Details
Translated title of the contribution | Chemical transport of solid solutions: Transport phenomena in the Co3O4/CoGa2O4 system |
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Original language | German |
Pages (from-to) | 1482-1487 |
Number of pages | 6 |
Journal | Zeitschrift fur Anorganische und Allgemeine Chemie |
Volume | 626 |
Issue number | 6 |
Publication status | Published - 16 May 2000 |
Abstract
Chemical transport reactions are a suitable pathway to the preparation of mixed spinels Co(Ga, Co)2O4 in the Co3O4/CoGa2O4 system. Solid solutions with specific CoIII/GaIII ratios are accessible via variation of the source material compositions, because Co3O4 and CoGa2O4 are completely miscible. Electron microprobe analyses indicate the beginning of a zoning process in the crystals deposited. Experiments are consistent with thermodynamic calculations.
ASJC Scopus subject areas
- Chemistry(all)
- Inorganic Chemistry
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In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 626, No. 6, 16.05.2000, p. 1482-1487.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Chemischer transport fester lösungen
T2 - Der chemische transport von mischkristallen im system Co3O4/CoGa2O4
AU - Patzke, Greta R.
AU - Koepke, Jürgen
AU - Binnewies, Michael
PY - 2000/5/16
Y1 - 2000/5/16
N2 - Chemical transport reactions are a suitable pathway to the preparation of mixed spinels Co(Ga, Co)2O4 in the Co3O4/CoGa2O4 system. Solid solutions with specific CoIII/GaIII ratios are accessible via variation of the source material compositions, because Co3O4 and CoGa2O4 are completely miscible. Electron microprobe analyses indicate the beginning of a zoning process in the crystals deposited. Experiments are consistent with thermodynamic calculations.
AB - Chemical transport reactions are a suitable pathway to the preparation of mixed spinels Co(Ga, Co)2O4 in the Co3O4/CoGa2O4 system. Solid solutions with specific CoIII/GaIII ratios are accessible via variation of the source material compositions, because Co3O4 and CoGa2O4 are completely miscible. Electron microprobe analyses indicate the beginning of a zoning process in the crystals deposited. Experiments are consistent with thermodynamic calculations.
KW - Chemical transport reactions
KW - Cobalt
KW - Gallium
KW - Mixed spinels
UR - http://www.scopus.com/inward/record.url?scp=0034385524&partnerID=8YFLogxK
U2 - 10.1002/(sici)1521-3749(200006)626:6<1482::aid-zaac1482>3.0.co;2-h
DO - 10.1002/(sici)1521-3749(200006)626:6<1482::aid-zaac1482>3.0.co;2-h
M3 - Artikel
AN - SCOPUS:0034385524
VL - 626
SP - 1482
EP - 1487
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
SN - 0044-2313
IS - 6
ER -