Details
| Original language | English |
|---|---|
| Pages (from-to) | 3781-3784 |
| Number of pages | 4 |
| Journal | Organic Letters |
| Volume | 2 |
| Issue number | 24 |
| Publication status | Published - 10 Nov 2000 |
Abstract
formula presented A new, polymer-bound reagent system for the efficient oxidation of primary alcohols to aldehydes and secondary alcohols to ketones in the presence of a catalytic amount of 2,2,6,6-tetramethyl-1-piperidinyloxyl (TEMPO) is described. In most cases, workup of this heavy metal-free oxidation is achieved by simple filtration followed by removal of the solvent. In selected examples this reagent was compared with the known polymer-bound permanganate and chromium(VI) reagents.
ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)
- Biochemistry
- Chemistry(all)
- Physical and Theoretical Chemistry
- Chemistry(all)
- Organic Chemistry
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In: Organic Letters, Vol. 2, No. 24, 10.11.2000, p. 3781-3784.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - A New Polymer-attached Reagent for the Oxidation of Primary and Secondary Alcohols
AU - Sourkouni-Argirusi, Georgia
AU - Kirschning, Andreas
PY - 2000/11/10
Y1 - 2000/11/10
N2 - formula presented A new, polymer-bound reagent system for the efficient oxidation of primary alcohols to aldehydes and secondary alcohols to ketones in the presence of a catalytic amount of 2,2,6,6-tetramethyl-1-piperidinyloxyl (TEMPO) is described. In most cases, workup of this heavy metal-free oxidation is achieved by simple filtration followed by removal of the solvent. In selected examples this reagent was compared with the known polymer-bound permanganate and chromium(VI) reagents.
AB - formula presented A new, polymer-bound reagent system for the efficient oxidation of primary alcohols to aldehydes and secondary alcohols to ketones in the presence of a catalytic amount of 2,2,6,6-tetramethyl-1-piperidinyloxyl (TEMPO) is described. In most cases, workup of this heavy metal-free oxidation is achieved by simple filtration followed by removal of the solvent. In selected examples this reagent was compared with the known polymer-bound permanganate and chromium(VI) reagents.
UR - http://www.scopus.com/inward/record.url?scp=0001520082&partnerID=8YFLogxK
U2 - 10.1021/ol006483t
DO - 10.1021/ol006483t
M3 - Article
AN - SCOPUS:0001520082
VL - 2
SP - 3781
EP - 3784
JO - Organic Letters
JF - Organic Letters
SN - 1523-7060
IS - 24
ER -