Weak CH⋯F bridges and internal dynamics in the CH 3F·CHF3 molecular complex

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Autoren

  • Walther Caminati
  • Juan C. López
  • José L. Alonso
  • Jens Uwe Grabow

Organisationseinheiten

Externe Organisationen

  • Università di Bologna
  • Universidad de Valladolid
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)3840-3844
Seitenumfang5
FachzeitschriftAngewandte Chemie - International Edition
Jahrgang44
Ausgabenummer25
Frühes Online-Datum2 Mai 2005
PublikationsstatusVeröffentlicht - 10 Juni 2005

Abstract

A preferred conformation of the internally highly dynamic fluoromethane-trifluoromethane molecular complex results from the stabilization of the two subunits by three weak CH⋯F hydrogen bonds and electrostatic dipole-dipole interactions (see picture). The two subunits are not rigidly locked, but exhibit large amplitude motions by almost freely spinning around their symmetry axes as shown. (Chemical Equation Presented)

ASJC Scopus Sachgebiete

Zitieren

Weak CH⋯F bridges and internal dynamics in the CH 3F·CHF3 molecular complex. / Caminati, Walther; López, Juan C.; Alonso, José L. et al.
in: Angewandte Chemie - International Edition, Jahrgang 44, Nr. 25, 10.06.2005, S. 3840-3844.

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Caminati W, López JC, Alonso JL, Grabow JU. Weak CH⋯F bridges and internal dynamics in the CH 3F·CHF3 molecular complex. Angewandte Chemie - International Edition. 2005 Jun 10;44(25):3840-3844. Epub 2005 Mai 2. doi: 10.1002/anie.200500775
Caminati, Walther ; López, Juan C. ; Alonso, José L. et al. / Weak CH⋯F bridges and internal dynamics in the CH 3F·CHF3 molecular complex. in: Angewandte Chemie - International Edition. 2005 ; Jahrgang 44, Nr. 25. S. 3840-3844.
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