Details
| Original language | English |
|---|---|
| Pages (from-to) | 583-589 |
| Number of pages | 7 |
| Journal | Synthesis |
| Issue number | 4 |
| Publication status | Published - 12 Jan 2007 |
Abstract
Jacobsen's cobalt-salen complex was covalently immobilized on polymer carriers that are part of different technical setups (polymer powder, composite Raschig rings, PASSflow microreactors) and employed for the enantioselective ring opening of terminal epoxides with water and phenols. The polymer-supported catalysts showed good activity and stereoselectivity and could be used repeatedly after a simple reactivation protocol in both batch as well as continuous-flow modes.
Keywords
- Catalysis, Continuous-flow processes, Enantioselective synthesis, Immobilization, Microreactor, Salen
ASJC Scopus subject areas
- Chemical Engineering(all)
- Catalysis
- Chemistry(all)
- Organic Chemistry
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In: Synthesis, No. 4, 12.01.2007, p. 583-589.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Continuous enantioselective kinetic resolution of terminal epoxides using immobilized chiral cobalt-salen complexes
AU - Solodenko, Wladimir
AU - Jas, Gerhard
AU - Kunz, Ulrich
AU - Kirschning, Andreas
PY - 2007/1/12
Y1 - 2007/1/12
N2 - Jacobsen's cobalt-salen complex was covalently immobilized on polymer carriers that are part of different technical setups (polymer powder, composite Raschig rings, PASSflow microreactors) and employed for the enantioselective ring opening of terminal epoxides with water and phenols. The polymer-supported catalysts showed good activity and stereoselectivity and could be used repeatedly after a simple reactivation protocol in both batch as well as continuous-flow modes.
AB - Jacobsen's cobalt-salen complex was covalently immobilized on polymer carriers that are part of different technical setups (polymer powder, composite Raschig rings, PASSflow microreactors) and employed for the enantioselective ring opening of terminal epoxides with water and phenols. The polymer-supported catalysts showed good activity and stereoselectivity and could be used repeatedly after a simple reactivation protocol in both batch as well as continuous-flow modes.
KW - Catalysis
KW - Continuous-flow processes
KW - Enantioselective synthesis
KW - Immobilization
KW - Microreactor
KW - Salen
UR - http://www.scopus.com/inward/record.url?scp=33947528653&partnerID=8YFLogxK
U2 - 10.1055/s-2007-965877
DO - 10.1055/s-2007-965877
M3 - Article
AN - SCOPUS:33947528653
SP - 583
EP - 589
JO - Synthesis
JF - Synthesis
SN - 0039-7881
IS - 4
ER -