The Microwave Spectrum and Dipole Moment of Hexafluoropropanone

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • J. U. Grabow
  • N. Heineking
  • W. Stahl

Externe Organisationen

  • Christian-Albrechts-Universität zu Kiel (CAU)
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)229-232
Seitenumfang4
FachzeitschriftZeitschrift fur Naturforschung - Section A Journal of Physical Sciences
Jahrgang46
Ausgabenummer3
PublikationsstatusVeröffentlicht - 1 März 1991

Abstract

We recorded the microwave spectrum of hexafluoropropanone between 7 and 15 GHz using a pulsed molecular beam microwave Fourier transform spectrometer. The rotational constants were determined to be A =2181.71980(14) MHz, B= 1037.22930(7) MHz, C = 934.89233(8) MHz, the quartic centrifugal distortion constants are D1j = 0.07378(39) kHz, D'JK= 0.10002(75) kHz, D'K = -0.07269(266) kHz, σ'J = 0.00623(29) kHz and R'6= 0.00755(12) kHz. Stark effect measurements yielded a dipole moment µ = ub= 0.3949(18) D.

Zitieren

The Microwave Spectrum and Dipole Moment of Hexafluoropropanone. / Grabow, J. U.; Heineking, N.; Stahl, W.
in: Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, Jahrgang 46, Nr. 3, 01.03.1991, S. 229-232.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Grabow JU, Heineking N, Stahl W. The Microwave Spectrum and Dipole Moment of Hexafluoropropanone. Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences. 1991 Mär 1;46(3):229-232. doi: 10.1515/zna-1991-0303
Grabow, J. U. ; Heineking, N. ; Stahl, W. / The Microwave Spectrum and Dipole Moment of Hexafluoropropanone. in: Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences. 1991 ; Jahrgang 46, Nr. 3. S. 229-232.
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abstract = "We recorded the microwave spectrum of hexafluoropropanone between 7 and 15 GHz using a pulsed molecular beam microwave Fourier transform spectrometer. The rotational constants were determined to be A =2181.71980(14) MHz, B= 1037.22930(7) MHz, C = 934.89233(8) MHz, the quartic centrifugal distortion constants are D1j = 0.07378(39) kHz, D'JK= 0.10002(75) kHz, D'K = -0.07269(266) kHz, σ'J = 0.00623(29) kHz and R'6= 0.00755(12) kHz. Stark effect measurements yielded a dipole moment µ = ub= 0.3949(18) D.",
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AU - Grabow, J. U.

AU - Heineking, N.

AU - Stahl, W.

N1 - Funding Information: We thank the members of our group for help and discussion. Funds of the Deutsche Forschungsgemeinschaft, the Land Schleswig-Holstein and the Fonds der Chemie are gratefully acknowledged.

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N2 - We recorded the microwave spectrum of hexafluoropropanone between 7 and 15 GHz using a pulsed molecular beam microwave Fourier transform spectrometer. The rotational constants were determined to be A =2181.71980(14) MHz, B= 1037.22930(7) MHz, C = 934.89233(8) MHz, the quartic centrifugal distortion constants are D1j = 0.07378(39) kHz, D'JK= 0.10002(75) kHz, D'K = -0.07269(266) kHz, σ'J = 0.00623(29) kHz and R'6= 0.00755(12) kHz. Stark effect measurements yielded a dipole moment µ = ub= 0.3949(18) D.

AB - We recorded the microwave spectrum of hexafluoropropanone between 7 and 15 GHz using a pulsed molecular beam microwave Fourier transform spectrometer. The rotational constants were determined to be A =2181.71980(14) MHz, B= 1037.22930(7) MHz, C = 934.89233(8) MHz, the quartic centrifugal distortion constants are D1j = 0.07378(39) kHz, D'JK= 0.10002(75) kHz, D'K = -0.07269(266) kHz, σ'J = 0.00623(29) kHz and R'6= 0.00755(12) kHz. Stark effect measurements yielded a dipole moment µ = ub= 0.3949(18) D.

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