Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 597-599 |
| Seitenumfang | 3 |
| Fachzeitschrift | Angewandte Chemie - International Edition |
| Jahrgang | 47 |
| Ausgabenummer | 3 |
| Publikationsstatus | Veröffentlicht - 2008 |
Abstract
(Chemical Equation Presented) Stacking the deck: The natural product chloronitril A contains an unprecedented motif in which a CCl2 unit in a 14-membered macrolide framework is flanked by two carbonyl groups. In the first total synthesis of chlorotonil A a highly selective intramolecular Diels-Alder reaction was employed to generate the decalin system.
ASJC Scopus Sachgebiete
- Chemische Verfahrenstechnik (insg.)
- Katalyse
- Chemie (insg.)
- Allgemeine Chemie
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in: Angewandte Chemie - International Edition, Jahrgang 47, Nr. 3, 2008, S. 597-599.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - The total synthesis of chlorotonil A
AU - Rahn, Nicola
AU - Kalesse, Markus
PY - 2008
Y1 - 2008
N2 - (Chemical Equation Presented) Stacking the deck: The natural product chloronitril A contains an unprecedented motif in which a CCl2 unit in a 14-membered macrolide framework is flanked by two carbonyl groups. In the first total synthesis of chlorotonil A a highly selective intramolecular Diels-Alder reaction was employed to generate the decalin system.
AB - (Chemical Equation Presented) Stacking the deck: The natural product chloronitril A contains an unprecedented motif in which a CCl2 unit in a 14-membered macrolide framework is flanked by two carbonyl groups. In the first total synthesis of chlorotonil A a highly selective intramolecular Diels-Alder reaction was employed to generate the decalin system.
KW - Chlorotonil
KW - Cross-coupling
KW - Cycloaddition
KW - Olefination
KW - Total synthesis
UR - http://www.scopus.com/inward/record.url?scp=38949192053&partnerID=8YFLogxK
U2 - 10.1002/anie.200703930
DO - 10.1002/anie.200703930
M3 - Article
C2 - 18041801
AN - SCOPUS:38949192053
VL - 47
SP - 597
EP - 599
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 3
ER -