Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 9658-9662 |
| Seitenumfang | 5 |
| Fachzeitschrift | Journal of Chemical Physics |
| Jahrgang | 116 |
| Ausgabenummer | 22 |
| Publikationsstatus | Veröffentlicht - 22 Mai 2002 |
| Extern publiziert | Ja |
Abstract
The measurements of time-resolved photodissociation of the sequential reaction Au8+CH3OH→Au8+→ Au7+ were performed for several excitation energies. The yields and production rates of the final state Au7+ in the sequential process were found to be strongly influenced by the excitation energy deposited into the evaporated methanol molecule. Both the yields and rate constants could be fitted with a single parameter, which is the binding energy of the cluster-methanol.
ASJC Scopus Sachgebiete
- Physik und Astronomie (insg.)
- Allgemeine Physik und Astronomie
- Chemie (insg.)
- Physikalische und Theoretische Chemie
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in: Journal of Chemical Physics, Jahrgang 116, Nr. 22, 22.05.2002, S. 9658-9662.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - The influence of internal degrees of freedom on the unimolecular decay of the molecule-cluster compound Au8+CH3OH
AU - Vogel, Manuel
AU - Hansen, Klavs
AU - Herlert, A.
AU - Schweikhard, L.
AU - Walther, Clemens
PY - 2002/5/22
Y1 - 2002/5/22
N2 - The measurements of time-resolved photodissociation of the sequential reaction Au8+CH3OH→Au8+→ Au7+ were performed for several excitation energies. The yields and production rates of the final state Au7+ in the sequential process were found to be strongly influenced by the excitation energy deposited into the evaporated methanol molecule. Both the yields and rate constants could be fitted with a single parameter, which is the binding energy of the cluster-methanol.
AB - The measurements of time-resolved photodissociation of the sequential reaction Au8+CH3OH→Au8+→ Au7+ were performed for several excitation energies. The yields and production rates of the final state Au7+ in the sequential process were found to be strongly influenced by the excitation energy deposited into the evaporated methanol molecule. Both the yields and rate constants could be fitted with a single parameter, which is the binding energy of the cluster-methanol.
UR - http://www.scopus.com/inward/record.url?scp=0037042629&partnerID=8YFLogxK
U2 - 10.1063/1.1476934
DO - 10.1063/1.1476934
M3 - Article
AN - SCOPUS:0037042629
VL - 116
SP - 9658
EP - 9662
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 22
ER -