The δ13C, δ18O and Δ 47 records in biogenic, pedogenic and geogenic carbonate types from paleosol-loess sequence and their paleoenvironmental meaning

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • Kazem Zamanian
  • Alex R. Lechler
  • Andrew J. Schauer
  • Yakov Kuzyakov
  • Katharine W. Huntington

Externe Organisationen

  • Georg-August-Universität Göttingen
  • Pacific Lutheran University
  • University of Washington
  • Kazan Volga Region Federal University
  • Peoples' Friendship University of Russia (RUDN)
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Details

OriginalspracheEnglisch
Seiten (von - bis)256-272
Seitenumfang17
FachzeitschriftQuaternary Research (United States)
Jahrgang101
PublikationsstatusVeröffentlicht - Mai 2021
Extern publiziertJa

Abstract

Paleoenvironmental reconstructions are commonly based on isotopic signatures of a variety of carbonate types, including rhizoliths and land-snail shells, present in paleosol-loess sequences. However, various carbonate types are formed through distinct biotic and abiotic processes over various periods, and therefore may record diverging environmental information in the same sedimentological layer. Here, we investigate the effects of carbonate type on δ13C, δ18O, and clumped isotope-derived paleotemperature [T(Δ47)] from the Quaternary Nussloch paleosol-loess sequence (Rhine Valley, SW Germany). δ13C, δ18O, and T(Δ47) values of co-occurring rhizoliths (-8.2‰ to-5.8‰,-6.1‰ to-5.9‰, 12-32°C, respectively), loess dolls (-7.0‰,-5.6‰, 23°C), land-snail shells (-8.1‰ to-3.2‰,-4.0‰ to-2.2‰, 12-38°C), earthworm biospheroliths (-11‰,-4.7‰, 8°C), and bulk carbonates (-1.9‰ to-0.5‰,-5.6‰ to-5.3‰, 78-120°C) from three sediment layers depend systematically on the carbonate type, admixture from geogenic carbonate, and the duration of formation periods. Based on these findings, we provide a comprehensive summary for the application of the three isotopic proxies of δ13C, δ18O, and Δ47 in biogenic and pedogenic carbonates present in the same sediment layer to reconstruct paleoenvironments (e.g., local vegetation, evaporative conditions, and temperature). We conclude that bulk carbonates in Nussloch loess should be excluded from paleoenvironmental reconstructions. Instead, pedogenic and biogenic carbonates should be used to provide context for interpreting the isotopic signature for detailed site- A nd time-specific paleoenvironmental information.

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The δ13C, δ18O and Δ 47 records in biogenic, pedogenic and geogenic carbonate types from paleosol-loess sequence and their paleoenvironmental meaning. / Zamanian, Kazem; Lechler, Alex R.; Schauer, Andrew J. et al.
in: Quaternary Research (United States), Jahrgang 101, 05.2021, S. 256-272.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

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abstract = "Paleoenvironmental reconstructions are commonly based on isotopic signatures of a variety of carbonate types, including rhizoliths and land-snail shells, present in paleosol-loess sequences. However, various carbonate types are formed through distinct biotic and abiotic processes over various periods, and therefore may record diverging environmental information in the same sedimentological layer. Here, we investigate the effects of carbonate type on δ13C, δ18O, and clumped isotope-derived paleotemperature [T(Δ47)] from the Quaternary Nussloch paleosol-loess sequence (Rhine Valley, SW Germany). δ13C, δ18O, and T(Δ47) values of co-occurring rhizoliths (-8.2‰ to-5.8‰,-6.1‰ to-5.9‰, 12-32°C, respectively), loess dolls (-7.0‰,-5.6‰, 23°C), land-snail shells (-8.1‰ to-3.2‰,-4.0‰ to-2.2‰, 12-38°C), earthworm biospheroliths (-11‰,-4.7‰, 8°C), and bulk carbonates (-1.9‰ to-0.5‰,-5.6‰ to-5.3‰, 78-120°C) from three sediment layers depend systematically on the carbonate type, admixture from geogenic carbonate, and the duration of formation periods. Based on these findings, we provide a comprehensive summary for the application of the three isotopic proxies of δ13C, δ18O, and Δ47 in biogenic and pedogenic carbonates present in the same sediment layer to reconstruct paleoenvironments (e.g., local vegetation, evaporative conditions, and temperature). We conclude that bulk carbonates in Nussloch loess should be excluded from paleoenvironmental reconstructions. Instead, pedogenic and biogenic carbonates should be used to provide context for interpreting the isotopic signature for detailed site- A nd time-specific paleoenvironmental information.",
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author = "Kazem Zamanian and Lechler, {Alex R.} and Schauer, {Andrew J.} and Yakov Kuzyakov and Huntington, {Katharine W.}",
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pages = "256--272",
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TY - JOUR

T1 - The δ13C, δ18O and Δ 47 records in biogenic, pedogenic and geogenic carbonate types from paleosol-loess sequence and their paleoenvironmental meaning

AU - Zamanian, Kazem

AU - Lechler, Alex R.

AU - Schauer, Andrew J.

AU - Kuzyakov, Yakov

AU - Huntington, Katharine W.

N1 - Publisher Copyright: Copyright © University of Washington. Published by Cambridge University Press, 2021.

PY - 2021/5

Y1 - 2021/5

N2 - Paleoenvironmental reconstructions are commonly based on isotopic signatures of a variety of carbonate types, including rhizoliths and land-snail shells, present in paleosol-loess sequences. However, various carbonate types are formed through distinct biotic and abiotic processes over various periods, and therefore may record diverging environmental information in the same sedimentological layer. Here, we investigate the effects of carbonate type on δ13C, δ18O, and clumped isotope-derived paleotemperature [T(Δ47)] from the Quaternary Nussloch paleosol-loess sequence (Rhine Valley, SW Germany). δ13C, δ18O, and T(Δ47) values of co-occurring rhizoliths (-8.2‰ to-5.8‰,-6.1‰ to-5.9‰, 12-32°C, respectively), loess dolls (-7.0‰,-5.6‰, 23°C), land-snail shells (-8.1‰ to-3.2‰,-4.0‰ to-2.2‰, 12-38°C), earthworm biospheroliths (-11‰,-4.7‰, 8°C), and bulk carbonates (-1.9‰ to-0.5‰,-5.6‰ to-5.3‰, 78-120°C) from three sediment layers depend systematically on the carbonate type, admixture from geogenic carbonate, and the duration of formation periods. Based on these findings, we provide a comprehensive summary for the application of the three isotopic proxies of δ13C, δ18O, and Δ47 in biogenic and pedogenic carbonates present in the same sediment layer to reconstruct paleoenvironments (e.g., local vegetation, evaporative conditions, and temperature). We conclude that bulk carbonates in Nussloch loess should be excluded from paleoenvironmental reconstructions. Instead, pedogenic and biogenic carbonates should be used to provide context for interpreting the isotopic signature for detailed site- A nd time-specific paleoenvironmental information.

AB - Paleoenvironmental reconstructions are commonly based on isotopic signatures of a variety of carbonate types, including rhizoliths and land-snail shells, present in paleosol-loess sequences. However, various carbonate types are formed through distinct biotic and abiotic processes over various periods, and therefore may record diverging environmental information in the same sedimentological layer. Here, we investigate the effects of carbonate type on δ13C, δ18O, and clumped isotope-derived paleotemperature [T(Δ47)] from the Quaternary Nussloch paleosol-loess sequence (Rhine Valley, SW Germany). δ13C, δ18O, and T(Δ47) values of co-occurring rhizoliths (-8.2‰ to-5.8‰,-6.1‰ to-5.9‰, 12-32°C, respectively), loess dolls (-7.0‰,-5.6‰, 23°C), land-snail shells (-8.1‰ to-3.2‰,-4.0‰ to-2.2‰, 12-38°C), earthworm biospheroliths (-11‰,-4.7‰, 8°C), and bulk carbonates (-1.9‰ to-0.5‰,-5.6‰ to-5.3‰, 78-120°C) from three sediment layers depend systematically on the carbonate type, admixture from geogenic carbonate, and the duration of formation periods. Based on these findings, we provide a comprehensive summary for the application of the three isotopic proxies of δ13C, δ18O, and Δ47 in biogenic and pedogenic carbonates present in the same sediment layer to reconstruct paleoenvironments (e.g., local vegetation, evaporative conditions, and temperature). We conclude that bulk carbonates in Nussloch loess should be excluded from paleoenvironmental reconstructions. Instead, pedogenic and biogenic carbonates should be used to provide context for interpreting the isotopic signature for detailed site- A nd time-specific paleoenvironmental information.

KW - CaCO 3 formation

KW - Clumped isotopes

KW - Key words Rhizoliths

KW - Land-snail shells

KW - Loess

KW - Paleoenvironment reconstruction

KW - Paleosol

KW - Paleosol-loess sequence

KW - Pedogenic carbonates

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U2 - 10.1017/qua.2020.109

DO - 10.1017/qua.2020.109

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JO - Quaternary Research (United States)

JF - Quaternary Research (United States)

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