Wall-slip effects and their dependence on the recipe- and molecular-weight-induced compound viscosity

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • B. Klie
  • E. Schubert
  • U. Giese

Externe Organisationen

  • Deutsches Institut für Kautschuktechnologie e.V. (DIK)
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)35-43
Seitenumfang9
FachzeitschriftKGK Kautschuk Gummi Kunststoffe
Jahrgang72
Ausgabenummer3
PublikationsstatusVeröffentlicht - März 2019
Extern publiziertJa

Abstract

Employing a high-pressure capillary viscometer, this study investigates the flow behavior of rubber compounds as a function of compound viscosity. Test series are carried out with EPDM rubbers and additionally, the compound viscosity of a low-molecular-weight EPDM is selectively varied by admixing different concentrations of carbon black or oil so as to shed light on the influence of recipe-dependent viscosity on the wall-slip effect. The results show that the wall-slip effect increases as the recipe-dependent viscosity and the molecular weight of the raw polymer rise and that the critical wall shear stress indicating supercritical flow behavior is achieved even at lower shear rates.

ASJC Scopus Sachgebiete

Zitieren

Wall-slip effects and their dependence on the recipe- and molecular-weight-induced compound viscosity. / Klie, B.; Schubert, E.; Giese, U.
in: KGK Kautschuk Gummi Kunststoffe, Jahrgang 72, Nr. 3, 03.2019, S. 35-43.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

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Download

TY - JOUR

T1 - Wall-slip effects and their dependence on the recipe- and molecular-weight-induced compound viscosity

AU - Klie, B.

AU - Schubert, E.

AU - Giese, U.

PY - 2019/3

Y1 - 2019/3

N2 - Employing a high-pressure capillary viscometer, this study investigates the flow behavior of rubber compounds as a function of compound viscosity. Test series are carried out with EPDM rubbers and additionally, the compound viscosity of a low-molecular-weight EPDM is selectively varied by admixing different concentrations of carbon black or oil so as to shed light on the influence of recipe-dependent viscosity on the wall-slip effect. The results show that the wall-slip effect increases as the recipe-dependent viscosity and the molecular weight of the raw polymer rise and that the critical wall shear stress indicating supercritical flow behavior is achieved even at lower shear rates.

AB - Employing a high-pressure capillary viscometer, this study investigates the flow behavior of rubber compounds as a function of compound viscosity. Test series are carried out with EPDM rubbers and additionally, the compound viscosity of a low-molecular-weight EPDM is selectively varied by admixing different concentrations of carbon black or oil so as to shed light on the influence of recipe-dependent viscosity on the wall-slip effect. The results show that the wall-slip effect increases as the recipe-dependent viscosity and the molecular weight of the raw polymer rise and that the critical wall shear stress indicating supercritical flow behavior is achieved even at lower shear rates.

KW - Compound viscosity

KW - EPDM

KW - Highpressure capillary viscometer (HCV)

KW - Rheology

KW - Rubber extrusion

KW - Slip-stick

KW - Wall slip

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JO - KGK Kautschuk Gummi Kunststoffe

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