Details
| Original language | English |
|---|---|
| Pages (from-to) | 1693-1696 |
| Number of pages | 4 |
| Journal | Tetrahedron letters |
| Volume | 25 |
| Issue number | 16 |
| Publication status | Published - 1984 |
| Externally published | Yes |
Abstract
Trihalotriquinacenes 3 react with secondary amines to yield 4,7-bis(dialkylamino)dihydroacepentalenes 4. Upon reduction with sodium the tetraenes 4 apparently form radical anion intermediates 5 which disproportionate to tris(dialkylamino)trienyl anions 6 and possibly acepentalenediide 2.
ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)
- Biochemistry
- Pharmacology, Toxicology and Pharmaceutics(all)
- Drug Discovery
- Chemistry(all)
- Organic Chemistry
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In: Tetrahedron letters, Vol. 25, No. 16, 1984, p. 1693-1696.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - 4,7-Bisdialkylaminotricyclo[5.2.1.04,10]deca-110,2,5,8- tetraenes as potential precursors to acepentalenediide
AU - Butenschön, Holger
AU - Meijere, Armin de
N1 - Funding information: This work was supported by the Stiftung Chemischen Industrie, the Hoechst AG and the Studienstiftung schen Volkes (Holger Butenschön).
PY - 1984
Y1 - 1984
N2 - Trihalotriquinacenes 3 react with secondary amines to yield 4,7-bis(dialkylamino)dihydroacepentalenes 4. Upon reduction with sodium the tetraenes 4 apparently form radical anion intermediates 5 which disproportionate to tris(dialkylamino)trienyl anions 6 and possibly acepentalenediide 2.
AB - Trihalotriquinacenes 3 react with secondary amines to yield 4,7-bis(dialkylamino)dihydroacepentalenes 4. Upon reduction with sodium the tetraenes 4 apparently form radical anion intermediates 5 which disproportionate to tris(dialkylamino)trienyl anions 6 and possibly acepentalenediide 2.
UR - http://www.scopus.com/inward/record.url?scp=18944372929&partnerID=8YFLogxK
U2 - 10.1016/S0040-4039(01)81146-1
DO - 10.1016/S0040-4039(01)81146-1
M3 - Article
AN - SCOPUS:18944372929
VL - 25
SP - 1693
EP - 1696
JO - Tetrahedron letters
JF - Tetrahedron letters
SN - 0040-4039
IS - 16
ER -