Structure of the benzene dimer - Governed by dynamics

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • Melanie Schnell
  • Undine Erlekam
  • P. R. Bunker
  • Gert Vonhelden
  • Jens Uwe Grabow
  • Gerard Meijer
  • Ad Vanderavoird

Externe Organisationen

  • Center for Free-Electron Laser Science (CFEL)
  • Max-Planck-Institut für Kernphysik
  • Fritz-Haber-Institut der Max-Planck-Gesellschaft
  • National Research Council of Canada
  • Radboud Universität Nijmegen (RU)
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)5180-5183
Seitenumfang4
FachzeitschriftAngewandte Chemie - International Edition
Jahrgang52
Ausgabenummer19
PublikationsstatusVeröffentlicht - 3 Mai 2013

Abstract

The benzene dimer, an important prototype for studying noncovalent interactions, exhibits characteristic splitting patterns in its rotational spectrum, which for a long time were not understood. A new theoretical model reveals their origin: a concerted internal motion involving sixfold hindered rotation tunneling of the molecule forming the stem of the T-shaped structure and tilt tunneling of the cap.

ASJC Scopus Sachgebiete

Zitieren

Structure of the benzene dimer - Governed by dynamics. / Schnell, Melanie; Erlekam, Undine; Bunker, P. R. et al.
in: Angewandte Chemie - International Edition, Jahrgang 52, Nr. 19, 03.05.2013, S. 5180-5183.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Schnell, M, Erlekam, U, Bunker, PR, Vonhelden, G, Grabow, JU, Meijer, G & Vanderavoird, A 2013, 'Structure of the benzene dimer - Governed by dynamics', Angewandte Chemie - International Edition, Jg. 52, Nr. 19, S. 5180-5183. https://doi.org/10.1002/anie.201300653
Schnell, M., Erlekam, U., Bunker, P. R., Vonhelden, G., Grabow, J. U., Meijer, G., & Vanderavoird, A. (2013). Structure of the benzene dimer - Governed by dynamics. Angewandte Chemie - International Edition, 52(19), 5180-5183. https://doi.org/10.1002/anie.201300653
Schnell M, Erlekam U, Bunker PR, Vonhelden G, Grabow JU, Meijer G et al. Structure of the benzene dimer - Governed by dynamics. Angewandte Chemie - International Edition. 2013 Mai 3;52(19):5180-5183. doi: 10.1002/anie.201300653
Schnell, Melanie ; Erlekam, Undine ; Bunker, P. R. et al. / Structure of the benzene dimer - Governed by dynamics. in: Angewandte Chemie - International Edition. 2013 ; Jahrgang 52, Nr. 19. S. 5180-5183.
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