basaltic glasses and melt inclusions for selected samples. Water contents determined in the parental melts are in the range 0.04-0.09 and 0.30-0.55 wt% H2O for depleted and enriched MORBs, respectively. Our results are in general agreement (within ±200 MPa) with previous approaches used to evaluate pressure estimates in MORB. However, the determination of pre-eruptive conditions of MORBs, including temperature and water content in addition to pressure, requires the improvement of magma crystallization models to simulate liquid lines of descent in the presence of small amounts of water.",
keywords = "Cotectic crystallization, Depth of crystallization, Mid-Atlantic Ridge, MORB, Phase equilibria calculations, Polybaric fractionation, Pressure estimates, Water abundances",
author = "Renat Almeev and Fran{\c c}ois Holtz and J{\"u}rgen Koepke and Karsten Haase and Colin Devey",
note = "Funding Information: This is publication 14 of the priority program SPP1144 {\textquoteleft}From Mantle to Ocean: Energy-, Material-and Life-cycles at Spreading Axes{\textquoteright} of the German Science Foundation (DFG) (Project Ho1337/10). We thank Alexei Ariskin and Jun-Ichi Kimura for helpful reviews of an earlier draft. The authors wish to thank Othmar Mu« ntener and three anonymous reviewers for their suggestions, which allowed us to improve the clarity and quality of the paper considerably. The authors acknowledge Wendy Bohrson for her editorial comments and efforts. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.",
year = "2007",
month = nov,
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doi = "10.1093/petrology/egm068",
language = "English",
volume = "49",
pages = "25--45",
journal = "Journal of Petrology",
issn = "0022-3530",
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TY - JOUR

T1 - Depths of partial crystallization of H2O-bearing MORB

T2 - Phase equilibria simulations of basalts at the MAR near Ascension Island (7-11°S)

AU - Almeev, Renat

AU - Holtz, François

AU - Koepke, Jürgen

AU - Haase, Karsten

AU - Devey, Colin

N1 - Funding Information: This is publication 14 of the priority program SPP1144 ‘From Mantle to Ocean: Energy-, Material-and Life-cycles at Spreading Axes’ of the German Science Foundation (DFG) (Project Ho1337/10). We thank Alexei Ariskin and Jun-Ichi Kimura for helpful reviews of an earlier draft. The authors wish to thank Othmar Mu« ntener and three anonymous reviewers for their suggestions, which allowed us to improve the clarity and quality of the paper considerably. The authors acknowledge Wendy Bohrson for her editorial comments and efforts. Copyright: Copyright 2008 Elsevier B.V., All rights reserved.

PY - 2007/11/27

Y1 - 2007/11/27

N2 - Phase equilibria simulations were performed on naturally quenched basaltic glasses to determine crystallization conditions prior to eruption of magmas at the Mid-Atlantic Ridge (MAR) east of Ascension Island (7-11°S). The results indicate that mid-ocean ridge basalt (MORB) magmas beneath different segments of the MAR have crystallized over a wide range of pressures (100-900 MPa). However, each segment seems to have a specific crystallization history. Nearly isobaric crystallization conditions (100-300 MPa) were obtained for the geochemically enriched MORB magmas of the central segments, whereas normal (N)-MORB magmas of the bounding segments are characterized by polybaric crystallization conditions (200-900 MPa). In addition, our results demonstrate close to anhydrous crystallization conditions of N-MORBs, whereas geochemically enriched MORBs were successfully modeled in the presence of 0.4-1 wt% H2O in the parental melts. These estimates are in agreement with direct (Fourier transform IR) measurements of H2O abundances in basaltic glasses and melt inclusions for selected samples. Water contents determined in the parental melts are in the range 0.04-0.09 and 0.30-0.55 wt% H2O for depleted and enriched MORBs, respectively. Our results are in general agreement (within ±200 MPa) with previous approaches used to evaluate pressure estimates in MORB. However, the determination of pre-eruptive conditions of MORBs, including temperature and water content in addition to pressure, requires the improvement of magma crystallization models to simulate liquid lines of descent in the presence of small amounts of water.

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KW - Depth of crystallization

KW - Mid-Atlantic Ridge

KW - MORB

KW - Phase equilibria calculations

KW - Polybaric fractionation

KW - Pressure estimates

KW - Water abundances

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