Synthesis and seawater desalination of molecular sieving zeolitic imidazolate framework membranes

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autorschaft

  • Yaqiong Zhu
  • Krishna M. Gupta
  • Qian Liu
  • Jianwen Jiang
  • Jürgen Caro
  • Aisheng Huang

Externe Organisationen

  • Chinese Academy of Sciences (CAS)
  • National University of Singapore
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)75-82
Seitenumfang8
FachzeitschriftDESALINATION
Jahrgang385
Frühes Online-Datum18 Feb. 2016
PublikationsstatusVeröffentlicht - 2 Mai 2016

Abstract

Through bio-inspired polydopamine modification of the ceramic support surface, dense and reproducible zeolitic imidazolate framework (ZIF) membranes have been developed for the first time for seawater desalination by pervaporation. Demonstrated by both experimental and simulation studies, the developed ZIF membranes show high desalination performances attributing to the small pore size of the ZIF membranes, which is exactly in between the size of water molecules and hydrated ions. The ZIF membranes show a high stability in seawater. At 25, 50, 75 and 100 °C, the water fluxes through the ZIF-8 membrane are 5.8, 8.1, 10.8, and 13.5 kg/(m2·h), respectively, with a high ion rejection of over 99.8%, which is promising for seawater desalination by ionic sieving.

ASJC Scopus Sachgebiete

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Synthesis and seawater desalination of molecular sieving zeolitic imidazolate framework membranes. / Zhu, Yaqiong; Gupta, Krishna M.; Liu, Qian et al.
in: DESALINATION, Jahrgang 385, 02.05.2016, S. 75-82.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Zhu Y, Gupta KM, Liu Q, Jiang J, Caro J, Huang A. Synthesis and seawater desalination of molecular sieving zeolitic imidazolate framework membranes. DESALINATION. 2016 Mai 2;385:75-82. Epub 2016 Feb 18. doi: 10.1016/j.desal.2016.02.005
Zhu, Yaqiong ; Gupta, Krishna M. ; Liu, Qian et al. / Synthesis and seawater desalination of molecular sieving zeolitic imidazolate framework membranes. in: DESALINATION. 2016 ; Jahrgang 385. S. 75-82.
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abstract = "Through bio-inspired polydopamine modification of the ceramic support surface, dense and reproducible zeolitic imidazolate framework (ZIF) membranes have been developed for the first time for seawater desalination by pervaporation. Demonstrated by both experimental and simulation studies, the developed ZIF membranes show high desalination performances attributing to the small pore size of the ZIF membranes, which is exactly in between the size of water molecules and hydrated ions. The ZIF membranes show a high stability in seawater. At 25, 50, 75 and 100 °C, the water fluxes through the ZIF-8 membrane are 5.8, 8.1, 10.8, and 13.5 kg/(m2·h), respectively, with a high ion rejection of over 99.8%, which is promising for seawater desalination by ionic sieving.",
keywords = "Covalent functionalization, Metal-organic frameworks, Seawater desalination, Zeolitic imidazolate framework",
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T1 - Synthesis and seawater desalination of molecular sieving zeolitic imidazolate framework membranes

AU - Zhu, Yaqiong

AU - Gupta, Krishna M.

AU - Liu, Qian

AU - Jiang, Jianwen

AU - Caro, Jürgen

AU - Huang, Aisheng

PY - 2016/5/2

Y1 - 2016/5/2

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AB - Through bio-inspired polydopamine modification of the ceramic support surface, dense and reproducible zeolitic imidazolate framework (ZIF) membranes have been developed for the first time for seawater desalination by pervaporation. Demonstrated by both experimental and simulation studies, the developed ZIF membranes show high desalination performances attributing to the small pore size of the ZIF membranes, which is exactly in between the size of water molecules and hydrated ions. The ZIF membranes show a high stability in seawater. At 25, 50, 75 and 100 °C, the water fluxes through the ZIF-8 membrane are 5.8, 8.1, 10.8, and 13.5 kg/(m2·h), respectively, with a high ion rejection of over 99.8%, which is promising for seawater desalination by ionic sieving.

KW - Covalent functionalization

KW - Metal-organic frameworks

KW - Seawater desalination

KW - Zeolitic imidazolate framework

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