Details
| Original language | English |
|---|---|
| Pages (from-to) | 2986-3007 |
| Number of pages | 22 |
| Journal | Energy and Fuels |
| Volume | 39 |
| Issue number | 6 |
| Early online date | 30 Jan 2025 |
| Publication status | Published - 13 Feb 2025 |
Abstract
Semiconductor photocatalysis is a sustainable technology to address environmental pollution problems by efficiently utilizing solar energy. Developing efficient photocatalysts is particularly important. Recently, metal halide perovskites, especially lead halide perovskites (LHPs), have garnered widespread interest in photocatalytic fields due to their unique optoelectronic properties. However, the high toxicity of elemental lead has become a significant obstacle restricting the practical application of LHPs. In response, bismuth halide perovskites (BHPs) have emerged as a promising alternative. This review summarizes recent advances in this exciting area. First, we examine the wet-chemical synthesis methods for various BHPs. The physicochemical properties of BHPs are then discussed, with special emphasis on their stability. Methods to enhance stability, including composition engineering, surface engineering, and packaging engineering, are described. Emerging applications of BHPs in photocatalytic hydrogen production (H2), carbon dioxide (CO2) reduction, oxynitride (NOx) oxidation, organic synthesis and pollutant dye degradation are also reviewed. Finally, the challenges faced by BHPs and future research directions are analyzed and prospected.
ASJC Scopus subject areas
- Chemical Engineering(all)
- General Chemical Engineering
- Energy(all)
- Fuel Technology
- Energy(all)
- Energy Engineering and Power Technology
Sustainable Development Goals
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In: Energy and Fuels, Vol. 39, No. 6, 13.02.2025, p. 2986-3007.
Research output: Contribution to journal › Review article › Research › peer review
}
TY - JOUR
T1 - Bi-Based Metal Halide Perovskites and Their Photocatalytic Properties
T2 - A Review
AU - Li, Yan Jie
AU - Mu, Ben Hong
AU - Li, Hong Bin
AU - Tang, Shuang Chao
AU - Tian, Jie
AU - Li, Yu
AU - Ji, Zhuo Yu
AU - Wang, Yan Jie
AU - He, Tao
AU - Emeline, Alexei V.
AU - Bahnemann, Detlef W.
AU - Pan, Jia Hong
N1 - Publisher Copyright: © 2025 American Chemical Society.
PY - 2025/2/13
Y1 - 2025/2/13
N2 - Semiconductor photocatalysis is a sustainable technology to address environmental pollution problems by efficiently utilizing solar energy. Developing efficient photocatalysts is particularly important. Recently, metal halide perovskites, especially lead halide perovskites (LHPs), have garnered widespread interest in photocatalytic fields due to their unique optoelectronic properties. However, the high toxicity of elemental lead has become a significant obstacle restricting the practical application of LHPs. In response, bismuth halide perovskites (BHPs) have emerged as a promising alternative. This review summarizes recent advances in this exciting area. First, we examine the wet-chemical synthesis methods for various BHPs. The physicochemical properties of BHPs are then discussed, with special emphasis on their stability. Methods to enhance stability, including composition engineering, surface engineering, and packaging engineering, are described. Emerging applications of BHPs in photocatalytic hydrogen production (H2), carbon dioxide (CO2) reduction, oxynitride (NOx) oxidation, organic synthesis and pollutant dye degradation are also reviewed. Finally, the challenges faced by BHPs and future research directions are analyzed and prospected.
AB - Semiconductor photocatalysis is a sustainable technology to address environmental pollution problems by efficiently utilizing solar energy. Developing efficient photocatalysts is particularly important. Recently, metal halide perovskites, especially lead halide perovskites (LHPs), have garnered widespread interest in photocatalytic fields due to their unique optoelectronic properties. However, the high toxicity of elemental lead has become a significant obstacle restricting the practical application of LHPs. In response, bismuth halide perovskites (BHPs) have emerged as a promising alternative. This review summarizes recent advances in this exciting area. First, we examine the wet-chemical synthesis methods for various BHPs. The physicochemical properties of BHPs are then discussed, with special emphasis on their stability. Methods to enhance stability, including composition engineering, surface engineering, and packaging engineering, are described. Emerging applications of BHPs in photocatalytic hydrogen production (H2), carbon dioxide (CO2) reduction, oxynitride (NOx) oxidation, organic synthesis and pollutant dye degradation are also reviewed. Finally, the challenges faced by BHPs and future research directions are analyzed and prospected.
UR - http://www.scopus.com/inward/record.url?scp=85217007106&partnerID=8YFLogxK
U2 - 10.1021/acs.energyfuels.4c06208
DO - 10.1021/acs.energyfuels.4c06208
M3 - Review article
AN - SCOPUS:85217007106
VL - 39
SP - 2986
EP - 3007
JO - Energy and Fuels
JF - Energy and Fuels
SN - 0887-0624
IS - 6
ER -