Details
Original language | English |
---|---|
Pages (from-to) | 2286-2294 |
Number of pages | 9 |
Journal | Industrial and Engineering Chemistry Research |
Volume | 46 |
Issue number | 8 |
Early online date | 23 Nov 2006 |
Publication status | Published - 1 Apr 2007 |
Abstract
Two consecutive model reactions of the type A → B → C are studied in two kinds of catalytic membrane reactors. The partial oxidation of methane to synthesis gas due to CH4 + 1/2O2 → CO + 2H 2 was investigated in a novel type of permselective membrane reactor using perovskite hollow fibers for the selective separation of oxygen from air. Partial hydrogenations were studied in a porevtnrough-flow membrane reactor as a special type of a catalytic membrane contactor. The catalytically functionalized pores of the membrane provide a medium with defined contact times for the cofeed of hydrogen and an unsaturated hydrocarbon, and the attempts of the scale-up of the successful laboratory experiments to the pilot scale are reported.
ASJC Scopus subject areas
- Chemistry(all)
- General Chemistry
- Chemical Engineering(all)
- General Chemical Engineering
- Engineering(all)
- Industrial and Manufacturing Engineering
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In: Industrial and Engineering Chemistry Research, Vol. 46, No. 8, 01.04.2007, p. 2286-2294.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Catalytic membrane reactors for partial oxidation using perovskite hollow fiber membranes and for partial hydrogenation using a catalytic membrane contactor
AU - Caro, Jürgen
AU - Caspary, Karl J.
AU - Hamel, Christof
AU - Hoting, Born
AU - Kölsch, Peter
AU - Langanke, Bernd
AU - Nassauer, Konrad
AU - Schiestel, Thomas
AU - Schmidt, Andrea
AU - Schomäcker, Reinhard
AU - Seidel-Morgenstern, Andreas
AU - Tsotsas, Evangelos
AU - Voigt, Ingolf
AU - Wang, Haihui
AU - Warsitz, Rafael
AU - Werth, Steffen
AU - Wolf, Aurel
PY - 2007/4/1
Y1 - 2007/4/1
N2 - Two consecutive model reactions of the type A → B → C are studied in two kinds of catalytic membrane reactors. The partial oxidation of methane to synthesis gas due to CH4 + 1/2O2 → CO + 2H 2 was investigated in a novel type of permselective membrane reactor using perovskite hollow fibers for the selective separation of oxygen from air. Partial hydrogenations were studied in a porevtnrough-flow membrane reactor as a special type of a catalytic membrane contactor. The catalytically functionalized pores of the membrane provide a medium with defined contact times for the cofeed of hydrogen and an unsaturated hydrocarbon, and the attempts of the scale-up of the successful laboratory experiments to the pilot scale are reported.
AB - Two consecutive model reactions of the type A → B → C are studied in two kinds of catalytic membrane reactors. The partial oxidation of methane to synthesis gas due to CH4 + 1/2O2 → CO + 2H 2 was investigated in a novel type of permselective membrane reactor using perovskite hollow fibers for the selective separation of oxygen from air. Partial hydrogenations were studied in a porevtnrough-flow membrane reactor as a special type of a catalytic membrane contactor. The catalytically functionalized pores of the membrane provide a medium with defined contact times for the cofeed of hydrogen and an unsaturated hydrocarbon, and the attempts of the scale-up of the successful laboratory experiments to the pilot scale are reported.
UR - http://www.scopus.com/inward/record.url?scp=34247542983&partnerID=8YFLogxK
U2 - 10.1021/ie0609620
DO - 10.1021/ie0609620
M3 - Article
AN - SCOPUS:34247542983
VL - 46
SP - 2286
EP - 2294
JO - Industrial and Engineering Chemistry Research
JF - Industrial and Engineering Chemistry Research
SN - 0888-5885
IS - 8
ER -