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Surface Zeta Potential and Diamond Seeding on Gallium Nitride Films

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autorschaft

  • Soumen Mandal
  • Evan L. H. Thomas
  • Callum Middleton
  • Laia Gines

Externe Organisationen

  • Cardiff University
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    • Citation Indexes: 36
    • Patent Family Citations: 1
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Details

OriginalspracheEnglisch
Seiten (von - bis)7275-7280
Seitenumfang6
FachzeitschriftACS Omega
Jahrgang2
Ausgabenummer10
PublikationsstatusVeröffentlicht - 31 Okt. 2017
Extern publiziertJa

Abstract

The measurement of ζ potential of Ga-face and N-face gallium nitride has been carried out as a function of pH. Both of the faces show negative ζ potential in the pH range 5.5-9. The Ga-face has an isoelectric point at pH 5.5. The N-face shows a more negative ζ potential due to larger concentration of adsorbed oxygen. The ζ potential data clearly showed that H-terminated diamond seed solution at pH 8 will be optimal for the self-assembly of a monolayer of diamond nanoparticles on the GaN surface. The subsequent growth of thin diamond films on GaN seeded with H-terminated diamond seeds produced fully coalesced films, confirming a seeding density in excess of 10 11 cm -2. This technique removes the requirement for a low thermal conduction seeding layer like silicon nitride on GaN.

Zitieren

Surface Zeta Potential and Diamond Seeding on Gallium Nitride Films. / Mandal, Soumen; Thomas, Evan L. H.; Middleton, Callum et al.
in: ACS Omega, Jahrgang 2, Nr. 10, 31.10.2017, S. 7275-7280.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Mandal, S, Thomas, ELH, Middleton, C, Gines, L, Griffiths, JT, Kappers, MJ, Oliver, RA, Wallis, DJ, Goff, LE, Lynch, SA, Kuball, M & Williams, OA 2017, 'Surface Zeta Potential and Diamond Seeding on Gallium Nitride Films', ACS Omega, Jg. 2, Nr. 10, S. 7275-7280. https://doi.org/10.1021/acsomega.7b01069
Mandal, S., Thomas, E. L. H., Middleton, C., Gines, L., Griffiths, J. T., Kappers, M. J., Oliver, R. A., Wallis, D. J., Goff, L. E., Lynch, S. A., Kuball, M., & Williams, O. A. (2017). Surface Zeta Potential and Diamond Seeding on Gallium Nitride Films. ACS Omega, 2(10), 7275-7280. https://doi.org/10.1021/acsomega.7b01069
Mandal S, Thomas ELH, Middleton C, Gines L, Griffiths JT, Kappers MJ et al. Surface Zeta Potential and Diamond Seeding on Gallium Nitride Films. ACS Omega. 2017 Okt 31;2(10):7275-7280. doi: 10.1021/acsomega.7b01069
Mandal, Soumen ; Thomas, Evan L. H. ; Middleton, Callum et al. / Surface Zeta Potential and Diamond Seeding on Gallium Nitride Films. in: ACS Omega. 2017 ; Jahrgang 2, Nr. 10. S. 7275-7280.
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T1 - Surface Zeta Potential and Diamond Seeding on Gallium Nitride Films

AU - Mandal, Soumen

AU - Thomas, Evan L. H.

AU - Middleton, Callum

AU - Gines, Laia

AU - Griffiths, James T.

AU - Kappers, Menno J.

AU - Oliver, Rachel A.

AU - Wallis, David J.

AU - Goff, Lucy E.

AU - Lynch, Stephen A.

AU - Kuball, Martin

AU - Williams, Oliver A.

N1 - Publisher Copyright: © 2017 American Chemical Society.

PY - 2017/10/31

Y1 - 2017/10/31

N2 - The measurement of ζ potential of Ga-face and N-face gallium nitride has been carried out as a function of pH. Both of the faces show negative ζ potential in the pH range 5.5-9. The Ga-face has an isoelectric point at pH 5.5. The N-face shows a more negative ζ potential due to larger concentration of adsorbed oxygen. The ζ potential data clearly showed that H-terminated diamond seed solution at pH 8 will be optimal for the self-assembly of a monolayer of diamond nanoparticles on the GaN surface. The subsequent growth of thin diamond films on GaN seeded with H-terminated diamond seeds produced fully coalesced films, confirming a seeding density in excess of 10 11 cm -2. This technique removes the requirement for a low thermal conduction seeding layer like silicon nitride on GaN.

AB - The measurement of ζ potential of Ga-face and N-face gallium nitride has been carried out as a function of pH. Both of the faces show negative ζ potential in the pH range 5.5-9. The Ga-face has an isoelectric point at pH 5.5. The N-face shows a more negative ζ potential due to larger concentration of adsorbed oxygen. The ζ potential data clearly showed that H-terminated diamond seed solution at pH 8 will be optimal for the self-assembly of a monolayer of diamond nanoparticles on the GaN surface. The subsequent growth of thin diamond films on GaN seeded with H-terminated diamond seeds produced fully coalesced films, confirming a seeding density in excess of 10 11 cm -2. This technique removes the requirement for a low thermal conduction seeding layer like silicon nitride on GaN.

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DO - 10.1021/acsomega.7b01069

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SP - 7275

EP - 7280

JO - ACS Omega

JF - ACS Omega

IS - 10

ER -

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