Details
| Original language | English |
|---|---|
| Pages (from-to) | 517-523 |
| Number of pages | 7 |
| Journal | Zeitschrift fur Kristallographie - New Crystal Structures |
| Volume | 209 |
| Issue number | 6 |
| Publication status | Published - 1994 |
| Externally published | Yes |
Abstract
Cubic silica sodalite with 1, 3, 5-trioxane template, [Si12O24]. 2 C3H603, a0 = 8.8349(1) A, space group 743m, Z = 1, was studied at room temperature and at elevated pressures up to 1.28 GPa with neutron powder diffraction. No deviations from cubic symmetry could be observed with increasing pressure. The linear bulk modulus of the compound was determined to be 132(7) GPa. Rietveld profile refinements revealed that the volume reduction under pressure is correlated with an increase of the cooperative tilting of the relatively rigid framework SiO4-tetrahedra. This suggests that the tilting is the principal component of the compression mechanism.
ASJC Scopus subject areas
- Materials Science(all)
- Physics and Astronomy(all)
- Condensed Matter Physics
- Chemistry(all)
- Inorganic Chemistry
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In: Zeitschrift fur Kristallographie - New Crystal Structures, Vol. 209, No. 6, 1994, p. 517-523.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Compression mechanism in trioxane silica sodalite, [Si12O24] • 2 C3H603
AU - Futterer, K.
AU - Depmeier, W.
AU - Altorfer, F.
AU - Behrens, P.
AU - Felsche, J.
PY - 1994
Y1 - 1994
N2 - Cubic silica sodalite with 1, 3, 5-trioxane template, [Si12O24]. 2 C3H603, a0 = 8.8349(1) A, space group 743m, Z = 1, was studied at room temperature and at elevated pressures up to 1.28 GPa with neutron powder diffraction. No deviations from cubic symmetry could be observed with increasing pressure. The linear bulk modulus of the compound was determined to be 132(7) GPa. Rietveld profile refinements revealed that the volume reduction under pressure is correlated with an increase of the cooperative tilting of the relatively rigid framework SiO4-tetrahedra. This suggests that the tilting is the principal component of the compression mechanism.
AB - Cubic silica sodalite with 1, 3, 5-trioxane template, [Si12O24]. 2 C3H603, a0 = 8.8349(1) A, space group 743m, Z = 1, was studied at room temperature and at elevated pressures up to 1.28 GPa with neutron powder diffraction. No deviations from cubic symmetry could be observed with increasing pressure. The linear bulk modulus of the compound was determined to be 132(7) GPa. Rietveld profile refinements revealed that the volume reduction under pressure is correlated with an increase of the cooperative tilting of the relatively rigid framework SiO4-tetrahedra. This suggests that the tilting is the principal component of the compression mechanism.
UR - http://www.scopus.com/inward/record.url?scp=84855485039&partnerID=8YFLogxK
U2 - 10.1524/zkri.1994.209.6.517
DO - 10.1524/zkri.1994.209.6.517
M3 - Article
AN - SCOPUS:84855485039
VL - 209
SP - 517
EP - 523
JO - Zeitschrift fur Kristallographie - New Crystal Structures
JF - Zeitschrift fur Kristallographie - New Crystal Structures
SN - 1433-7266
IS - 6
ER -