Details
| Original language | English |
|---|---|
| Pages (from-to) | 1243-1252 |
| Number of pages | 10 |
| Journal | Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals |
| Volume | 335 |
| Publication status | Published - 1999 |
| Externally published | Yes |
| Event | 1998 6th International Conference on Molecule Based Magnets (ICMM'98) - Seignosse, France Duration: 12 Sept 1998 → 17 Sept 1998 |
Abstract
[Fe(II)(2,6-bis-(benzimidazol-2′-yl)-pyridine)2 ](ClO4)2 diffused into a poly(vinyl)alcohol polymer matrix, exhibits an thermally induced spin-crossover. After stretching the matrix, the compound orients itself in the matrix. Polarized UV/VIS spectra measured parallel and perpendicular to the stretching direction allowed to calculate the distortion of the molecule in the matrix by means of semi-empirical PPP SCF-CI calculations.
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Condensed Matter Physics
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In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 335, 1999, p. 1243-1252.
Research output: Contribution to journal › Conference article › Research › peer review
}
TY - JOUR
T1 - Anisotropic effect after stretching of the spin-crossover compound [Fe(II)(2,6-bis-(benzimidazol-2′-yl)pyridine)2] (ClO4)2 in polyvinylalcohol polymer matrix
AU - Renz, Franz
AU - Hasegawa, Miki
AU - Hoshi, Toshihiku
AU - El-Ayaan, Usama
AU - Linert, Wolfgang
AU - Fukuda, Yutaka
PY - 1999
Y1 - 1999
N2 - [Fe(II)(2,6-bis-(benzimidazol-2′-yl)-pyridine)2 ](ClO4)2 diffused into a poly(vinyl)alcohol polymer matrix, exhibits an thermally induced spin-crossover. After stretching the matrix, the compound orients itself in the matrix. Polarized UV/VIS spectra measured parallel and perpendicular to the stretching direction allowed to calculate the distortion of the molecule in the matrix by means of semi-empirical PPP SCF-CI calculations.
AB - [Fe(II)(2,6-bis-(benzimidazol-2′-yl)-pyridine)2 ](ClO4)2 diffused into a poly(vinyl)alcohol polymer matrix, exhibits an thermally induced spin-crossover. After stretching the matrix, the compound orients itself in the matrix. Polarized UV/VIS spectra measured parallel and perpendicular to the stretching direction allowed to calculate the distortion of the molecule in the matrix by means of semi-empirical PPP SCF-CI calculations.
UR - http://www.scopus.com/inward/record.url?scp=0033352699&partnerID=8YFLogxK
M3 - Conference article
AN - SCOPUS:0033352699
VL - 335
SP - 1243
EP - 1252
JO - Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
JF - Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
SN - 1058-725X
T2 - 1998 6th International Conference on Molecule Based Magnets (ICMM'98)
Y2 - 12 September 1998 through 17 September 1998
ER -