Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 479-482 |
| Seitenumfang | 4 |
| Fachzeitschrift | Organic Letters |
| Jahrgang | 7 |
| Ausgabenummer | 3 |
| Publikationsstatus | Veröffentlicht - 13 Jan. 2005 |
Abstract
(Chemical Equation Presented) The first enantioselective total synthesis of tonantzitlolone, a novel 15-membered macrocyclic diterpene, utilized a Julia olefination, a highly selective, potassium enolate-based anti-Felkin aldol reaction, and an E-selective ring-closing metathesis as key C-C bond-forming steps. The absolute configuration of tonantzitlolone is established.
ASJC Scopus Sachgebiete
- Biochemie, Genetik und Molekularbiologie (insg.)
- Biochemie
- Chemie (insg.)
- Physikalische und Theoretische Chemie
- Chemie (insg.)
- Organische Chemie
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in: Organic Letters, Jahrgang 7, Nr. 3, 13.01.2005, S. 479-482.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Total synthesis and elucidation of the absolute configuration of the diterpene tonantzitlolone
AU - Jasper, Christian
AU - Wittenberg, Rüdiger
AU - Quitschalle, Monika
AU - Jakupovic, Jasmin
AU - Kirschning, Andreas
PY - 2005/1/13
Y1 - 2005/1/13
N2 - (Chemical Equation Presented) The first enantioselective total synthesis of tonantzitlolone, a novel 15-membered macrocyclic diterpene, utilized a Julia olefination, a highly selective, potassium enolate-based anti-Felkin aldol reaction, and an E-selective ring-closing metathesis as key C-C bond-forming steps. The absolute configuration of tonantzitlolone is established.
AB - (Chemical Equation Presented) The first enantioselective total synthesis of tonantzitlolone, a novel 15-membered macrocyclic diterpene, utilized a Julia olefination, a highly selective, potassium enolate-based anti-Felkin aldol reaction, and an E-selective ring-closing metathesis as key C-C bond-forming steps. The absolute configuration of tonantzitlolone is established.
UR - http://www.scopus.com/inward/record.url?scp=13844272566&partnerID=8YFLogxK
UR - https://pubs.acs.org/doi/10.1021/ol0504401
U2 - 10.1021/ol047559e
DO - 10.1021/ol047559e
M3 - Article
C2 - 15673269
AN - SCOPUS:13844272566
VL - 7
SP - 479
EP - 482
JO - Organic Letters
JF - Organic Letters
SN - 1523-7060
IS - 3
ER -