Tetracyanobutadiene Bridged Push-Pull Chromophores: Development of New Generation Optoelectronic Materials

Publikation: Beitrag in FachzeitschriftÜbersichtsarbeitForschungPeer-Review

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  • Indian Institute of Technology Indore (IITI)
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OriginalspracheEnglisch
Aufsatznummere202200208
Seitenumfang30
FachzeitschriftThe chemical record
Jahrgang23
Ausgabenummer1
PublikationsstatusVeröffentlicht - 19 Jan. 2023

Abstract

This review describes the design strategies used for the synthesis of various tetracyanobutadiene bridged donor-acceptor molecular architectures by a click type [2+2] cycloaddition-retroelectrocyclization (CA-RE) reaction sequence. The photophysical and electrochemical properties of the tetracyanobutadiene bridged molecular architectures based on various moieties including diketopyrrolopyrrole, isoindigo, benzothiadiazole, pyrene, pyrazabole, truxene, boron dipyrromethene (BODIPY), phenothiazine, triphenylamine, thiazole and bisthiazole are summarized. Further, we discuss some important applications of the tetracyanobutadiene bridged derivatives in dye sensitized solar cells, bulk heterojunction solar cells and photothermal cancer therapy.

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Tetracyanobutadiene Bridged Push-Pull Chromophores: Development of New Generation Optoelectronic Materials. / Patil, Yuvraj; Butenschön, Holger; Misra, Rajneesh.
in: The chemical record, Jahrgang 23, Nr. 1, e202200208, 19.01.2023.

Publikation: Beitrag in FachzeitschriftÜbersichtsarbeitForschungPeer-Review

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abstract = "This review describes the design strategies used for the synthesis of various tetracyanobutadiene bridged donor-acceptor molecular architectures by a click type [2+2] cycloaddition-retroelectrocyclization (CA-RE) reaction sequence. The photophysical and electrochemical properties of the tetracyanobutadiene bridged molecular architectures based on various moieties including diketopyrrolopyrrole, isoindigo, benzothiadiazole, pyrene, pyrazabole, truxene, boron dipyrromethene (BODIPY), phenothiazine, triphenylamine, thiazole and bisthiazole are summarized. Further, we discuss some important applications of the tetracyanobutadiene bridged derivatives in dye sensitized solar cells, bulk heterojunction solar cells and photothermal cancer therapy.",
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author = "Yuvraj Patil and Holger Butensch{\"o}n and Rajneesh Misra",
note = "Funding Information: We thank the and SERB (Project No. CRG/2018/000032), New Delhi, and DAAD (Leibniz University Hannover and IIT Indore project). R. M. thanks the Alexander von Humboldt Foundation for a research fellowship. Open Access funding enabled and organized by Projekt DEAL. New Passage to India ",
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T1 - Tetracyanobutadiene Bridged Push-Pull Chromophores

T2 - Development of New Generation Optoelectronic Materials

AU - Patil, Yuvraj

AU - Butenschön, Holger

AU - Misra, Rajneesh

N1 - Funding Information: We thank the and SERB (Project No. CRG/2018/000032), New Delhi, and DAAD (Leibniz University Hannover and IIT Indore project). R. M. thanks the Alexander von Humboldt Foundation for a research fellowship. Open Access funding enabled and organized by Projekt DEAL. New Passage to India

PY - 2023/1/19

Y1 - 2023/1/19

N2 - This review describes the design strategies used for the synthesis of various tetracyanobutadiene bridged donor-acceptor molecular architectures by a click type [2+2] cycloaddition-retroelectrocyclization (CA-RE) reaction sequence. The photophysical and electrochemical properties of the tetracyanobutadiene bridged molecular architectures based on various moieties including diketopyrrolopyrrole, isoindigo, benzothiadiazole, pyrene, pyrazabole, truxene, boron dipyrromethene (BODIPY), phenothiazine, triphenylamine, thiazole and bisthiazole are summarized. Further, we discuss some important applications of the tetracyanobutadiene bridged derivatives in dye sensitized solar cells, bulk heterojunction solar cells and photothermal cancer therapy.

AB - This review describes the design strategies used for the synthesis of various tetracyanobutadiene bridged donor-acceptor molecular architectures by a click type [2+2] cycloaddition-retroelectrocyclization (CA-RE) reaction sequence. The photophysical and electrochemical properties of the tetracyanobutadiene bridged molecular architectures based on various moieties including diketopyrrolopyrrole, isoindigo, benzothiadiazole, pyrene, pyrazabole, truxene, boron dipyrromethene (BODIPY), phenothiazine, triphenylamine, thiazole and bisthiazole are summarized. Further, we discuss some important applications of the tetracyanobutadiene bridged derivatives in dye sensitized solar cells, bulk heterojunction solar cells and photothermal cancer therapy.

KW - Cycloaddition-retroelectrocyclization

KW - Photothermal Therapy

KW - Solar Cells

KW - Tetracyanoethylene

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