Details
| Original language | English |
|---|---|
| Pages (from-to) | 84-90 |
| Number of pages | 7 |
| Journal | Chemical Engineering Journal |
| Volume | 347 |
| Early online date | 16 Apr 2018 |
| Publication status | Published - 1 Sept 2018 |
Abstract
For practical application in syngas production, the oxygen permeable membranes should possess both high oxygen permeation flux and good stability in harsh environment (CO2-containing reductive atmosphere). Under the premise of keeping stability, anion-doping method was applied to improve the oxygen permeability of the CO2-stable (Pr0.9La0.1)2.0(Ni0.74Cu0.21Ga0.05)O4+δ ((PL)2.0NCG) membrane. The developed (Pr0.9La0.1)2.0(Ni0.74Cu0.21Ga0.05)O4+δCl0.1 ((PL)2.0NCGCl0.1) exhibited three times higher oxygen permeation fluxes, similar CO2-tolerance and long-term stability compared with its parent one. Furthermore, the (PL)2.0NCGCl0.1 membrane was constructed to be used in reactors for the syngas production through partial oxidation of methane, which showed an oxygen permeation flux of 5 mL/min cm2, a methane conversion of 99.9%, and a CO selectivity of 97.5% at 900 °C, and no any degradation was observed during 100 h.
Keywords
- Anion-doping, CO stability, Oxygen separation membrane, Partial oxidation of methane
ASJC Scopus subject areas
- Chemistry(all)
- Environmental Science(all)
- Environmental Chemistry
- Chemical Engineering(all)
- Engineering(all)
- Industrial and Manufacturing Engineering
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In: Chemical Engineering Journal, Vol. 347, 01.09.2018, p. 84-90.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Anion doping CO2-stable oxygen permeable membranes for syngas production
AU - Xue, Jian
AU - Li, Jiaqi
AU - Zhuang, Libin
AU - Chen, Li
AU - Feldhoff, Armin
AU - Wang, Haihui
N1 - Funding Information: The Authors thank the financial support from National Natural Science Foundation of China (No. 21706076 , 21536005 , 51621001 ), Natural Science Foundation of Guangdong (and 2017A030310431 and 2014A030312007 ), China Postdoctoral Science Foundation (No. 2017M612665 ), Fundamental Research Funds for the Central Universities (No. 2017BQ016 ) and the Deutsche Forschungsgemeinschaft (DFG) ( FE928/7-1 ). Publisher Copyright: © 2018 Elsevier B.V. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2018/9/1
Y1 - 2018/9/1
N2 - For practical application in syngas production, the oxygen permeable membranes should possess both high oxygen permeation flux and good stability in harsh environment (CO2-containing reductive atmosphere). Under the premise of keeping stability, anion-doping method was applied to improve the oxygen permeability of the CO2-stable (Pr0.9La0.1)2.0(Ni0.74Cu0.21Ga0.05)O4+δ ((PL)2.0NCG) membrane. The developed (Pr0.9La0.1)2.0(Ni0.74Cu0.21Ga0.05)O4+δCl0.1 ((PL)2.0NCGCl0.1) exhibited three times higher oxygen permeation fluxes, similar CO2-tolerance and long-term stability compared with its parent one. Furthermore, the (PL)2.0NCGCl0.1 membrane was constructed to be used in reactors for the syngas production through partial oxidation of methane, which showed an oxygen permeation flux of 5 mL/min cm2, a methane conversion of 99.9%, and a CO selectivity of 97.5% at 900 °C, and no any degradation was observed during 100 h.
AB - For practical application in syngas production, the oxygen permeable membranes should possess both high oxygen permeation flux and good stability in harsh environment (CO2-containing reductive atmosphere). Under the premise of keeping stability, anion-doping method was applied to improve the oxygen permeability of the CO2-stable (Pr0.9La0.1)2.0(Ni0.74Cu0.21Ga0.05)O4+δ ((PL)2.0NCG) membrane. The developed (Pr0.9La0.1)2.0(Ni0.74Cu0.21Ga0.05)O4+δCl0.1 ((PL)2.0NCGCl0.1) exhibited three times higher oxygen permeation fluxes, similar CO2-tolerance and long-term stability compared with its parent one. Furthermore, the (PL)2.0NCGCl0.1 membrane was constructed to be used in reactors for the syngas production through partial oxidation of methane, which showed an oxygen permeation flux of 5 mL/min cm2, a methane conversion of 99.9%, and a CO selectivity of 97.5% at 900 °C, and no any degradation was observed during 100 h.
KW - Anion-doping
KW - CO stability
KW - Oxygen separation membrane
KW - Partial oxidation of methane
UR - http://www.scopus.com/inward/record.url?scp=85049662451&partnerID=8YFLogxK
U2 - 10.1016/j.cej.2018.04.090
DO - 10.1016/j.cej.2018.04.090
M3 - Article
AN - SCOPUS:85049662451
VL - 347
SP - 84
EP - 90
JO - Chemical Engineering Journal
JF - Chemical Engineering Journal
SN - 1385-8947
ER -