"Super-Lindqvist" Aggregate and Large 3D Interpenetrating Coordination Polymer from Solvothermal Reactions of [Fe2(OtBu)6] with Ethanol

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Autoren

  • Olaf Nachtigall
  • Matthias Kusserow
  • Rodolphe Clérac
  • Wolfgang Wernsdorfer
  • Michael Menzel
  • Franz Renz
  • Jerzy Mrozinski
  • Johann Spandl

Organisationseinheiten

Externe Organisationen

  • Freie Universität Berlin (FU Berlin)
  • Centre national de la recherche scientifique (CNRS)
  • Universite de Bordeaux
  • Institut Neel
  • Bundesanstalt für Materialforschung und -prüfung (BAM)
  • University of Wroclaw
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)10361-10364
Seitenumfang4
FachzeitschriftAngewandte Chemie - International Edition
Jahrgang54
Ausgabenummer35
PublikationsstatusVeröffentlicht - 1 Aug. 2015

Abstract

The syntheses, crystal structures, and physical properties of [HFe19O14(OEt)30] and {Fe11(OEt)24}∞ are reported. [HFe19O14(OEt)30] has an octahedral shape. Its core with a central Fe metal ion surrounded by six μ6-oxo ligands is arranged in the rock salt structure. {Fe11(OEt)24}∞ is a mixed-valence coordination polymer in which FeIII metal ions form three 3D interpenetrating (10,3)-b nets. The arrangement of the FeIII ions can also be compared to that of Si ions in α-ThSi2. Thus, the described structures are at the interface between molecular and solid-state chemistry.

ASJC Scopus Sachgebiete

Zitieren

"Super-Lindqvist" Aggregate and Large 3D Interpenetrating Coordination Polymer from Solvothermal Reactions of [Fe2(OtBu)6] with Ethanol. / Nachtigall, Olaf; Kusserow, Matthias; Clérac, Rodolphe et al.
in: Angewandte Chemie - International Edition, Jahrgang 54, Nr. 35, 01.08.2015, S. 10361-10364.

Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review

Nachtigall, O, Kusserow, M, Clérac, R, Wernsdorfer, W, Menzel, M, Renz, F, Mrozinski, J & Spandl, J 2015, '"Super-Lindqvist" Aggregate and Large 3D Interpenetrating Coordination Polymer from Solvothermal Reactions of [Fe2(OtBu)6] with Ethanol', Angewandte Chemie - International Edition, Jg. 54, Nr. 35, S. 10361-10364. https://doi.org/10.1002/anie.201503647
Nachtigall, O., Kusserow, M., Clérac, R., Wernsdorfer, W., Menzel, M., Renz, F., Mrozinski, J., & Spandl, J. (2015). "Super-Lindqvist" Aggregate and Large 3D Interpenetrating Coordination Polymer from Solvothermal Reactions of [Fe2(OtBu)6] with Ethanol. Angewandte Chemie - International Edition, 54(35), 10361-10364. https://doi.org/10.1002/anie.201503647
Nachtigall O, Kusserow M, Clérac R, Wernsdorfer W, Menzel M, Renz F et al. "Super-Lindqvist" Aggregate and Large 3D Interpenetrating Coordination Polymer from Solvothermal Reactions of [Fe2(OtBu)6] with Ethanol. Angewandte Chemie - International Edition. 2015 Aug 1;54(35):10361-10364. doi: 10.1002/anie.201503647
Nachtigall, Olaf ; Kusserow, Matthias ; Clérac, Rodolphe et al. / "Super-Lindqvist" Aggregate and Large 3D Interpenetrating Coordination Polymer from Solvothermal Reactions of [Fe2(OtBu)6] with Ethanol. in: Angewandte Chemie - International Edition. 2015 ; Jahrgang 54, Nr. 35. S. 10361-10364.
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abstract = "The syntheses, crystal structures, and physical properties of [HFe19O14(OEt)30] and {Fe11(OEt)24}∞ are reported. [HFe19O14(OEt)30] has an octahedral shape. Its core with a central Fe metal ion surrounded by six μ6-oxo ligands is arranged in the rock salt structure. {Fe11(OEt)24}∞ is a mixed-valence coordination polymer in which FeIII metal ions form three 3D interpenetrating (10,3)-b nets. The arrangement of the FeIII ions can also be compared to that of Si ions in α-ThSi2. Thus, the described structures are at the interface between molecular and solid-state chemistry.",
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TY - JOUR

T1 - "Super-Lindqvist" Aggregate and Large 3D Interpenetrating Coordination Polymer from Solvothermal Reactions of [Fe2(OtBu)6] with Ethanol

AU - Nachtigall, Olaf

AU - Kusserow, Matthias

AU - Clérac, Rodolphe

AU - Wernsdorfer, Wolfgang

AU - Menzel, Michael

AU - Renz, Franz

AU - Mrozinski, Jerzy

AU - Spandl, Johann

PY - 2015/8/1

Y1 - 2015/8/1

N2 - The syntheses, crystal structures, and physical properties of [HFe19O14(OEt)30] and {Fe11(OEt)24}∞ are reported. [HFe19O14(OEt)30] has an octahedral shape. Its core with a central Fe metal ion surrounded by six μ6-oxo ligands is arranged in the rock salt structure. {Fe11(OEt)24}∞ is a mixed-valence coordination polymer in which FeIII metal ions form three 3D interpenetrating (10,3)-b nets. The arrangement of the FeIII ions can also be compared to that of Si ions in α-ThSi2. Thus, the described structures are at the interface between molecular and solid-state chemistry.

AB - The syntheses, crystal structures, and physical properties of [HFe19O14(OEt)30] and {Fe11(OEt)24}∞ are reported. [HFe19O14(OEt)30] has an octahedral shape. Its core with a central Fe metal ion surrounded by six μ6-oxo ligands is arranged in the rock salt structure. {Fe11(OEt)24}∞ is a mixed-valence coordination polymer in which FeIII metal ions form three 3D interpenetrating (10,3)-b nets. The arrangement of the FeIII ions can also be compared to that of Si ions in α-ThSi2. Thus, the described structures are at the interface between molecular and solid-state chemistry.

KW - coordination polymers

KW - iron

KW - polyoxometalates

KW - single-molecule magnets

KW - solvothermal syntheses

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