Synthesis of biodegradable copolymers based on ethylene vinyl acetate and polylactic acid

Publikation: Beitrag in Buch/Bericht/Sammelwerk/KonferenzbandAufsatz in KonferenzbandForschungPeer-Review

Autoren

Externe Organisationen

  • University of Minho
  • Universität Lyon
  • Université Claude Bernard Lyon 1
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Details

OriginalspracheEnglisch
Titel des SammelwerksAdvanced Materials Forum V
Herausgeber/-innenLuis Guerra Rosa, Luis Guerra Rosa, Fernanda Margarido, Fernanda Margarido
Seiten819-824
Seitenumfang6
PublikationsstatusVeröffentlicht - 2010
Extern publiziertJa
Veranstaltung5th International Materials Symposium MATERIAiS 2009 - 14th meeting of SPM - Sociedade Portuguesa de Materiais - Lisbon, Portugal
Dauer: 5 Apr. 20098 Apr. 2009

Publikationsreihe

NameMaterials Science Forum
Band636-637
ISSN (Print)0255-5476
ISSN (elektronisch)1662-9752

Abstract

In the present study biodegradable copolymers of ethylene vinyl acetate and polylactic acid were synthesized using transesterification reactions, the structure, morphology, mechanical properties and biodegradability of the produced materials were characterized. Ethylene vinyl acetate was modified with polylactic acid in an internal mixer using titanium propoxide as transesterification catalyst. The graft copolymers were characterized by elemental analysis, infrared spectroscopy, rheology, scanning electron microscopy and thermal analysis. Selective extractions for all copolymers were made, and the results indicate that a maximum of 25 % of EVA-g-PLA copolymer was synthesized by this method. Biodegradation tests were carried out using the standard ISO 14851 (1999), which specifies a method for determining the biochemical oxygen demand in a closed respirometer. This procedure allowed to synthesize biodegradable copolymers with mechanical properties similar to conventional polymers.

ASJC Scopus Sachgebiete

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Synthesis of biodegradable copolymers based on ethylene vinyl acetate and polylactic acid. / Moura, I.; Machado, A. V.; Nogueira, R. et al.
Advanced Materials Forum V. Hrsg. / Luis Guerra Rosa; Luis Guerra Rosa; Fernanda Margarido; Fernanda Margarido. 2010. S. 819-824 (Materials Science Forum; Band 636-637).

Publikation: Beitrag in Buch/Bericht/Sammelwerk/KonferenzbandAufsatz in KonferenzbandForschungPeer-Review

Moura, I, Machado, AV, Nogueira, R & Bounor-Legare, V 2010, Synthesis of biodegradable copolymers based on ethylene vinyl acetate and polylactic acid. in LG Rosa, LG Rosa, F Margarido & F Margarido (Hrsg.), Advanced Materials Forum V. Materials Science Forum, Bd. 636-637, S. 819-824, 5th International Materials Symposium MATERIAiS 2009 - 14th meeting of SPM - Sociedade Portuguesa de Materiais, Lisbon, Portugal, 5 Apr. 2009. https://doi.org/10.4028/www.scientific.net/MSF.636-637.819
Moura, I., Machado, A. V., Nogueira, R., & Bounor-Legare, V. (2010). Synthesis of biodegradable copolymers based on ethylene vinyl acetate and polylactic acid. In L. G. Rosa, L. G. Rosa, F. Margarido, & F. Margarido (Hrsg.), Advanced Materials Forum V (S. 819-824). (Materials Science Forum; Band 636-637). https://doi.org/10.4028/www.scientific.net/MSF.636-637.819
Moura I, Machado AV, Nogueira R, Bounor-Legare V. Synthesis of biodegradable copolymers based on ethylene vinyl acetate and polylactic acid. in Rosa LG, Rosa LG, Margarido F, Margarido F, Hrsg., Advanced Materials Forum V. 2010. S. 819-824. (Materials Science Forum). doi: 10.4028/www.scientific.net/MSF.636-637.819
Moura, I. ; Machado, A. V. ; Nogueira, R. et al. / Synthesis of biodegradable copolymers based on ethylene vinyl acetate and polylactic acid. Advanced Materials Forum V. Hrsg. / Luis Guerra Rosa ; Luis Guerra Rosa ; Fernanda Margarido ; Fernanda Margarido. 2010. S. 819-824 (Materials Science Forum).
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abstract = "In the present study biodegradable copolymers of ethylene vinyl acetate and polylactic acid were synthesized using transesterification reactions, the structure, morphology, mechanical properties and biodegradability of the produced materials were characterized. Ethylene vinyl acetate was modified with polylactic acid in an internal mixer using titanium propoxide as transesterification catalyst. The graft copolymers were characterized by elemental analysis, infrared spectroscopy, rheology, scanning electron microscopy and thermal analysis. Selective extractions for all copolymers were made, and the results indicate that a maximum of 25 % of EVA-g-PLA copolymer was synthesized by this method. Biodegradation tests were carried out using the standard ISO 14851 (1999), which specifies a method for determining the biochemical oxygen demand in a closed respirometer. This procedure allowed to synthesize biodegradable copolymers with mechanical properties similar to conventional polymers.",
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AU - Moura, I.

AU - Machado, A. V.

AU - Nogueira, R.

AU - Bounor-Legare, V.

PY - 2010

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N2 - In the present study biodegradable copolymers of ethylene vinyl acetate and polylactic acid were synthesized using transesterification reactions, the structure, morphology, mechanical properties and biodegradability of the produced materials were characterized. Ethylene vinyl acetate was modified with polylactic acid in an internal mixer using titanium propoxide as transesterification catalyst. The graft copolymers were characterized by elemental analysis, infrared spectroscopy, rheology, scanning electron microscopy and thermal analysis. Selective extractions for all copolymers were made, and the results indicate that a maximum of 25 % of EVA-g-PLA copolymer was synthesized by this method. Biodegradation tests were carried out using the standard ISO 14851 (1999), which specifies a method for determining the biochemical oxygen demand in a closed respirometer. This procedure allowed to synthesize biodegradable copolymers with mechanical properties similar to conventional polymers.

AB - In the present study biodegradable copolymers of ethylene vinyl acetate and polylactic acid were synthesized using transesterification reactions, the structure, morphology, mechanical properties and biodegradability of the produced materials were characterized. Ethylene vinyl acetate was modified with polylactic acid in an internal mixer using titanium propoxide as transesterification catalyst. The graft copolymers were characterized by elemental analysis, infrared spectroscopy, rheology, scanning electron microscopy and thermal analysis. Selective extractions for all copolymers were made, and the results indicate that a maximum of 25 % of EVA-g-PLA copolymer was synthesized by this method. Biodegradation tests were carried out using the standard ISO 14851 (1999), which specifies a method for determining the biochemical oxygen demand in a closed respirometer. This procedure allowed to synthesize biodegradable copolymers with mechanical properties similar to conventional polymers.

KW - BOD

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A2 - Rosa, Luis Guerra

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Y2 - 5 April 2009 through 8 April 2009

ER -

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