Details
| Original language | English |
|---|---|
| Pages (from-to) | 388-390 |
| Number of pages | 3 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 5 |
| Publication status | Published - 1986 |
| Externally published | Yes |
Abstract
(η5-C5H5)Co(CO)2 catalyses the [2+2+2] cycloaddition of silylated enediynes to furnish 1-trimethylsilyl and 1,11-bis(trimethylsilylated) A-ring aromatic steroids which exhibit unexpected hindered rotation of the trimethylsilyl groups.
ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)
- Molecular Medicine
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In: Journal of the Chemical Society, Chemical Communications, No. 5, 1986, p. 388-390.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Cobalt-mediated Synthesis of Highly Crowded Steroids
T2 - Unusual Observations of Hindered Rotation of a Trimethylsilyl Group
AU - Butenschön, Holger
AU - Winkler, Matthias
AU - Vollhardt, K. Peter C.
PY - 1986
Y1 - 1986
N2 - (η5-C5H5)Co(CO)2 catalyses the [2+2+2] cycloaddition of silylated enediynes to furnish 1-trimethylsilyl and 1,11-bis(trimethylsilylated) A-ring aromatic steroids which exhibit unexpected hindered rotation of the trimethylsilyl groups.
AB - (η5-C5H5)Co(CO)2 catalyses the [2+2+2] cycloaddition of silylated enediynes to furnish 1-trimethylsilyl and 1,11-bis(trimethylsilylated) A-ring aromatic steroids which exhibit unexpected hindered rotation of the trimethylsilyl groups.
UR - http://www.scopus.com/inward/record.url?scp=37049074971&partnerID=8YFLogxK
U2 - 10.1039/C39860000388
DO - 10.1039/C39860000388
M3 - Article
AN - SCOPUS:37049074971
SP - 388
EP - 390
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
SN - 0022-4936
IS - 5
ER -