The Rotational Spectrum of the Fluorobenzene-Argon Van der Waals Complex

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • W. Stahl
  • J. U. Grabow

Externe Organisationen

  • Christian-Albrechts-Universität zu Kiel (CAU)
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)681-684
Seitenumfang4
FachzeitschriftZeitschrift fur Naturforschung - Section A Journal of Physical Sciences
Jahrgang47
Ausgabenummer5
PublikationsstatusVeröffentlicht - 1 Mai 1992

Abstract

The rotational spectrum of the fluorobenzene-argon complex has been studied in the microwave region between 7 and 18 GHz using a pulsed molecular beam microwave Fourier transform spectrometer. The rotational constants were found to be A = 1811.81369(11) MHz, B= 1105.12965(15) MHz, C = 901.84281 (5) MHz, the centrifugal distortion constants are ΔJ= 2.6886(17) kHz, ΔJK = 8.3761 (52) kHz ΔK = -8.278(5) kHz, δJ=0.65993(72) kHz, and δK= 6.013(11) kHz. The argon atom is placed 3.55 A above the ring plane.

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The Rotational Spectrum of the Fluorobenzene-Argon Van der Waals Complex. / Stahl, W.; Grabow, J. U.
in: Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, Jahrgang 47, Nr. 5, 01.05.1992, S. 681-684.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

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abstract = "The rotational spectrum of the fluorobenzene-argon complex has been studied in the microwave region between 7 and 18 GHz using a pulsed molecular beam microwave Fourier transform spectrometer. The rotational constants were found to be A = 1811.81369(11) MHz, B= 1105.12965(15) MHz, C = 901.84281 (5) MHz, the centrifugal distortion constants are ΔJ= 2.6886(17) kHz, ΔJK = 8.3761 (52) kHz ΔK = -8.278(5) kHz, δJ=0.65993(72) kHz, and δK= 6.013(11) kHz. The argon atom is placed 3.55 A above the ring plane.",
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Download

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T1 - The Rotational Spectrum of the Fluorobenzene-Argon Van der Waals Complex

AU - Stahl, W.

AU - Grabow, J. U.

N1 - Funding Information: We thank Prof. Dr. H. Dreizler for critically reading the manuscript. Funds from the Deutsche Forschungs-gemeinschaft, the Land Schleswig-Holstein, and the Fonds der Chemischen Industrie are gratefully acknowledged.

PY - 1992/5/1

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N2 - The rotational spectrum of the fluorobenzene-argon complex has been studied in the microwave region between 7 and 18 GHz using a pulsed molecular beam microwave Fourier transform spectrometer. The rotational constants were found to be A = 1811.81369(11) MHz, B= 1105.12965(15) MHz, C = 901.84281 (5) MHz, the centrifugal distortion constants are ΔJ= 2.6886(17) kHz, ΔJK = 8.3761 (52) kHz ΔK = -8.278(5) kHz, δJ=0.65993(72) kHz, and δK= 6.013(11) kHz. The argon atom is placed 3.55 A above the ring plane.

AB - The rotational spectrum of the fluorobenzene-argon complex has been studied in the microwave region between 7 and 18 GHz using a pulsed molecular beam microwave Fourier transform spectrometer. The rotational constants were found to be A = 1811.81369(11) MHz, B= 1105.12965(15) MHz, C = 901.84281 (5) MHz, the centrifugal distortion constants are ΔJ= 2.6886(17) kHz, ΔJK = 8.3761 (52) kHz ΔK = -8.278(5) kHz, δJ=0.65993(72) kHz, and δK= 6.013(11) kHz. The argon atom is placed 3.55 A above the ring plane.

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