The analysis of aging processes of EPDM elastomers using low field NMR with inverse laplace transform and stress relaxation measurements

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • Yuichi Aoyagi
  • Ulrich Giese
  • Juliane Jungk
  • Klaus Beck

Externe Organisationen

  • Freudenberg SE
  • Deutsches Institut für Kautschuktechnologie e.V. (DIK)
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)26-35
Seitenumfang10
FachzeitschriftKGK Kautschuk Gummi Kunststoffe
Jahrgang71
Ausgabenummer7-8
PublikationsstatusVeröffentlicht - 1 Juli 2018
Extern publiziertJa

Abstract

With regard to the long-term stability of seals, “stress-relaxation” testing is known to deliver important information. The mechanism of stress relaxation is, however, difficult to interpret, as several effects take place simultaneously, with each effect itself dependent on external and internal parameters. This paper draws on a combination of stress relaxation experiments and low field NMR measurements. NMR relaxation curves as a function of aging time were analyzed using inverse Laplace transform. The resulting distributions of transversal relaxation times (T2) shows that during thermal oxidation the network structure and the chain mobility of cured EPDM, with and without carbon black filler, changes differently.

ASJC Scopus Sachgebiete

Zitieren

The analysis of aging processes of EPDM elastomers using low field NMR with inverse laplace transform and stress relaxation measurements. / Aoyagi, Yuichi; Giese, Ulrich; Jungk, Juliane et al.
in: KGK Kautschuk Gummi Kunststoffe, Jahrgang 71, Nr. 7-8, 01.07.2018, S. 26-35.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Download
@article{5ddc03efe5d54bf99c97572e5280c914,
title = "The analysis of aging processes of EPDM elastomers using low field NMR with inverse laplace transform and stress relaxation measurements",
abstract = "With regard to the long-term stability of seals, “stress-relaxation” testing is known to deliver important information. The mechanism of stress relaxation is, however, difficult to interpret, as several effects take place simultaneously, with each effect itself dependent on external and internal parameters. This paper draws on a combination of stress relaxation experiments and low field NMR measurements. NMR relaxation curves as a function of aging time were analyzed using inverse Laplace transform. The resulting distributions of transversal relaxation times (T2) shows that during thermal oxidation the network structure and the chain mobility of cured EPDM, with and without carbon black filler, changes differently.",
keywords = "Aging, EPDM, Inverse laplace transform, Low field NMR, Transverse relaxation time",
author = "Yuichi Aoyagi and Ulrich Giese and Juliane Jungk and Klaus Beck",
year = "2018",
month = jul,
day = "1",
language = "English",
volume = "71",
pages = "26--35",
journal = "KGK Kautschuk Gummi Kunststoffe",
issn = "0948-3276",
publisher = "Huethig GmbH & Co. KG",
number = "7-8",

}

Download

TY - JOUR

T1 - The analysis of aging processes of EPDM elastomers using low field NMR with inverse laplace transform and stress relaxation measurements

AU - Aoyagi, Yuichi

AU - Giese, Ulrich

AU - Jungk, Juliane

AU - Beck, Klaus

PY - 2018/7/1

Y1 - 2018/7/1

N2 - With regard to the long-term stability of seals, “stress-relaxation” testing is known to deliver important information. The mechanism of stress relaxation is, however, difficult to interpret, as several effects take place simultaneously, with each effect itself dependent on external and internal parameters. This paper draws on a combination of stress relaxation experiments and low field NMR measurements. NMR relaxation curves as a function of aging time were analyzed using inverse Laplace transform. The resulting distributions of transversal relaxation times (T2) shows that during thermal oxidation the network structure and the chain mobility of cured EPDM, with and without carbon black filler, changes differently.

AB - With regard to the long-term stability of seals, “stress-relaxation” testing is known to deliver important information. The mechanism of stress relaxation is, however, difficult to interpret, as several effects take place simultaneously, with each effect itself dependent on external and internal parameters. This paper draws on a combination of stress relaxation experiments and low field NMR measurements. NMR relaxation curves as a function of aging time were analyzed using inverse Laplace transform. The resulting distributions of transversal relaxation times (T2) shows that during thermal oxidation the network structure and the chain mobility of cured EPDM, with and without carbon black filler, changes differently.

KW - Aging

KW - EPDM

KW - Inverse laplace transform

KW - Low field NMR

KW - Transverse relaxation time

UR - http://www.scopus.com/inward/record.url?scp=85051865696&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:85051865696

VL - 71

SP - 26

EP - 35

JO - KGK Kautschuk Gummi Kunststoffe

JF - KGK Kautschuk Gummi Kunststoffe

SN - 0948-3276

IS - 7-8

ER -