Details
| Original language | English |
|---|---|
| Pages (from-to) | 3722-3728 |
| Number of pages | 7 |
| Journal | Chemistry - a European journal |
| Volume | 7 |
| Issue number | 17 |
| Publication status | Published - 3 Sept 2001 |
Abstract
The synthesis of poly(vinyl ether)s or polyvinylcarbazole under the conditions of constricted geometry can be achieved by means of cationic host - guest polymerisation of the corresponding monomers in the pores of MCM-41 (pore diameter 3.6 nm), MCM-48 (pore diameter 2.4 nm) and in nanoporous glasses (Gelsil® with a pore diameter of 5 nm) with bis(4-methoxyphenyl)methyl chloride (BMCC) or triphenylmethyl chloride as the internal surface initiator. The reaction products are new polymer/ MCM-41, polymer/MCM-48 etc., host - guest hybrid materials. The molecular mass of the enclosed polymer and the degree of loading of the host compounds can be adjusted within certain limits. The molecular dynamics were investigated by using broad-band dielectric spectroscopy. Under the conditions of constricted geometry, molecular fluctuation is observed as well as a secondary β-relaxation, which is hardly affected (in comparison with the free melt) and which corresponds to the relaxation between structural substates (dynamic glass transition). This process is several orders of magnitude faster in its relaxation rate than in the free melt and thus follows a confinement effect. This is already well known in lower molecular weight systems with constricted geometry.
Keywords
- Organic-inorganic hybrid composites, Polymerization, Vinyl ether, Vinylcarbazole, Zeolites
ASJC Scopus subject areas
- Chemical Engineering(all)
- Catalysis
- Chemistry(all)
- Organic Chemistry
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In: Chemistry - a European journal, Vol. 7, No. 17, 03.09.2001, p. 3722-3728.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Cationic host - Guest polymerization of N-vinylcarbazole and vinyl ethers in MCM-41, MCM-48, and nanoporous glasses
AU - Spange, Stefan
AU - Gräser, Annett
AU - Huwe, Andreas
AU - Kremer, Friedrich
AU - Tintemann, Carsten
AU - Behrens, Peter
PY - 2001/9/3
Y1 - 2001/9/3
N2 - The synthesis of poly(vinyl ether)s or polyvinylcarbazole under the conditions of constricted geometry can be achieved by means of cationic host - guest polymerisation of the corresponding monomers in the pores of MCM-41 (pore diameter 3.6 nm), MCM-48 (pore diameter 2.4 nm) and in nanoporous glasses (Gelsil® with a pore diameter of 5 nm) with bis(4-methoxyphenyl)methyl chloride (BMCC) or triphenylmethyl chloride as the internal surface initiator. The reaction products are new polymer/ MCM-41, polymer/MCM-48 etc., host - guest hybrid materials. The molecular mass of the enclosed polymer and the degree of loading of the host compounds can be adjusted within certain limits. The molecular dynamics were investigated by using broad-band dielectric spectroscopy. Under the conditions of constricted geometry, molecular fluctuation is observed as well as a secondary β-relaxation, which is hardly affected (in comparison with the free melt) and which corresponds to the relaxation between structural substates (dynamic glass transition). This process is several orders of magnitude faster in its relaxation rate than in the free melt and thus follows a confinement effect. This is already well known in lower molecular weight systems with constricted geometry.
AB - The synthesis of poly(vinyl ether)s or polyvinylcarbazole under the conditions of constricted geometry can be achieved by means of cationic host - guest polymerisation of the corresponding monomers in the pores of MCM-41 (pore diameter 3.6 nm), MCM-48 (pore diameter 2.4 nm) and in nanoporous glasses (Gelsil® with a pore diameter of 5 nm) with bis(4-methoxyphenyl)methyl chloride (BMCC) or triphenylmethyl chloride as the internal surface initiator. The reaction products are new polymer/ MCM-41, polymer/MCM-48 etc., host - guest hybrid materials. The molecular mass of the enclosed polymer and the degree of loading of the host compounds can be adjusted within certain limits. The molecular dynamics were investigated by using broad-band dielectric spectroscopy. Under the conditions of constricted geometry, molecular fluctuation is observed as well as a secondary β-relaxation, which is hardly affected (in comparison with the free melt) and which corresponds to the relaxation between structural substates (dynamic glass transition). This process is several orders of magnitude faster in its relaxation rate than in the free melt and thus follows a confinement effect. This is already well known in lower molecular weight systems with constricted geometry.
KW - Organic-inorganic hybrid composites
KW - Polymerization
KW - Vinyl ether
KW - Vinylcarbazole
KW - Zeolites
UR - http://www.scopus.com/inward/record.url?scp=0035801647&partnerID=8YFLogxK
U2 - 10.1002/1521-3765(20010903)7:17<3722::AID-CHEM3722<3.0.CO;2-J
DO - 10.1002/1521-3765(20010903)7:17<3722::AID-CHEM3722<3.0.CO;2-J
M3 - Article
C2 - 11575772
AN - SCOPUS:0035801647
VL - 7
SP - 3722
EP - 3728
JO - Chemistry - a European journal
JF - Chemistry - a European journal
SN - 0947-6539
IS - 17
ER -