Synthesis of visible light driven TiO2 coated carbon nanospheres for degradation of dyes

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • Waseem Raza
  • M. M. Haque
  • M. Muneer
  • D. Bahnemann

Organisationseinheiten

Externe Organisationen

  • Aligarh Muslim University
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)3534-3545
Seitenumfang12
FachzeitschriftArabian journal of chemistry
Jahrgang12
Ausgabenummer8
Frühes Online-Datum12 Sept. 2015
PublikationsstatusVeröffentlicht - Dez. 2019

Abstract

Herein, we report the successful synthesis of visible light driven metal doped TiO 2 coated carbon nanospheres (CNS) via a facile hydrothermal approach. The synthesized materials were characterized by standard analytical techniques, such as XRD, SEM–EDS-mapping, TEM, FTIR, PL, Raman and UV–Vis absorption spectroscopy. The effect of dopants on the band gap energy, crystallite size and photocatalytic properties of the TiO 2 coated CNS was investigated systematically. The incorporation of dopants in TiO 2 matrix found to significantly extend the absorption edge toward visible region and efficient separation of charge carriers on excitation. The photodegradation of two different organic dyes were investigated to evaluate the activity of the photocatalyst under different conditions such as dopant percentage, catalyst dose, different quenchers and calcination temperature. The best photocatalytic activity was observed with 3.0% Ce, doped TiO 2 coated CNS with 1.5 g L −1 concentration calcined at 400 °C. We also performed the antibacterial activity of pure and doped-TiO 2 coated CNS against pathogenic gram negative and gram positive bacteria. The doped-TiO 2 coated CNS exhibited excellent antibacterial activity against both bacteria.

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Synthesis of visible light driven TiO2 coated carbon nanospheres for degradation of dyes. / Raza, Waseem; Haque, M. M.; Muneer, M. et al.
in: Arabian journal of chemistry, Jahrgang 12, Nr. 8, 12.2019, S. 3534-3545.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Raza W, Haque MM, Muneer M, Bahnemann D. Synthesis of visible light driven TiO2 coated carbon nanospheres for degradation of dyes. Arabian journal of chemistry. 2019 Dez;12(8):3534-3545. Epub 2015 Sep 12. doi: 10.1016/j.arabjc.2015.09.002, 10.15488/781
Raza, Waseem ; Haque, M. M. ; Muneer, M. et al. / Synthesis of visible light driven TiO2 coated carbon nanospheres for degradation of dyes. in: Arabian journal of chemistry. 2019 ; Jahrgang 12, Nr. 8. S. 3534-3545.
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title = "Synthesis of visible light driven TiO2 coated carbon nanospheres for degradation of dyes",
abstract = "Herein, we report the successful synthesis of visible light driven metal doped TiO 2 coated carbon nanospheres (CNS) via a facile hydrothermal approach. The synthesized materials were characterized by standard analytical techniques, such as XRD, SEM–EDS-mapping, TEM, FTIR, PL, Raman and UV–Vis absorption spectroscopy. The effect of dopants on the band gap energy, crystallite size and photocatalytic properties of the TiO 2 coated CNS was investigated systematically. The incorporation of dopants in TiO 2 matrix found to significantly extend the absorption edge toward visible region and efficient separation of charge carriers on excitation. The photodegradation of two different organic dyes were investigated to evaluate the activity of the photocatalyst under different conditions such as dopant percentage, catalyst dose, different quenchers and calcination temperature. The best photocatalytic activity was observed with 3.0% Ce, doped TiO 2 coated CNS with 1.5 g L −1 concentration calcined at 400 °C. We also performed the antibacterial activity of pure and doped-TiO 2 coated CNS against pathogenic gram negative and gram positive bacteria. The doped-TiO 2 coated CNS exhibited excellent antibacterial activity against both bacteria. ",
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note = "Funding Information: Financial support to Research Project from Ministry of Mines, Government of India, New Delhi, and Alexander von Humboldt Foundation, Germany, under research group linkage programme is gratefully acknowledged. We also thank Department of Physics and Department of Interdisciplinary Biotechnology Unit A.M.U., Aligarh, for conducting XRD-analysis and biological testing of synthesized powder.",
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Download

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T1 - Synthesis of visible light driven TiO2 coated carbon nanospheres for degradation of dyes

AU - Raza, Waseem

AU - Haque, M. M.

AU - Muneer, M.

AU - Bahnemann, D.

N1 - Funding Information: Financial support to Research Project from Ministry of Mines, Government of India, New Delhi, and Alexander von Humboldt Foundation, Germany, under research group linkage programme is gratefully acknowledged. We also thank Department of Physics and Department of Interdisciplinary Biotechnology Unit A.M.U., Aligarh, for conducting XRD-analysis and biological testing of synthesized powder.

PY - 2019/12

Y1 - 2019/12

N2 - Herein, we report the successful synthesis of visible light driven metal doped TiO 2 coated carbon nanospheres (CNS) via a facile hydrothermal approach. The synthesized materials were characterized by standard analytical techniques, such as XRD, SEM–EDS-mapping, TEM, FTIR, PL, Raman and UV–Vis absorption spectroscopy. The effect of dopants on the band gap energy, crystallite size and photocatalytic properties of the TiO 2 coated CNS was investigated systematically. The incorporation of dopants in TiO 2 matrix found to significantly extend the absorption edge toward visible region and efficient separation of charge carriers on excitation. The photodegradation of two different organic dyes were investigated to evaluate the activity of the photocatalyst under different conditions such as dopant percentage, catalyst dose, different quenchers and calcination temperature. The best photocatalytic activity was observed with 3.0% Ce, doped TiO 2 coated CNS with 1.5 g L −1 concentration calcined at 400 °C. We also performed the antibacterial activity of pure and doped-TiO 2 coated CNS against pathogenic gram negative and gram positive bacteria. The doped-TiO 2 coated CNS exhibited excellent antibacterial activity against both bacteria.

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KW - CNS coated TiO

KW - Dye degradation

KW - Metal doped TiO

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