Details
| Translated title of the contribution | Synthese des Kohlenstoffoxids C12O6 über hoch gespannte Benzine |
|---|---|
| Original language | English |
| Pages (from-to) | 4012-4014 |
| Number of pages | 3 |
| Journal | Angewandte Chemie |
| Volume | 46 |
| Issue number | 22 |
| Publication status | Published - 16 May 2007 |
Abstract
(Chemical Equation Presented) Some fine arynes: Elimination of triflate followed by [2+2] cycloaddition with ketene silyl acetals facilitates the formation of highly strained benzynes with one or two annulated cyclobutane rings. A prominent example based on this chemistry is the synthesis of the novel oxocarbon C12O6 (see structure).
Keywords
- Arynes, Carbocycles, Heterocumulenes, Oxocarbons, Strained molecules
ASJC Scopus subject areas
- Chemical Engineering(all)
- Catalysis
- Chemistry(all)
- General Chemistry
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In: Angewandte Chemie , Vol. 46, No. 22, 16.05.2007, p. 4012-4014.
Research output: Contribution to journal › Survey paper › Research › peer review
}
TY - JOUR
T1 - A new oxocarbon C12O6 via highly strained benzyne intermediates
AU - Butenschön, Holger
PY - 2007/5/16
Y1 - 2007/5/16
N2 - (Chemical Equation Presented) Some fine arynes: Elimination of triflate followed by [2+2] cycloaddition with ketene silyl acetals facilitates the formation of highly strained benzynes with one or two annulated cyclobutane rings. A prominent example based on this chemistry is the synthesis of the novel oxocarbon C12O6 (see structure).
AB - (Chemical Equation Presented) Some fine arynes: Elimination of triflate followed by [2+2] cycloaddition with ketene silyl acetals facilitates the formation of highly strained benzynes with one or two annulated cyclobutane rings. A prominent example based on this chemistry is the synthesis of the novel oxocarbon C12O6 (see structure).
KW - Arynes
KW - Carbocycles
KW - Heterocumulenes
KW - Oxocarbons
KW - Strained molecules
UR - http://www.scopus.com/inward/record.url?scp=34250766127&partnerID=8YFLogxK
U2 - 10.1002/anie.200700926
DO - 10.1002/anie.200700926
M3 - Survey paper
AN - SCOPUS:34250766127
VL - 46
SP - 4012
EP - 4014
JO - Angewandte Chemie
JF - Angewandte Chemie
SN - 1433-7851
IS - 22
ER -