Details
| Original language | English |
|---|---|
| Pages (from-to) | 95-100 |
| Number of pages | 6 |
| Journal | Inorganica chimica acta |
| Volume | 287 |
| Issue number | 1 |
| Publication status | Published - 2 Apr 1999 |
Abstract
Two dinuclear iron complexes, bridged via cyano groups, containing units of [Fe(phen)2(CN)2]n (n=0 or +1) and a chelating ligand, the nitrilotriacetic acid anion, have been synthesised. These compounds, containing iron atoms in different and/or the same oxidation states [Fe(II)/Fe(III) (1); Fe(III)/Fe(III) (2)] were characterised by elemental analyses, IR and UV spectra, TGA and DSC thermograms. Mössbauer spectra and magnetic susceptibility of complex 1 were investigated and discussed.
Keywords
- Cyano-bridged complexes, Dinuclear complexes, Iron complexes
ASJC Scopus subject areas
- Chemistry(all)
- Physical and Theoretical Chemistry
- Chemistry(all)
- Inorganic Chemistry
- Materials Science(all)
- Materials Chemistry
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In: Inorganica chimica acta, Vol. 287, No. 1, 02.04.1999, p. 95-100.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Cyano-bridged dinuclear iron complexes in different oxidation states
AU - Gou, Shaohua
AU - Renz, Franz
AU - Fukuda, Yutaka
AU - Linert, Wolfgang
N1 - Funding Information: Acknowledgment for financial support is due to the Fonds zur Förderung der Wissenschaflichen Forschung in Österreich (project 11218), and to the Training and Mobility of Researchers Network (TMR) project Thermal and Optical Spin State Switching (TOSS) supported by the European Community under the Contract number ERB-FMRX-CT98-0199. Grants in aid for Scientific Research from the Ministry of Education, Science and Culture in Japan (nos. 07454173, 08220222, and 08554026) are thankfully acknowledged. S.G. is grateful to the ÖAD (Österreichischer Akademischer Austauschdienst) for a research scholarship. We would also like to thank G. Wiesinger of the Institute of Experimental Physics at TU-Wien for his assistance in the measurement of the Mössbauer spectrum and R. Boca (TU-Bratislava, Slovakia) for assistance with the magnetic measurements.
PY - 1999/4/2
Y1 - 1999/4/2
N2 - Two dinuclear iron complexes, bridged via cyano groups, containing units of [Fe(phen)2(CN)2]n (n=0 or +1) and a chelating ligand, the nitrilotriacetic acid anion, have been synthesised. These compounds, containing iron atoms in different and/or the same oxidation states [Fe(II)/Fe(III) (1); Fe(III)/Fe(III) (2)] were characterised by elemental analyses, IR and UV spectra, TGA and DSC thermograms. Mössbauer spectra and magnetic susceptibility of complex 1 were investigated and discussed.
AB - Two dinuclear iron complexes, bridged via cyano groups, containing units of [Fe(phen)2(CN)2]n (n=0 or +1) and a chelating ligand, the nitrilotriacetic acid anion, have been synthesised. These compounds, containing iron atoms in different and/or the same oxidation states [Fe(II)/Fe(III) (1); Fe(III)/Fe(III) (2)] were characterised by elemental analyses, IR and UV spectra, TGA and DSC thermograms. Mössbauer spectra and magnetic susceptibility of complex 1 were investigated and discussed.
KW - Cyano-bridged complexes
KW - Dinuclear complexes
KW - Iron complexes
UR - http://www.scopus.com/inward/record.url?scp=0003037368&partnerID=8YFLogxK
U2 - 10.1016/S0020-1693(99)00003-1
DO - 10.1016/S0020-1693(99)00003-1
M3 - Article
AN - SCOPUS:0003037368
VL - 287
SP - 95
EP - 100
JO - Inorganica chimica acta
JF - Inorganica chimica acta
SN - 0020-1693
IS - 1
ER -