Details
| Original language | English |
|---|---|
| Pages (from-to) | 62656-62667 |
| Number of pages | 12 |
| Journal | RSC Advances |
| Volume | 6 |
| Issue number | 67 |
| Publication status | Published - 2016 |
Abstract
We present a novel approach to the solid-state synthesis of garnet-type cubic Li7La3Zr2O12 (c-LLZO) nanostructured particles with 1.0 mass% Al at 750 °C within 3 h. In contrast to conventional solid-state processes, a highly reactive precursor was prepared in two steps: (i) by homogenizing the stoichiometric mixture without Li, and (ii) subsequent addition of Li in the form of an ethanolic solution of lithium acetate. The actual composition determined by ICP analysis was Li6.61La3Zr2Al0.13O11.98. Sintering these nanoparticles at 1100 °C for 3 h in air after cold isostatic pressing brought a dense ceramic pellet with a relative density of 90.5%. The corresponding ionic conductivity with Au electrodes was 1.6 × 10-4 S cm-1 at room temperature. To study its electrochemical behavior as an electrolyte, a model cell of Li//(1 M LiPF6 + c-LLZO)//LiCoO2 configuration was constructed. Cyclic voltammetry of the cell delivered one set of redox couple with narrow voltage separation (15 mV) with a Li+ diffusion coefficient at room temperature of about 2 × 10-11 cm2 s-1 at the interface between LiCoO2 and 1 M LiPF6 + c-LLZO. The cell received an average discharge capacity of 64.4, 60.3, 56.1, 51.9 and 46.9 μA h cm-2 μm-1 at discharge rates 0.5C, 1C, 2C, 4C and 6C, respectively. The cell exhibited complete oxidation and reduction reactions with an average initial discharge capacity of about 64 μA h cm-2 μm-1, which is 92.7% of LiCoO2 theoretical value. These observations indicate the applicability of the present c-LLZO as an electrolyte for a solid-state Li-ion battery.
ASJC Scopus subject areas
- Chemistry(all)
- General Chemistry
- Chemical Engineering(all)
- General Chemical Engineering
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In: RSC Advances, Vol. 6, No. 67, 2016, p. 62656-62667.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - A novel low-temperature solid-state route for nanostructured cubic garnet Li7La3Zr2O12 and its application to Li-ion battery
AU - Kumar, P. Jeevan
AU - Nishimura, K.
AU - Senna, M.
AU - Düvel, A.
AU - Heitjans, P.
AU - Kawaguchi, T.
AU - Sakamoto, N.
AU - Wakiya, N.
AU - Suzuki, H.
N1 - Publisher Copyright: © 2016 The Royal Society of Chemistry.
PY - 2016
Y1 - 2016
N2 - We present a novel approach to the solid-state synthesis of garnet-type cubic Li7La3Zr2O12 (c-LLZO) nanostructured particles with 1.0 mass% Al at 750 °C within 3 h. In contrast to conventional solid-state processes, a highly reactive precursor was prepared in two steps: (i) by homogenizing the stoichiometric mixture without Li, and (ii) subsequent addition of Li in the form of an ethanolic solution of lithium acetate. The actual composition determined by ICP analysis was Li6.61La3Zr2Al0.13O11.98. Sintering these nanoparticles at 1100 °C for 3 h in air after cold isostatic pressing brought a dense ceramic pellet with a relative density of 90.5%. The corresponding ionic conductivity with Au electrodes was 1.6 × 10-4 S cm-1 at room temperature. To study its electrochemical behavior as an electrolyte, a model cell of Li//(1 M LiPF6 + c-LLZO)//LiCoO2 configuration was constructed. Cyclic voltammetry of the cell delivered one set of redox couple with narrow voltage separation (15 mV) with a Li+ diffusion coefficient at room temperature of about 2 × 10-11 cm2 s-1 at the interface between LiCoO2 and 1 M LiPF6 + c-LLZO. The cell received an average discharge capacity of 64.4, 60.3, 56.1, 51.9 and 46.9 μA h cm-2 μm-1 at discharge rates 0.5C, 1C, 2C, 4C and 6C, respectively. The cell exhibited complete oxidation and reduction reactions with an average initial discharge capacity of about 64 μA h cm-2 μm-1, which is 92.7% of LiCoO2 theoretical value. These observations indicate the applicability of the present c-LLZO as an electrolyte for a solid-state Li-ion battery.
AB - We present a novel approach to the solid-state synthesis of garnet-type cubic Li7La3Zr2O12 (c-LLZO) nanostructured particles with 1.0 mass% Al at 750 °C within 3 h. In contrast to conventional solid-state processes, a highly reactive precursor was prepared in two steps: (i) by homogenizing the stoichiometric mixture without Li, and (ii) subsequent addition of Li in the form of an ethanolic solution of lithium acetate. The actual composition determined by ICP analysis was Li6.61La3Zr2Al0.13O11.98. Sintering these nanoparticles at 1100 °C for 3 h in air after cold isostatic pressing brought a dense ceramic pellet with a relative density of 90.5%. The corresponding ionic conductivity with Au electrodes was 1.6 × 10-4 S cm-1 at room temperature. To study its electrochemical behavior as an electrolyte, a model cell of Li//(1 M LiPF6 + c-LLZO)//LiCoO2 configuration was constructed. Cyclic voltammetry of the cell delivered one set of redox couple with narrow voltage separation (15 mV) with a Li+ diffusion coefficient at room temperature of about 2 × 10-11 cm2 s-1 at the interface between LiCoO2 and 1 M LiPF6 + c-LLZO. The cell received an average discharge capacity of 64.4, 60.3, 56.1, 51.9 and 46.9 μA h cm-2 μm-1 at discharge rates 0.5C, 1C, 2C, 4C and 6C, respectively. The cell exhibited complete oxidation and reduction reactions with an average initial discharge capacity of about 64 μA h cm-2 μm-1, which is 92.7% of LiCoO2 theoretical value. These observations indicate the applicability of the present c-LLZO as an electrolyte for a solid-state Li-ion battery.
UR - http://www.scopus.com/inward/record.url?scp=84977487497&partnerID=8YFLogxK
U2 - 10.1039/c6ra09695f
DO - 10.1039/c6ra09695f
M3 - Article
AN - SCOPUS:84977487497
VL - 6
SP - 62656
EP - 62667
JO - RSC Advances
JF - RSC Advances
SN - 2046-2069
IS - 67
ER -