A general viscosity model of Campi Flegrei (Italy) melts

Research output: Contribution to journalArticleResearchpeer review

Authors

  • V. Misiti
  • F. Vetere
  • C. Freda
  • P. Scarlato
  • H. Behrens
  • A. Mangiacapra
  • D. B. Dingwell

Research Organisations

External Research Organisations

  • Istituto Nazionale Di Geofisica E Vulcanologia, Rome
  • University of Chieti
  • Ludwig-Maximilians-Universität München (LMU)
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Details

Original languageEnglish
Pages (from-to)50-59
Number of pages10
JournalChemical geology
Volume290
Issue number1-2
Early online date9 Sept 2011
Publication statusPublished - 7 Nov 2011

Abstract

Viscosities of shoshonitic and latitic melts, relevant to the Campi Flegrei caldera magmas, have been experimentally determined at atmospheric pressure and 0.5GPa, temperatures between 840K and 1870K, and H2O contents from 0.02 to 3.30wt.%.The concentric cylinder technique was employed at atmospheric pressure to determine viscosity of nominally anhydrous melts in the viscosity range of 101.5-103Pas. The micropenetration technique was used to determine the viscosity of hydrous and anhydrous melts at atmospheric pressure in the high viscosity range (1010Pas). Falling sphere experiments were performed at 0.5GPa in the low viscosity range (from 100.35 to 102.79Pas) in order to obtain viscosity data of anhydrous and hydrous melts. The combination of data obtained from the three different techniques adopted permits a general description of viscosity as a function of temperature and water content using the following modified VFT equation:logη=-a+bT-c+dT-e·expg·wTwhere η is the viscosity in Pa·s, T the temperature in K, w the H2O content in wt.%, and a, b, c, d, e, and g are the VFT parameters. This model reproduces the experimental data (95 measurements) with a 1σ standard deviation of 0.19 and 0.22 log units for shoshonite and latite, respectively. The proposed model has been applied also to a more evolved composition (trachyte) from the same area in order to create a general model applicable to the whole compositional range of Campi Flegrei products.Moreover, speed data have been used to constrain the ascent velocity of latitic, shoshonitic, and trachytic melts within dikes. Using petrological data and volcanological information (geometrical parameters of the eruptive fissure and depth of magma storage), we estimate a time scale for the ascent of melt from 9. km to 4. km depth (where deep and shallow reservoirs, respectively, are located) in the order of few minutes. Such a rapid ascent should be taken into account for the hazard assessment in the Campi Flegrei area.

Keywords

    Campi Flegrei, Concentric cylinder, Falling sphere, Latites, Micropenetration, Shoshonites

ASJC Scopus subject areas

Cite this

A general viscosity model of Campi Flegrei (Italy) melts. / Misiti, V.; Vetere, F.; Freda, C. et al.
In: Chemical geology, Vol. 290, No. 1-2, 07.11.2011, p. 50-59.

Research output: Contribution to journalArticleResearchpeer review

Misiti, V, Vetere, F, Freda, C, Scarlato, P, Behrens, H, Mangiacapra, A & Dingwell, DB 2011, 'A general viscosity model of Campi Flegrei (Italy) melts', Chemical geology, vol. 290, no. 1-2, pp. 50-59. https://doi.org/10.1016/j.chemgeo.2011.08.010
Misiti, V., Vetere, F., Freda, C., Scarlato, P., Behrens, H., Mangiacapra, A., & Dingwell, D. B. (2011). A general viscosity model of Campi Flegrei (Italy) melts. Chemical geology, 290(1-2), 50-59. https://doi.org/10.1016/j.chemgeo.2011.08.010
Misiti V, Vetere F, Freda C, Scarlato P, Behrens H, Mangiacapra A et al. A general viscosity model of Campi Flegrei (Italy) melts. Chemical geology. 2011 Nov 7;290(1-2):50-59. Epub 2011 Sept 9. doi: 10.1016/j.chemgeo.2011.08.010
Misiti, V. ; Vetere, F. ; Freda, C. et al. / A general viscosity model of Campi Flegrei (Italy) melts. In: Chemical geology. 2011 ; Vol. 290, No. 1-2. pp. 50-59.
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title = "A general viscosity model of Campi Flegrei (Italy) melts",
abstract = "Viscosities of shoshonitic and latitic melts, relevant to the Campi Flegrei caldera magmas, have been experimentally determined at atmospheric pressure and 0.5GPa, temperatures between 840K and 1870K, and H2O contents from 0.02 to 3.30wt.%.The concentric cylinder technique was employed at atmospheric pressure to determine viscosity of nominally anhydrous melts in the viscosity range of 101.5-103Pas. The micropenetration technique was used to determine the viscosity of hydrous and anhydrous melts at atmospheric pressure in the high viscosity range (1010Pas). Falling sphere experiments were performed at 0.5GPa in the low viscosity range (from 100.35 to 102.79Pas) in order to obtain viscosity data of anhydrous and hydrous melts. The combination of data obtained from the three different techniques adopted permits a general description of viscosity as a function of temperature and water content using the following modified VFT equation:logη=-a+bT-c+dT-e·expg·wTwhere η is the viscosity in Pa·s, T the temperature in K, w the H2O content in wt.%, and a, b, c, d, e, and g are the VFT parameters. This model reproduces the experimental data (95 measurements) with a 1σ standard deviation of 0.19 and 0.22 log units for shoshonite and latite, respectively. The proposed model has been applied also to a more evolved composition (trachyte) from the same area in order to create a general model applicable to the whole compositional range of Campi Flegrei products.Moreover, speed data have been used to constrain the ascent velocity of latitic, shoshonitic, and trachytic melts within dikes. Using petrological data and volcanological information (geometrical parameters of the eruptive fissure and depth of magma storage), we estimate a time scale for the ascent of melt from 9. km to 4. km depth (where deep and shallow reservoirs, respectively, are located) in the order of few minutes. Such a rapid ascent should be taken into account for the hazard assessment in the Campi Flegrei area.",
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T1 - A general viscosity model of Campi Flegrei (Italy) melts

AU - Misiti, V.

AU - Vetere, F.

AU - Freda, C.

AU - Scarlato, P.

AU - Behrens, H.

AU - Mangiacapra, A.

AU - Dingwell, D. B.

N1 - Funding Information: This work has been supported by the INGV-DPC Project V1-UNREST , by the EU Volcanic Dynamics Research and Training Network , and by the German Science Foundation (funding came from a project related to the drilling in the Campi Flegrei). We would like also to thank O. Diedrich for FTIR sample preparations.

PY - 2011/11/7

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N2 - Viscosities of shoshonitic and latitic melts, relevant to the Campi Flegrei caldera magmas, have been experimentally determined at atmospheric pressure and 0.5GPa, temperatures between 840K and 1870K, and H2O contents from 0.02 to 3.30wt.%.The concentric cylinder technique was employed at atmospheric pressure to determine viscosity of nominally anhydrous melts in the viscosity range of 101.5-103Pas. The micropenetration technique was used to determine the viscosity of hydrous and anhydrous melts at atmospheric pressure in the high viscosity range (1010Pas). Falling sphere experiments were performed at 0.5GPa in the low viscosity range (from 100.35 to 102.79Pas) in order to obtain viscosity data of anhydrous and hydrous melts. The combination of data obtained from the three different techniques adopted permits a general description of viscosity as a function of temperature and water content using the following modified VFT equation:logη=-a+bT-c+dT-e·expg·wTwhere η is the viscosity in Pa·s, T the temperature in K, w the H2O content in wt.%, and a, b, c, d, e, and g are the VFT parameters. This model reproduces the experimental data (95 measurements) with a 1σ standard deviation of 0.19 and 0.22 log units for shoshonite and latite, respectively. The proposed model has been applied also to a more evolved composition (trachyte) from the same area in order to create a general model applicable to the whole compositional range of Campi Flegrei products.Moreover, speed data have been used to constrain the ascent velocity of latitic, shoshonitic, and trachytic melts within dikes. Using petrological data and volcanological information (geometrical parameters of the eruptive fissure and depth of magma storage), we estimate a time scale for the ascent of melt from 9. km to 4. km depth (where deep and shallow reservoirs, respectively, are located) in the order of few minutes. Such a rapid ascent should be taken into account for the hazard assessment in the Campi Flegrei area.

AB - Viscosities of shoshonitic and latitic melts, relevant to the Campi Flegrei caldera magmas, have been experimentally determined at atmospheric pressure and 0.5GPa, temperatures between 840K and 1870K, and H2O contents from 0.02 to 3.30wt.%.The concentric cylinder technique was employed at atmospheric pressure to determine viscosity of nominally anhydrous melts in the viscosity range of 101.5-103Pas. The micropenetration technique was used to determine the viscosity of hydrous and anhydrous melts at atmospheric pressure in the high viscosity range (1010Pas). Falling sphere experiments were performed at 0.5GPa in the low viscosity range (from 100.35 to 102.79Pas) in order to obtain viscosity data of anhydrous and hydrous melts. The combination of data obtained from the three different techniques adopted permits a general description of viscosity as a function of temperature and water content using the following modified VFT equation:logη=-a+bT-c+dT-e·expg·wTwhere η is the viscosity in Pa·s, T the temperature in K, w the H2O content in wt.%, and a, b, c, d, e, and g are the VFT parameters. This model reproduces the experimental data (95 measurements) with a 1σ standard deviation of 0.19 and 0.22 log units for shoshonite and latite, respectively. The proposed model has been applied also to a more evolved composition (trachyte) from the same area in order to create a general model applicable to the whole compositional range of Campi Flegrei products.Moreover, speed data have been used to constrain the ascent velocity of latitic, shoshonitic, and trachytic melts within dikes. Using petrological data and volcanological information (geometrical parameters of the eruptive fissure and depth of magma storage), we estimate a time scale for the ascent of melt from 9. km to 4. km depth (where deep and shallow reservoirs, respectively, are located) in the order of few minutes. Such a rapid ascent should be taken into account for the hazard assessment in the Campi Flegrei area.

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