Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 2263-2271 |
| Seitenumfang | 9 |
| Fachzeitschrift | Journal of Organometallic Chemistry |
| Jahrgang | 690 |
| Ausgabenummer | 9 |
| Publikationsstatus | Veröffentlicht - 23 März 2005 |
Abstract
The syntheses of a number of cyclopentadienylcarbene iron half sandwich complexes are described. In addition to their spectroscopic characterization an X-ray crystal structure analysis is provided. The complexes prepared include chromium, molybdenum, and tungsten carbene complexes. The dicarbonyliron unit is substituted by benzyl, butyl or trimethylsilylmethyl groups. In two cases tetrametallic dimeric complexes connected by a propyl chain are presented. The reaction of the formylcyclopentadienyliron complex with a chromium carbene complex provided a vinylogous representative. Cyclic voltammetry was performed, and the data obtained are discussed in comparison to similar ferrocene based complexes.
ASJC Scopus Sachgebiete
- Biochemie, Genetik und Molekularbiologie (insg.)
- Biochemie
- Chemie (insg.)
- Physikalische und Theoretische Chemie
- Chemie (insg.)
- Organische Chemie
- Chemie (insg.)
- Anorganische Chemie
- Werkstoffwissenschaften (insg.)
- Werkstoffchemie
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in: Journal of Organometallic Chemistry, Jahrgang 690, Nr. 9, 23.03.2005, S. 2263-2271.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Synthesis and cyclic voltammetry of some new metal carbene substituted cyclopentadienyliron half sandwich complexes
AU - Schwarz, Markus
AU - Vollmann, Marc
AU - Wartchow, Rudolf
AU - Butenschön, Holger
PY - 2005/3/23
Y1 - 2005/3/23
N2 - The syntheses of a number of cyclopentadienylcarbene iron half sandwich complexes are described. In addition to their spectroscopic characterization an X-ray crystal structure analysis is provided. The complexes prepared include chromium, molybdenum, and tungsten carbene complexes. The dicarbonyliron unit is substituted by benzyl, butyl or trimethylsilylmethyl groups. In two cases tetrametallic dimeric complexes connected by a propyl chain are presented. The reaction of the formylcyclopentadienyliron complex with a chromium carbene complex provided a vinylogous representative. Cyclic voltammetry was performed, and the data obtained are discussed in comparison to similar ferrocene based complexes.
AB - The syntheses of a number of cyclopentadienylcarbene iron half sandwich complexes are described. In addition to their spectroscopic characterization an X-ray crystal structure analysis is provided. The complexes prepared include chromium, molybdenum, and tungsten carbene complexes. The dicarbonyliron unit is substituted by benzyl, butyl or trimethylsilylmethyl groups. In two cases tetrametallic dimeric complexes connected by a propyl chain are presented. The reaction of the formylcyclopentadienyliron complex with a chromium carbene complex provided a vinylogous representative. Cyclic voltammetry was performed, and the data obtained are discussed in comparison to similar ferrocene based complexes.
UR - http://www.scopus.com/inward/record.url?scp=17444384867&partnerID=8YFLogxK
U2 - 10.1016/j.jorganchem.2005.02.030
DO - 10.1016/j.jorganchem.2005.02.030
M3 - Article
AN - SCOPUS:17444384867
VL - 690
SP - 2263
EP - 2271
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 9
ER -