Construction of Carbon Frameworks with the Help of Ruthenium Complexes: 1,5‐Cyclooctadiene as a Reagent in Transition Metal Catalyzed Reactions

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Translated title of the contributionAufbau von Kohlenstoffgerüsten mit Hilfe von Rutheniumkomplexen: 1,5-Cyclooctadien als Reagens in übergangsmetallkatalysierten Reaktionen
Original languageEnglish
Pages (from-to)636-638
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume33
Issue number6
Publication statusPublished - 31 Mar 1994

Abstract

Hitherto 1,5‐cyclooctadiene (COD) was used almost exclusively as a ligand in transition metal complexes; however, Trost et al. have recently found a ruthenium‐catalyzed reaction, in which COD functions as bis‐homodiene and undergoes a cyclization with alkynes to form derivatives of the tricyclo‐[4.2.2.02, 5]dec‐7‐ene (1) in good yields. Thus, COD may now be considered as a synthetic building block. (Figure Presented.)

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@article{97306f46fbaf49ecaeb761d714de696d,
title = "Construction of Carbon Frameworks with the Help of Ruthenium Complexes: 1,5‐Cyclooctadiene as a Reagent in Transition Metal Catalyzed Reactions",
abstract = "Hitherto 1,5‐cyclooctadiene (COD) was used almost exclusively as a ligand in transition metal complexes; however, Trost et al. have recently found a ruthenium‐catalyzed reaction, in which COD functions as bis‐homodiene and undergoes a cyclization with alkynes to form derivatives of the tricyclo‐[4.2.2.02, 5]dec‐7‐ene (1) in good yields. Thus, COD may now be considered as a synthetic building block. (Figure Presented.)",
author = "Holger Butensch{\"o}n",
year = "1994",
month = mar,
day = "31",
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language = "English",
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pages = "636--638",
journal = "Angewandte Chemie International Edition in English",
issn = "0570-0833",
publisher = "John Wiley and Sons Ltd",
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T2 - 1,5‐Cyclooctadiene as a Reagent in Transition Metal Catalyzed Reactions

AU - Butenschön, Holger

PY - 1994/3/31

Y1 - 1994/3/31

N2 - Hitherto 1,5‐cyclooctadiene (COD) was used almost exclusively as a ligand in transition metal complexes; however, Trost et al. have recently found a ruthenium‐catalyzed reaction, in which COD functions as bis‐homodiene and undergoes a cyclization with alkynes to form derivatives of the tricyclo‐[4.2.2.02, 5]dec‐7‐ene (1) in good yields. Thus, COD may now be considered as a synthetic building block. (Figure Presented.)

AB - Hitherto 1,5‐cyclooctadiene (COD) was used almost exclusively as a ligand in transition metal complexes; however, Trost et al. have recently found a ruthenium‐catalyzed reaction, in which COD functions as bis‐homodiene and undergoes a cyclization with alkynes to form derivatives of the tricyclo‐[4.2.2.02, 5]dec‐7‐ene (1) in good yields. Thus, COD may now be considered as a synthetic building block. (Figure Presented.)

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U2 - 10.1002/anie.199406361

DO - 10.1002/anie.199406361

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VL - 33

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EP - 638

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

SN - 0570-0833

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ER -