Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 999-1000 |
| Seitenumfang | 2 |
| Fachzeitschrift | Journal of the Chemical Society, Chemical Communications |
| Ausgabenummer | 8 |
| Publikationsstatus | Veröffentlicht - 1994 |
| Extern publiziert | Ja |
Abstract
Tricarbonyl(η6-1,2-dioxobenzocyclobutene)chromium(0) 1 can be converted into benzocyclooctenedione derivatives 3, 7 and 8 as well as fused five-membered ring systems 2, 4 and 6 by addition of vinyl lithium derivatives and following double anionic oxy-Cope rearrangement under very mild reaction conditions (-78 °C); product ratios depend on the method of hydrolysis.
ASJC Scopus Sachgebiete
- Biochemie, Genetik und Molekularbiologie (insg.)
- Molekularmedizin
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in: Journal of the Chemical Society, Chemical Communications, Nr. 8, 1994, S. 999-1000.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Syntheses of Benzocyclooctenedione Derivatives, Cyclopenta[a]indanones and a Benzo-anellated Tetraquinane via Sequential Transformations of Tricarbonyl(η6-1,2-dioxobenzocyclobutene)chromium(0)
AU - Brands, Michael
AU - Bruckmann, Joachim
AU - Krüger, Carl
AU - Butenschön, Holger
PY - 1994
Y1 - 1994
N2 - Tricarbonyl(η6-1,2-dioxobenzocyclobutene)chromium(0) 1 can be converted into benzocyclooctenedione derivatives 3, 7 and 8 as well as fused five-membered ring systems 2, 4 and 6 by addition of vinyl lithium derivatives and following double anionic oxy-Cope rearrangement under very mild reaction conditions (-78 °C); product ratios depend on the method of hydrolysis.
AB - Tricarbonyl(η6-1,2-dioxobenzocyclobutene)chromium(0) 1 can be converted into benzocyclooctenedione derivatives 3, 7 and 8 as well as fused five-membered ring systems 2, 4 and 6 by addition of vinyl lithium derivatives and following double anionic oxy-Cope rearrangement under very mild reaction conditions (-78 °C); product ratios depend on the method of hydrolysis.
UR - http://www.scopus.com/inward/record.url?scp=37049067780&partnerID=8YFLogxK
U2 - 10.1039/C39940000999
DO - 10.1039/C39940000999
M3 - Article
AN - SCOPUS:37049067780
SP - 999
EP - 1000
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
SN - 0022-4936
IS - 8
ER -