Toward three-dimensional hybrid inorganic/organic optoelectronics based on GaN/oCVD-PEDOT structures

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Autoren

  • Linus Krieg
  • Florian Meierhofer
  • Sascha Gorny
  • Stefan Leis
  • Daniel Splith
  • Zhipeng Zhang
  • Holger von Wenckstern
  • Marius Grundmann
  • Xiaoxue Wang
  • Jana Hartmann
  • Christoph Margenfeld
  • Irene Manglano Clavero
  • Adrian Avramescu
  • Tilman Schimpke
  • Dominik Scholz
  • Hans Jürgen Lugauer
  • Martin Strassburg
  • Jörgen Jungclaus
  • Steffen Bornemann
  • Hendrik Spende
  • Andreas Waag
  • Karen K. Gleason
  • Tobias Voss

Externe Organisationen

  • Technische Universität Braunschweig
  • Universität Leipzig
  • Massachusetts Institute of Technology (MIT)
  • The Ohio State University
  • OSRAM Licht AG
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Aufsatznummer5092
FachzeitschriftNature Communications
Jahrgang11
Ausgabenummer1
PublikationsstatusVeröffentlicht - 1 Dez. 2020
Extern publiziertJa

Abstract

The combination of inorganic semiconductors with organic thin films promises new strategies for the realization of complex hybrid optoelectronic devices. Oxidative chemical vapor deposition (oCVD) of conductive polymers offers a flexible and scalable path towards high-quality three-dimensional inorganic/organic optoelectronic structures. Here, hole-conductive poly(3,4-ethylenedioxythiophene) (PEDOT) grown by oxidative chemical vapor deposition is used to fabricate transparent and conformal wrap-around p-type contacts on three-dimensional microLEDs with large aspect ratios, a yet unsolved challenge in three-dimensional gallium nitride technology. The electrical characteristics of two-dimensional reference structures confirm the quasi-metallic state of the polymer, show high rectification ratios, and exhibit excellent thermal and temporal stability. We analyze the electroluminescence from a three-dimensional hybrid microrod/polymer LED array and demonstrate its improved optical properties compared with a purely inorganic microrod LED. The findings highlight a way towards the fabrication of hybrid three-dimensional optoelectronics on the sub-micron scale.

ASJC Scopus Sachgebiete

Zitieren

Toward three-dimensional hybrid inorganic/organic optoelectronics based on GaN/oCVD-PEDOT structures. / Krieg, Linus; Meierhofer, Florian; Gorny, Sascha et al.
in: Nature Communications, Jahrgang 11, Nr. 1, 5092, 01.12.2020.

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Krieg, L, Meierhofer, F, Gorny, S, Leis, S, Splith, D, Zhang, Z, von Wenckstern, H, Grundmann, M, Wang, X, Hartmann, J, Margenfeld, C, Manglano Clavero, I, Avramescu, A, Schimpke, T, Scholz, D, Lugauer, HJ, Strassburg, M, Jungclaus, J, Bornemann, S, Spende, H, Waag, A, Gleason, KK & Voss, T 2020, 'Toward three-dimensional hybrid inorganic/organic optoelectronics based on GaN/oCVD-PEDOT structures', Nature Communications, Jg. 11, Nr. 1, 5092. https://doi.org/10.1038/s41467-020-18914-7
Krieg, L., Meierhofer, F., Gorny, S., Leis, S., Splith, D., Zhang, Z., von Wenckstern, H., Grundmann, M., Wang, X., Hartmann, J., Margenfeld, C., Manglano Clavero, I., Avramescu, A., Schimpke, T., Scholz, D., Lugauer, H. J., Strassburg, M., Jungclaus, J., Bornemann, S., ... Voss, T. (2020). Toward three-dimensional hybrid inorganic/organic optoelectronics based on GaN/oCVD-PEDOT structures. Nature Communications, 11(1), Artikel 5092. https://doi.org/10.1038/s41467-020-18914-7
Krieg L, Meierhofer F, Gorny S, Leis S, Splith D, Zhang Z et al. Toward three-dimensional hybrid inorganic/organic optoelectronics based on GaN/oCVD-PEDOT structures. Nature Communications. 2020 Dez 1;11(1):5092. doi: 10.1038/s41467-020-18914-7
Krieg, Linus ; Meierhofer, Florian ; Gorny, Sascha et al. / Toward three-dimensional hybrid inorganic/organic optoelectronics based on GaN/oCVD-PEDOT structures. in: Nature Communications. 2020 ; Jahrgang 11, Nr. 1.
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title = "Toward three-dimensional hybrid inorganic/organic optoelectronics based on GaN/oCVD-PEDOT structures",
abstract = "The combination of inorganic semiconductors with organic thin films promises new strategies for the realization of complex hybrid optoelectronic devices. Oxidative chemical vapor deposition (oCVD) of conductive polymers offers a flexible and scalable path towards high-quality three-dimensional inorganic/organic optoelectronic structures. Here, hole-conductive poly(3,4-ethylenedioxythiophene) (PEDOT) grown by oxidative chemical vapor deposition is used to fabricate transparent and conformal wrap-around p-type contacts on three-dimensional microLEDs with large aspect ratios, a yet unsolved challenge in three-dimensional gallium nitride technology. The electrical characteristics of two-dimensional reference structures confirm the quasi-metallic state of the polymer, show high rectification ratios, and exhibit excellent thermal and temporal stability. We analyze the electroluminescence from a three-dimensional hybrid microrod/polymer LED array and demonstrate its improved optical properties compared with a purely inorganic microrod LED. The findings highlight a way towards the fabrication of hybrid three-dimensional optoelectronics on the sub-micron scale.",
author = "Linus Krieg and Florian Meierhofer and Sascha Gorny and Stefan Leis and Daniel Splith and Zhipeng Zhang and {von Wenckstern}, Holger and Marius Grundmann and Xiaoxue Wang and Jana Hartmann and Christoph Margenfeld and {Manglano Clavero}, Irene and Adrian Avramescu and Tilman Schimpke and Dominik Scholz and Lugauer, {Hans J{\"u}rgen} and Martin Strassburg and J{\"o}rgen Jungclaus and Steffen Bornemann and Hendrik Spende and Andreas Waag and Gleason, {Karen K.} and Tobias Voss",
note = "Funding information: We thank Klaas Strempel for ECV measurements and Maike R{\"u}hmann and Juliane Breitfelder for the processing and lithography of the samples. We acknowledge financial support from “Nieders{\"a}chsisches Vorab” through “Quantum-and Nano-Metrology (QUANOMET)” initiative within the project NL-3 “Sensors” and NP-3 “Modell-Nanopartikel.” We gratefully acknowledge support by the Deutsche For-schungsgemeinschaft (DFG, German Research Foundation) Research Training Group GrK1952/1 “Metrology for Complex Nanosystems” and the Braunschweig International Graduate School of Metrology B-IGSM. This work has been supported by the DFG within the research unit FOR1616 and funded by the DFG under Germany{\textquoteright}s Excellence Strategy—EXC-2123 QuantumFrontiers—390837967. We acknowledge financial support from the epitaxy competence center ec2. M.G., H.v.W., and D.S. acknowledge funding by the European Social Fund within the Young Investigator Group “Oxide Hetero-structures” (SAB 100310460).",
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T1 - Toward three-dimensional hybrid inorganic/organic optoelectronics based on GaN/oCVD-PEDOT structures

AU - Krieg, Linus

AU - Meierhofer, Florian

AU - Gorny, Sascha

AU - Leis, Stefan

AU - Splith, Daniel

AU - Zhang, Zhipeng

AU - von Wenckstern, Holger

AU - Grundmann, Marius

AU - Wang, Xiaoxue

AU - Hartmann, Jana

AU - Margenfeld, Christoph

AU - Manglano Clavero, Irene

AU - Avramescu, Adrian

AU - Schimpke, Tilman

AU - Scholz, Dominik

AU - Lugauer, Hans Jürgen

AU - Strassburg, Martin

AU - Jungclaus, Jörgen

AU - Bornemann, Steffen

AU - Spende, Hendrik

AU - Waag, Andreas

AU - Gleason, Karen K.

AU - Voss, Tobias

N1 - Funding information: We thank Klaas Strempel for ECV measurements and Maike Rühmann and Juliane Breitfelder for the processing and lithography of the samples. We acknowledge financial support from “Niedersächsisches Vorab” through “Quantum-and Nano-Metrology (QUANOMET)” initiative within the project NL-3 “Sensors” and NP-3 “Modell-Nanopartikel.” We gratefully acknowledge support by the Deutsche For-schungsgemeinschaft (DFG, German Research Foundation) Research Training Group GrK1952/1 “Metrology for Complex Nanosystems” and the Braunschweig International Graduate School of Metrology B-IGSM. This work has been supported by the DFG within the research unit FOR1616 and funded by the DFG under Germany’s Excellence Strategy—EXC-2123 QuantumFrontiers—390837967. We acknowledge financial support from the epitaxy competence center ec2. M.G., H.v.W., and D.S. acknowledge funding by the European Social Fund within the Young Investigator Group “Oxide Hetero-structures” (SAB 100310460).

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Y1 - 2020/12/1

N2 - The combination of inorganic semiconductors with organic thin films promises new strategies for the realization of complex hybrid optoelectronic devices. Oxidative chemical vapor deposition (oCVD) of conductive polymers offers a flexible and scalable path towards high-quality three-dimensional inorganic/organic optoelectronic structures. Here, hole-conductive poly(3,4-ethylenedioxythiophene) (PEDOT) grown by oxidative chemical vapor deposition is used to fabricate transparent and conformal wrap-around p-type contacts on three-dimensional microLEDs with large aspect ratios, a yet unsolved challenge in three-dimensional gallium nitride technology. The electrical characteristics of two-dimensional reference structures confirm the quasi-metallic state of the polymer, show high rectification ratios, and exhibit excellent thermal and temporal stability. We analyze the electroluminescence from a three-dimensional hybrid microrod/polymer LED array and demonstrate its improved optical properties compared with a purely inorganic microrod LED. The findings highlight a way towards the fabrication of hybrid three-dimensional optoelectronics on the sub-micron scale.

AB - The combination of inorganic semiconductors with organic thin films promises new strategies for the realization of complex hybrid optoelectronic devices. Oxidative chemical vapor deposition (oCVD) of conductive polymers offers a flexible and scalable path towards high-quality three-dimensional inorganic/organic optoelectronic structures. Here, hole-conductive poly(3,4-ethylenedioxythiophene) (PEDOT) grown by oxidative chemical vapor deposition is used to fabricate transparent and conformal wrap-around p-type contacts on three-dimensional microLEDs with large aspect ratios, a yet unsolved challenge in three-dimensional gallium nitride technology. The electrical characteristics of two-dimensional reference structures confirm the quasi-metallic state of the polymer, show high rectification ratios, and exhibit excellent thermal and temporal stability. We analyze the electroluminescence from a three-dimensional hybrid microrod/polymer LED array and demonstrate its improved optical properties compared with a purely inorganic microrod LED. The findings highlight a way towards the fabrication of hybrid three-dimensional optoelectronics on the sub-micron scale.

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