Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 126-132 |
| Seitenumfang | 7 |
| Fachzeitschrift | Journal of membrane science |
| Jahrgang | 454 |
| Frühes Online-Datum | 16 Dez. 2013 |
| Publikationsstatus | Veröffentlicht - 15 März 2014 |
Abstract
Metal-organic frameworks (MOFs), as a newly developed family of crystalline microporous materials, have attracted considerable attention as promising candidates for the fabrication of superior molecular sieve membranes. For the synthesis of MOF membranes, the MOF's characteristics, such as pore size, stability, and adsorption affinity, have to be considered carefully. In this work, we prepare a highly hydrophobic and permselective Zn(BDC)(TED)0.5 membrane for H2/CO2 separation through secondary growth method with seeding. Attributed to the preferential adsorption affinity and capacity to CO2 as well as a highly porous structure with large channels, the Zn(BDC)(TED)0.5 membrane displays a high H2/CO2 permselectivity. For the separation of an equimolar H2/CO2 mixture at 180°C and 1bar, a H2 permeance of 2.65×10-6molm-2s-1Pa-1 and a H2/CO2 selectivity of 12.1 are obtained. Furthermore, because of its high hydrophobicity, the pore volume of Zn(BDC)(TED)0.5 is not blocked in the presence of steam, which is promising for potential applications of hydrogen separation and purification.
ASJC Scopus Sachgebiete
- Biochemie, Genetik und Molekularbiologie (insg.)
- Biochemie
- Werkstoffwissenschaften (insg.)
- Chemie (insg.)
- Physikalische und Theoretische Chemie
- Chemische Verfahrenstechnik (insg.)
- Filtration und Separation
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in: Journal of membrane science, Jahrgang 454, 15.03.2014, S. 126-132.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Synthesis of highly hydrophobic and permselective metal-organic framework Zn(BDC)(TED)0.5 membranes for H2/CO2 separation
AU - Huang, Aisheng
AU - Chen, Yifei
AU - Liu, Qian
AU - Wang, Nanyi
AU - Jiang, Jianwen
AU - Caro, Jürgen
PY - 2014/3/15
Y1 - 2014/3/15
N2 - Metal-organic frameworks (MOFs), as a newly developed family of crystalline microporous materials, have attracted considerable attention as promising candidates for the fabrication of superior molecular sieve membranes. For the synthesis of MOF membranes, the MOF's characteristics, such as pore size, stability, and adsorption affinity, have to be considered carefully. In this work, we prepare a highly hydrophobic and permselective Zn(BDC)(TED)0.5 membrane for H2/CO2 separation through secondary growth method with seeding. Attributed to the preferential adsorption affinity and capacity to CO2 as well as a highly porous structure with large channels, the Zn(BDC)(TED)0.5 membrane displays a high H2/CO2 permselectivity. For the separation of an equimolar H2/CO2 mixture at 180°C and 1bar, a H2 permeance of 2.65×10-6molm-2s-1Pa-1 and a H2/CO2 selectivity of 12.1 are obtained. Furthermore, because of its high hydrophobicity, the pore volume of Zn(BDC)(TED)0.5 is not blocked in the presence of steam, which is promising for potential applications of hydrogen separation and purification.
AB - Metal-organic frameworks (MOFs), as a newly developed family of crystalline microporous materials, have attracted considerable attention as promising candidates for the fabrication of superior molecular sieve membranes. For the synthesis of MOF membranes, the MOF's characteristics, such as pore size, stability, and adsorption affinity, have to be considered carefully. In this work, we prepare a highly hydrophobic and permselective Zn(BDC)(TED)0.5 membrane for H2/CO2 separation through secondary growth method with seeding. Attributed to the preferential adsorption affinity and capacity to CO2 as well as a highly porous structure with large channels, the Zn(BDC)(TED)0.5 membrane displays a high H2/CO2 permselectivity. For the separation of an equimolar H2/CO2 mixture at 180°C and 1bar, a H2 permeance of 2.65×10-6molm-2s-1Pa-1 and a H2/CO2 selectivity of 12.1 are obtained. Furthermore, because of its high hydrophobicity, the pore volume of Zn(BDC)(TED)0.5 is not blocked in the presence of steam, which is promising for potential applications of hydrogen separation and purification.
KW - H/CO separation
KW - Metal-organic frameworks
KW - Molecular sieve membrane
KW - Simulation study
KW - Zn(BDC)(TED) membrane
UR - http://www.scopus.com/inward/record.url?scp=84891399646&partnerID=8YFLogxK
U2 - 10.1016/j.memsci.2013.12.018
DO - 10.1016/j.memsci.2013.12.018
M3 - Article
AN - SCOPUS:84891399646
VL - 454
SP - 126
EP - 132
JO - Journal of membrane science
JF - Journal of membrane science
SN - 0376-7388
ER -