Using high-resolution XRF analyses as a sequence stratigraphic tool in a mudstone-dominated succession (Early Cretaceous, Lower Saxony Basin, Northern Germany)

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • Hauke Thöle
  • André Bornemann
  • Ulrich Heimhofer
  • Friedrich Wilhelm Luppold
  • Martin Blumenberg
  • Reiner Dohrmann
  • Jochen Erbacher

Externe Organisationen

  • Bundesanstalt für Geowissenschaften und Rohstoffe (BGR)
  • Landesamt für Bergbau, Energie und Geologie (LBEG)
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Details

OriginalspracheEnglisch
Seiten (von - bis)236-258
Seitenumfang23
FachzeitschriftThe Depositional Record
Jahrgang6
Ausgabenummer1
Frühes Online-Datum25 Juli 2019
PublikationsstatusVeröffentlicht - 5 Feb. 2020

Abstract

Delineation of stratigraphic sequences and their component systems tracts in mudstone-dominated successions is challenging due to the relatively homogenous, fine-grained nature of the strata. High-resolution elemental intensity data from X-ray fluorescence core scanning is used in order to develop a sequence stratigraphic framework for the Lower Cretaceous monotonous mudstone succession in the eastern Lower Saxony Basin. The study is based on four drill cores covering the Berriasian to Aptian interval. In addition, carbon isotope (δ13Corg), grain size and CaCO3 analyses were carried out on discrete samples. The studied cores represent both proximal and distal basinal environments of the eastern Lower Saxony Basin and can be reliably correlated by utilizing variations in selected X-ray flourescence elemental ratios, K/Ti data have proven to be particularly suitable in this regard. The core correlation shows that chemostratigraphic variability within the studied succession is laterally reproducible in the eastern Lower Saxony Basin, and can be used to establish a sequence stratigraphic framework. Further, Si/Al and Ca/Ti ratios have been applied to characterize the cores in terms of variation in grain size and CaCO3 content, respectively. Vertical grading trends inferred from Si/Al changes were used to identify transgressive and regressive systems tracts within the studied succession. An important regression in the uppermost lower Valanginian coincides with the onset of the Valanginian Weissert Event, as indicated by the well-known positive δ13C shift, and, thus, supports the idea that the initial interval of this event corresponds to enhanced supply of terrigenous material. The results of this study are also in agreement with previously recognized transgressive–regressive trends in the Lower Saxony Basin and adjacent areas. This clearly shows that systematic geochemical variations recorded in mudstone-dominated basinal settings are suitable to establish sequence stratigraphic frameworks.

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Using high-resolution XRF analyses as a sequence stratigraphic tool in a mudstone-dominated succession (Early Cretaceous, Lower Saxony Basin, Northern Germany). / Thöle, Hauke; Bornemann, André; Heimhofer, Ulrich et al.
in: The Depositional Record, Jahrgang 6, Nr. 1, 05.02.2020, S. 236-258.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Thöle, H, Bornemann, A, Heimhofer, U, Luppold, FW, Blumenberg, M, Dohrmann, R & Erbacher, J 2020, 'Using high-resolution XRF analyses as a sequence stratigraphic tool in a mudstone-dominated succession (Early Cretaceous, Lower Saxony Basin, Northern Germany)', The Depositional Record, Jg. 6, Nr. 1, S. 236-258. https://doi.org/10.1002/dep2.83
Thöle, H., Bornemann, A., Heimhofer, U., Luppold, F. W., Blumenberg, M., Dohrmann, R., & Erbacher, J. (2020). Using high-resolution XRF analyses as a sequence stratigraphic tool in a mudstone-dominated succession (Early Cretaceous, Lower Saxony Basin, Northern Germany). The Depositional Record, 6(1), 236-258. https://doi.org/10.1002/dep2.83
Thöle H, Bornemann A, Heimhofer U, Luppold FW, Blumenberg M, Dohrmann R et al. Using high-resolution XRF analyses as a sequence stratigraphic tool in a mudstone-dominated succession (Early Cretaceous, Lower Saxony Basin, Northern Germany). The Depositional Record. 2020 Feb 5;6(1):236-258. Epub 2019 Jul 25. doi: 10.1002/dep2.83
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title = "Using high-resolution XRF analyses as a sequence stratigraphic tool in a mudstone-dominated succession (Early Cretaceous, Lower Saxony Basin, Northern Germany)",
abstract = "Delineation of stratigraphic sequences and their component systems tracts in mudstone-dominated successions is challenging due to the relatively homogenous, fine-grained nature of the strata. High-resolution elemental intensity data from X-ray fluorescence core scanning is used in order to develop a sequence stratigraphic framework for the Lower Cretaceous monotonous mudstone succession in the eastern Lower Saxony Basin. The study is based on four drill cores covering the Berriasian to Aptian interval. In addition, carbon isotope (δ13Corg), grain size and CaCO3 analyses were carried out on discrete samples. The studied cores represent both proximal and distal basinal environments of the eastern Lower Saxony Basin and can be reliably correlated by utilizing variations in selected X-ray flourescence elemental ratios, K/Ti data have proven to be particularly suitable in this regard. The core correlation shows that chemostratigraphic variability within the studied succession is laterally reproducible in the eastern Lower Saxony Basin, and can be used to establish a sequence stratigraphic framework. Further, Si/Al and Ca/Ti ratios have been applied to characterize the cores in terms of variation in grain size and CaCO3 content, respectively. Vertical grading trends inferred from Si/Al changes were used to identify transgressive and regressive systems tracts within the studied succession. An important regression in the uppermost lower Valanginian coincides with the onset of the Valanginian Weissert Event, as indicated by the well-known positive δ13C shift, and, thus, supports the idea that the initial interval of this event corresponds to enhanced supply of terrigenous material. The results of this study are also in agreement with previously recognized transgressive–regressive trends in the Lower Saxony Basin and adjacent areas. This clearly shows that systematic geochemical variations recorded in mudstone-dominated basinal settings are suitable to establish sequence stratigraphic frameworks.",
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note = "Funding information: This research has been funded by the Federal Institute for Geosciences and Natural Resources (BGR) in the framework of the project {\textquoteleft}Subsurface Potentials for Storage and Economic Use in the North German Basin (TUNB)'. T. Kollaske is thanked for her support during XRF?CS, G. Gr{\"u}tzner and S. St{\"a}ger for sample preparation (all BGR). We further thank two anonymous reviewers for their insightful and constructive comments.",
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AU - Thöle, Hauke

AU - Bornemann, André

AU - Heimhofer, Ulrich

AU - Luppold, Friedrich Wilhelm

AU - Blumenberg, Martin

AU - Dohrmann, Reiner

AU - Erbacher, Jochen

N1 - Funding information: This research has been funded by the Federal Institute for Geosciences and Natural Resources (BGR) in the framework of the project ‘Subsurface Potentials for Storage and Economic Use in the North German Basin (TUNB)'. T. Kollaske is thanked for her support during XRF?CS, G. Grützner and S. Stäger for sample preparation (all BGR). We further thank two anonymous reviewers for their insightful and constructive comments.

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N2 - Delineation of stratigraphic sequences and their component systems tracts in mudstone-dominated successions is challenging due to the relatively homogenous, fine-grained nature of the strata. High-resolution elemental intensity data from X-ray fluorescence core scanning is used in order to develop a sequence stratigraphic framework for the Lower Cretaceous monotonous mudstone succession in the eastern Lower Saxony Basin. The study is based on four drill cores covering the Berriasian to Aptian interval. In addition, carbon isotope (δ13Corg), grain size and CaCO3 analyses were carried out on discrete samples. The studied cores represent both proximal and distal basinal environments of the eastern Lower Saxony Basin and can be reliably correlated by utilizing variations in selected X-ray flourescence elemental ratios, K/Ti data have proven to be particularly suitable in this regard. The core correlation shows that chemostratigraphic variability within the studied succession is laterally reproducible in the eastern Lower Saxony Basin, and can be used to establish a sequence stratigraphic framework. Further, Si/Al and Ca/Ti ratios have been applied to characterize the cores in terms of variation in grain size and CaCO3 content, respectively. Vertical grading trends inferred from Si/Al changes were used to identify transgressive and regressive systems tracts within the studied succession. An important regression in the uppermost lower Valanginian coincides with the onset of the Valanginian Weissert Event, as indicated by the well-known positive δ13C shift, and, thus, supports the idea that the initial interval of this event corresponds to enhanced supply of terrigenous material. The results of this study are also in agreement with previously recognized transgressive–regressive trends in the Lower Saxony Basin and adjacent areas. This clearly shows that systematic geochemical variations recorded in mudstone-dominated basinal settings are suitable to establish sequence stratigraphic frameworks.

AB - Delineation of stratigraphic sequences and their component systems tracts in mudstone-dominated successions is challenging due to the relatively homogenous, fine-grained nature of the strata. High-resolution elemental intensity data from X-ray fluorescence core scanning is used in order to develop a sequence stratigraphic framework for the Lower Cretaceous monotonous mudstone succession in the eastern Lower Saxony Basin. The study is based on four drill cores covering the Berriasian to Aptian interval. In addition, carbon isotope (δ13Corg), grain size and CaCO3 analyses were carried out on discrete samples. The studied cores represent both proximal and distal basinal environments of the eastern Lower Saxony Basin and can be reliably correlated by utilizing variations in selected X-ray flourescence elemental ratios, K/Ti data have proven to be particularly suitable in this regard. The core correlation shows that chemostratigraphic variability within the studied succession is laterally reproducible in the eastern Lower Saxony Basin, and can be used to establish a sequence stratigraphic framework. Further, Si/Al and Ca/Ti ratios have been applied to characterize the cores in terms of variation in grain size and CaCO3 content, respectively. Vertical grading trends inferred from Si/Al changes were used to identify transgressive and regressive systems tracts within the studied succession. An important regression in the uppermost lower Valanginian coincides with the onset of the Valanginian Weissert Event, as indicated by the well-known positive δ13C shift, and, thus, supports the idea that the initial interval of this event corresponds to enhanced supply of terrigenous material. The results of this study are also in agreement with previously recognized transgressive–regressive trends in the Lower Saxony Basin and adjacent areas. This clearly shows that systematic geochemical variations recorded in mudstone-dominated basinal settings are suitable to establish sequence stratigraphic frameworks.

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