Details
Original language | English |
---|---|
Article number | e202412406 |
Number of pages | 6 |
Journal | Angewandte Chemie - International Edition |
Volume | 63 |
Issue number | 48 |
Early online date | 22 Aug 2024 |
Publication status | Published - 17 Nov 2024 |
Abstract
This study delves into driving forces behind the formation of a hetero ternary cluster consisting of volatile organic compounds from industrial or combustion sources, specifically cyclopentene, alongside greenhouse gases like carbon dioxide, and water vapor. While substantial progress has been made in understanding binary complexes, the structural intricacies of hetero ternary clusters remain largely uncharted. Our research characterized the cyclopentene−CO2−H2O hetero ternary cluster utilizing Fourier transform microwave spectroscopy. The observed isomer in the pulsed jet has CO2 and H2O aligning above the cyclopentene ring, with water undergoing an internal rotation approximately about its C2 symmetry axis. Theoretical analyses support these observations, identifying an O−H⋅⋅⋅π hydrogen bond and a secondary C⋅⋅⋅O tetrel bond within this cluster. This study marks a critical step towards comprehending the molecular dynamics and interactions of VOCs, greenhouse gases, and water in the atmosphere, paving the way for further investigations into their roles in climate dynamics and air quality.
Keywords
- cyclopentene, Fourier transform microwave spectroscopy, hetero ternary cluster, rotational spectroscopy, volatile organic compounds
ASJC Scopus subject areas
- Chemical Engineering(all)
- Catalysis
- Chemistry(all)
- General Chemistry
Sustainable Development Goals
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In: Angewandte Chemie - International Edition, Vol. 63, No. 48, e202412406, 17.11.2024.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Complex Dance of Molecules in the Sky
T2 - Choreography of Intermolecular Structure and Dynamics in the Cyclopentene−CO2−H2O Hetero Ternary Cluster
AU - Tian, Xiao
AU - Lei, Juncheng
AU - Gao, Tianyue
AU - Zou, Siyu
AU - Wang, Xiujuan
AU - Li, Meiyue
AU - Wang, Chenxu
AU - Chen, Junhua
AU - Grabow, Jens Uwe
AU - Jäger, Wolfgang
AU - Gou, Qian
N1 - Publisher Copyright: © 2024 Wiley-VCH GmbH.
PY - 2024/11/17
Y1 - 2024/11/17
N2 - This study delves into driving forces behind the formation of a hetero ternary cluster consisting of volatile organic compounds from industrial or combustion sources, specifically cyclopentene, alongside greenhouse gases like carbon dioxide, and water vapor. While substantial progress has been made in understanding binary complexes, the structural intricacies of hetero ternary clusters remain largely uncharted. Our research characterized the cyclopentene−CO2−H2O hetero ternary cluster utilizing Fourier transform microwave spectroscopy. The observed isomer in the pulsed jet has CO2 and H2O aligning above the cyclopentene ring, with water undergoing an internal rotation approximately about its C2 symmetry axis. Theoretical analyses support these observations, identifying an O−H⋅⋅⋅π hydrogen bond and a secondary C⋅⋅⋅O tetrel bond within this cluster. This study marks a critical step towards comprehending the molecular dynamics and interactions of VOCs, greenhouse gases, and water in the atmosphere, paving the way for further investigations into their roles in climate dynamics and air quality.
AB - This study delves into driving forces behind the formation of a hetero ternary cluster consisting of volatile organic compounds from industrial or combustion sources, specifically cyclopentene, alongside greenhouse gases like carbon dioxide, and water vapor. While substantial progress has been made in understanding binary complexes, the structural intricacies of hetero ternary clusters remain largely uncharted. Our research characterized the cyclopentene−CO2−H2O hetero ternary cluster utilizing Fourier transform microwave spectroscopy. The observed isomer in the pulsed jet has CO2 and H2O aligning above the cyclopentene ring, with water undergoing an internal rotation approximately about its C2 symmetry axis. Theoretical analyses support these observations, identifying an O−H⋅⋅⋅π hydrogen bond and a secondary C⋅⋅⋅O tetrel bond within this cluster. This study marks a critical step towards comprehending the molecular dynamics and interactions of VOCs, greenhouse gases, and water in the atmosphere, paving the way for further investigations into their roles in climate dynamics and air quality.
KW - cyclopentene
KW - Fourier transform microwave spectroscopy
KW - hetero ternary cluster
KW - rotational spectroscopy
KW - volatile organic compounds
UR - http://www.scopus.com/inward/record.url?scp=85206628837&partnerID=8YFLogxK
U2 - 10.1002/anie.202412406
DO - 10.1002/anie.202412406
M3 - Article
C2 - 39175182
AN - SCOPUS:85206628837
VL - 63
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 48
M1 - e202412406
ER -