Thermodynamic view on the loss mechanisms in PEM-fuel cells

Publikation: Beitrag in Buch/Bericht/Sammelwerk/KonferenzbandAufsatz in KonferenzbandForschungPeer-Review

Autoren

  • S. Kabelac
  • M. Siemer

Externe Organisationen

  • Helmut-Schmidt-Universität/Universität der Bundeswehr Hamburg
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Titel des SammelwerksASME 2005 Summer Heat Transfer Conference collocated with the ASME 2005 Pacific Rim Technical Conference and Exhibition on Integration and Packaging of MEMS, NEMS, and Electronic Systems
Untertitel3rd International Conference on Fuel Cell Science, Engineering and Technology. Ypsilanti, Michigan, USA. May 23–25, 2005
Herausgeber (Verlag)American Society of Mechanical Engineers(ASME)
Seiten405-411
Seitenumfang7
ISBN (Print)0791837645, 9780791837641
PublikationsstatusVeröffentlicht - 2005
Extern publiziertJa
Veranstaltung3rd International Conference on Fuel Cell Science, Engineering and Technology - Ypsilanti, MI, USA / Vereinigte Staaten
Dauer: 23 Mai 200525 Mai 2005
Konferenznummer: 3

Abstract

The fuel cell, which is a highly promising candidate for high efficiency energy conversion, is not reaching expected conversion efficiencies of η > 0,5 yet. Parallel to standard explanations of loss mechanisms by means of overvoltages, a thermodynamic view of addressing irreversibilities by calculating local entropy production rates is helpful. Entropy production rates are calculated by multiplying local transport fluxes with appropriate driving forces, i.e., gradients of temperature, chemical potentials and electric potentials. These gradients have to be calculated by solving the set of constitutive balance equations. Before this tedious task is done, simplified model equations have to be used. The reversible fuel cell is the starting point of analysis. Results for a one-dimensional PEM-FC are shown.

ASJC Scopus Sachgebiete

Zitieren

Thermodynamic view on the loss mechanisms in PEM-fuel cells. / Kabelac, S.; Siemer, M.
ASME 2005 Summer Heat Transfer Conference collocated with the ASME 2005 Pacific Rim Technical Conference and Exhibition on Integration and Packaging of MEMS, NEMS, and Electronic Systems: 3rd International Conference on Fuel Cell Science, Engineering and Technology. Ypsilanti, Michigan, USA. May 23–25, 2005. American Society of Mechanical Engineers(ASME), 2005. S. 405-411 FUELCELL2005-74071.

Publikation: Beitrag in Buch/Bericht/Sammelwerk/KonferenzbandAufsatz in KonferenzbandForschungPeer-Review

Kabelac, S & Siemer, M 2005, Thermodynamic view on the loss mechanisms in PEM-fuel cells. in ASME 2005 Summer Heat Transfer Conference collocated with the ASME 2005 Pacific Rim Technical Conference and Exhibition on Integration and Packaging of MEMS, NEMS, and Electronic Systems: 3rd International Conference on Fuel Cell Science, Engineering and Technology. Ypsilanti, Michigan, USA. May 23–25, 2005., FUELCELL2005-74071, American Society of Mechanical Engineers(ASME), S. 405-411, 3rd International Conference on Fuel Cell Science, Engineering and Technology, Ypsilanti, MI, Michigan, USA / Vereinigte Staaten, 23 Mai 2005. https://doi.org/10.1115/fuelcell2005-74071
Kabelac, S., & Siemer, M. (2005). Thermodynamic view on the loss mechanisms in PEM-fuel cells. In ASME 2005 Summer Heat Transfer Conference collocated with the ASME 2005 Pacific Rim Technical Conference and Exhibition on Integration and Packaging of MEMS, NEMS, and Electronic Systems: 3rd International Conference on Fuel Cell Science, Engineering and Technology. Ypsilanti, Michigan, USA. May 23–25, 2005 (S. 405-411). Artikel FUELCELL2005-74071 American Society of Mechanical Engineers(ASME). https://doi.org/10.1115/fuelcell2005-74071
Kabelac S, Siemer M. Thermodynamic view on the loss mechanisms in PEM-fuel cells. in ASME 2005 Summer Heat Transfer Conference collocated with the ASME 2005 Pacific Rim Technical Conference and Exhibition on Integration and Packaging of MEMS, NEMS, and Electronic Systems: 3rd International Conference on Fuel Cell Science, Engineering and Technology. Ypsilanti, Michigan, USA. May 23–25, 2005. American Society of Mechanical Engineers(ASME). 2005. S. 405-411. FUELCELL2005-74071 doi: 10.1115/fuelcell2005-74071
Kabelac, S. ; Siemer, M. / Thermodynamic view on the loss mechanisms in PEM-fuel cells. ASME 2005 Summer Heat Transfer Conference collocated with the ASME 2005 Pacific Rim Technical Conference and Exhibition on Integration and Packaging of MEMS, NEMS, and Electronic Systems: 3rd International Conference on Fuel Cell Science, Engineering and Technology. Ypsilanti, Michigan, USA. May 23–25, 2005. American Society of Mechanical Engineers(ASME), 2005. S. 405-411
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abstract = "The fuel cell, which is a highly promising candidate for high efficiency energy conversion, is not reaching expected conversion efficiencies of η > 0,5 yet. Parallel to standard explanations of loss mechanisms by means of overvoltages, a thermodynamic view of addressing irreversibilities by calculating local entropy production rates is helpful. Entropy production rates are calculated by multiplying local transport fluxes with appropriate driving forces, i.e., gradients of temperature, chemical potentials and electric potentials. These gradients have to be calculated by solving the set of constitutive balance equations. Before this tedious task is done, simplified model equations have to be used. The reversible fuel cell is the starting point of analysis. Results for a one-dimensional PEM-FC are shown.",
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