Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 1541-1542 |
| Seitenumfang | 2 |
| Fachzeitschrift | Journal of the Chemical Society, Chemical Communications |
| Ausgabenummer | 21 |
| Publikationsstatus | Veröffentlicht - 1 Dez. 1991 |
| Extern publiziert | Ja |
Abstract
An unexpected opening of a proximal bond in the anellated four-membered ring of benzocyclobutene tricarbonylchromium(0) complexes occurs when the 1-hydroxy-1-hex-5-enyl complex 2 is treated with base: in general, rupture of the distal bond is observed. The reaction of tricarbonyl-η6-(1- oxobenzocyclobutene)chromium(0) 1 with primary amines also causes a proximal ring-opening reaction.
ASJC Scopus Sachgebiete
- Biochemie, Genetik und Molekularbiologie (insg.)
- Molekularmedizin
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in: Journal of the Chemical Society, Chemical Communications, Nr. 21, 01.12.1991, S. 1541-1542.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Unexpected Proximal Ring Opening Reactions of Benzocyclobutene Complexes
AU - Brands, Michael
AU - Wey, Hans G.
AU - Butenschön, Holger
PY - 1991/12/1
Y1 - 1991/12/1
N2 - An unexpected opening of a proximal bond in the anellated four-membered ring of benzocyclobutene tricarbonylchromium(0) complexes occurs when the 1-hydroxy-1-hex-5-enyl complex 2 is treated with base: in general, rupture of the distal bond is observed. The reaction of tricarbonyl-η6-(1- oxobenzocyclobutene)chromium(0) 1 with primary amines also causes a proximal ring-opening reaction.
AB - An unexpected opening of a proximal bond in the anellated four-membered ring of benzocyclobutene tricarbonylchromium(0) complexes occurs when the 1-hydroxy-1-hex-5-enyl complex 2 is treated with base: in general, rupture of the distal bond is observed. The reaction of tricarbonyl-η6-(1- oxobenzocyclobutene)chromium(0) 1 with primary amines also causes a proximal ring-opening reaction.
UR - http://www.scopus.com/inward/record.url?scp=0026055184&partnerID=8YFLogxK
U2 - 10.1039/C39910001541
DO - 10.1039/C39910001541
M3 - Article
AN - SCOPUS:0026055184
SP - 1541
EP - 1542
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
SN - 0022-4936
IS - 21
ER -