Details
| Original language | English |
|---|---|
| Pages (from-to) | 632-637 |
| Number of pages | 6 |
| Journal | Solid State Ionics |
| Volume | 192 |
| Issue number | 1 |
| Early online date | 11 Aug 2010 |
| Publication status | Published - 16 Jun 2011 |
Abstract
Nanocrystalline ZnSe was prepared by mechanochemical synthesis in a laboratory mill and an industrial mill from the mixture of Zn and Se powdered precursors. XRD measurements indicate the formation of the cubic and hexagonal modifications of ZnSe during mechanochemical synthesis in the laboratory mill. Hexagonal modification disappears with increasing time of mechanochemical reaction. XPS analysis was applied to study the surface composition of mechanosynthesized ZnSe. The reaction products were also characterized by TEM. An application of the industrial mill verified the possibility of a large-scale mechanochemical production of ZnSe semiconductor at ambient temperature and in a relatively short reaction time (15-60 min).
Keywords
- Industrial mill, Mechanochemistry, TEM, XPS, Zinc selenide
ASJC Scopus subject areas
- Chemistry(all)
- General Chemistry
- Materials Science(all)
- General Materials Science
- Physics and Astronomy(all)
- Condensed Matter Physics
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In: Solid State Ionics, Vol. 192, No. 1, 16.06.2011, p. 632-637.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Characterization of mechanochemically synthesized ZnSe in a laboratory and an industrial mill
AU - Achimovičová, M.
AU - Baláž, P.
AU - Ohtani, T.
AU - Kostova, N.
AU - Tyuliev, G.
AU - Feldhoff, Armin
AU - Šepelák, V.
PY - 2011/6/16
Y1 - 2011/6/16
N2 - Nanocrystalline ZnSe was prepared by mechanochemical synthesis in a laboratory mill and an industrial mill from the mixture of Zn and Se powdered precursors. XRD measurements indicate the formation of the cubic and hexagonal modifications of ZnSe during mechanochemical synthesis in the laboratory mill. Hexagonal modification disappears with increasing time of mechanochemical reaction. XPS analysis was applied to study the surface composition of mechanosynthesized ZnSe. The reaction products were also characterized by TEM. An application of the industrial mill verified the possibility of a large-scale mechanochemical production of ZnSe semiconductor at ambient temperature and in a relatively short reaction time (15-60 min).
AB - Nanocrystalline ZnSe was prepared by mechanochemical synthesis in a laboratory mill and an industrial mill from the mixture of Zn and Se powdered precursors. XRD measurements indicate the formation of the cubic and hexagonal modifications of ZnSe during mechanochemical synthesis in the laboratory mill. Hexagonal modification disappears with increasing time of mechanochemical reaction. XPS analysis was applied to study the surface composition of mechanosynthesized ZnSe. The reaction products were also characterized by TEM. An application of the industrial mill verified the possibility of a large-scale mechanochemical production of ZnSe semiconductor at ambient temperature and in a relatively short reaction time (15-60 min).
KW - Industrial mill
KW - Mechanochemistry
KW - TEM
KW - XPS
KW - Zinc selenide
UR - http://www.scopus.com/inward/record.url?scp=79958813759&partnerID=8YFLogxK
U2 - 10.1016/j.ssi.2010.07.009
DO - 10.1016/j.ssi.2010.07.009
M3 - Article
AN - SCOPUS:79958813759
VL - 192
SP - 632
EP - 637
JO - Solid State Ionics
JF - Solid State Ionics
SN - 0167-2738
IS - 1
ER -