Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 429-432 |
| Seitenumfang | 4 |
| Fachzeitschrift | Synlett |
| Ausgabenummer | 3 |
| Publikationsstatus | Veröffentlicht - 21 Jan. 2009 |
Abstract
The first 1,2-Brook rearrangements with bis(dimethylphenylsilyl) ketone, initiated after addition of different C- and S-nucleophiles, are described. The resulting, newly formed carbanion can be trapped with electrophiles thus paving the way for utilizing bissilyl ketones as formyl dianion equivalents in the future.
ASJC Scopus Sachgebiete
- Chemie (insg.)
- Organische Chemie
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in: Synlett, Nr. 3, 21.01.2009, S. 429-432.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Studies on the 1,2-brook rearrangement of bissilyl ketones
AU - Kirschning, Andreas
AU - Luiken, Silke
AU - Migliorini, Antonella
AU - Loreto, Maria Antonietta
AU - Vogt, Monika
PY - 2009/1/21
Y1 - 2009/1/21
N2 - The first 1,2-Brook rearrangements with bis(dimethylphenylsilyl) ketone, initiated after addition of different C- and S-nucleophiles, are described. The resulting, newly formed carbanion can be trapped with electrophiles thus paving the way for utilizing bissilyl ketones as formyl dianion equivalents in the future.
AB - The first 1,2-Brook rearrangements with bis(dimethylphenylsilyl) ketone, initiated after addition of different C- and S-nucleophiles, are described. The resulting, newly formed carbanion can be trapped with electrophiles thus paving the way for utilizing bissilyl ketones as formyl dianion equivalents in the future.
KW - Bissilyl ketones
KW - Brook rearrangement
KW - Formyl anion
KW - Organolithium species
KW - Silyl migration
UR - http://www.scopus.com/inward/record.url?scp=62249152542&partnerID=8YFLogxK
U2 - 10.1055/s-0028-1087535
DO - 10.1055/s-0028-1087535
M3 - Article
AN - SCOPUS:62249152542
SP - 429
EP - 432
JO - Synlett
JF - Synlett
SN - 0936-5214
IS - 3
ER -