Details
| Originalsprache | Englisch |
|---|---|
| Aufsatznummer | ss-2018-z0731-sr |
| Seiten (von - bis) | 161-177 |
| Seitenumfang | 17 |
| Fachzeitschrift | Synthesis (Germany) |
| Jahrgang | 51 |
| Ausgabenummer | 1 |
| Frühes Online-Datum | 27 Nov. 2018 |
| Publikationsstatus | Veröffentlicht - Jan. 2019 |
Abstract
Tris(acetylacetonato) iron(III) [Fe(acac) 3 ] is an indispensable reagent in synthetic chemistry. Its applications range from hydrogen atom transfer to cross-coupling reactions and to use as a Lewis acid. Consequently, the exceptional utility of Fe(acac) 3 has been demonstrated in several total syntheses. This short review summarizes the applications of Fe(acac) 3 in methodology and catalysis and highlights its use for the synthesis of medicinally relevant structures and in natural product syntheses. 1 Introduction 2 Hydrogen Atom Transfer (HAT) 3 Oxidations and Radical Transformations 4 Synthesis and Use of Alkynes and Allenes 5 Cross-Couplings and Cycloisomerizations 6 Borylations 7 Miscellaneous Reactions 8 Conclusions.
ASJC Scopus Sachgebiete
- Chemische Verfahrenstechnik (insg.)
- Katalyse
- Chemie (insg.)
- Organische Chemie
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in: Synthesis (Germany), Jahrgang 51, Nr. 1, ss-2018-z0731-sr, 01.2019, S. 161-177.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Tris(acetylacetonato) Iron(III): Recent Developments and Synthetic Applications
AU - Lübken, Dennis
AU - Saxarra, Marius
AU - Kalesse, Markus
PY - 2019/1
Y1 - 2019/1
N2 - Tris(acetylacetonato) iron(III) [Fe(acac) 3 ] is an indispensable reagent in synthetic chemistry. Its applications range from hydrogen atom transfer to cross-coupling reactions and to use as a Lewis acid. Consequently, the exceptional utility of Fe(acac) 3 has been demonstrated in several total syntheses. This short review summarizes the applications of Fe(acac) 3 in methodology and catalysis and highlights its use for the synthesis of medicinally relevant structures and in natural product syntheses. 1 Introduction 2 Hydrogen Atom Transfer (HAT) 3 Oxidations and Radical Transformations 4 Synthesis and Use of Alkynes and Allenes 5 Cross-Couplings and Cycloisomerizations 6 Borylations 7 Miscellaneous Reactions 8 Conclusions.
AB - Tris(acetylacetonato) iron(III) [Fe(acac) 3 ] is an indispensable reagent in synthetic chemistry. Its applications range from hydrogen atom transfer to cross-coupling reactions and to use as a Lewis acid. Consequently, the exceptional utility of Fe(acac) 3 has been demonstrated in several total syntheses. This short review summarizes the applications of Fe(acac) 3 in methodology and catalysis and highlights its use for the synthesis of medicinally relevant structures and in natural product syntheses. 1 Introduction 2 Hydrogen Atom Transfer (HAT) 3 Oxidations and Radical Transformations 4 Synthesis and Use of Alkynes and Allenes 5 Cross-Couplings and Cycloisomerizations 6 Borylations 7 Miscellaneous Reactions 8 Conclusions.
KW - catalysis
KW - cross-couplings
KW - Fe(acac)
KW - hydrogen atom transfer
KW - radical transformations
KW - synthetic chemistry
KW - tris(acetylacetonato) iron(III)
UR - http://www.scopus.com/inward/record.url?scp=85058518887&partnerID=8YFLogxK
U2 - 10.1055/s-0037-1610393
DO - 10.1055/s-0037-1610393
M3 - Article
AN - SCOPUS:85058518887
VL - 51
SP - 161
EP - 177
JO - Synthesis (Germany)
JF - Synthesis (Germany)
SN - 0039-7881
IS - 1
M1 - ss-2018-z0731-sr
ER -