Details
| Originalsprache | Englisch |
|---|---|
| Seiten (von - bis) | 1498-1504 |
| Seitenumfang | 7 |
| Fachzeitschrift | European Journal of Inorganic Chemistry |
| Jahrgang | 2021 |
| Ausgabenummer | 15 |
| Frühes Online-Datum | 4 März 2021 |
| Publikationsstatus | Veröffentlicht - 17 Apr. 2021 |
Abstract
Six new mononuclear [FeIII(LBr,Cl)X]-complexes (LBr,Cl is the dianionic penta-N3O2-dentate Schiff base ligand N,N′-bis(2’-hydroxy-3-bromo-5-chlorobenzylidene)-1,6-diamino-3-azahexane; X: Cl−, N3−, NCO−, NCS−, NCSe−, CN−) were synthesized and their structures, magnetic and electrochemical properties studied. Structure analysis and magnetic measurements showed that [FeIII(LBr,Cl)CN] is in the low spin state and the other five complexes are in high spin states. Furthermore, the trinuclear mixed valent cobalt complex {[CoIII(LH,H)CN]2[CoII(1-methylimidazole)3(H2O)]} was prepared and its magnetic behavior studied.
ASJC Scopus Sachgebiete
- Chemie (insg.)
- Anorganische Chemie
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in: European Journal of Inorganic Chemistry, Jahrgang 2021, Nr. 15, 17.04.2021, S. 1498-1504.
Publikation: Beitrag in Fachzeitschrift › Artikel › Forschung › Peer-Review
}
TY - JOUR
T1 - Structural, Magnetic, and Electrochemical Characterization of Iron(III) and Cobalt Complexes with Penta-N3O2-dentate Ligands
AU - Natke, Dominik
AU - Preiss, Annika
AU - Klimke, Stephen
AU - Shiga, Takuya
AU - Boca, Roman
AU - Ohba, Masaaki
AU - Oshio, Hiroki
AU - Renz, Franz
N1 - Funding Information: This work was supported by the Hannover School for Nanotechnology (HSN) and the German Academic Exchange Service (DAAD). Open access funding enabled and organized by Projekt DEAL.
PY - 2021/4/17
Y1 - 2021/4/17
N2 - Six new mononuclear [FeIII(LBr,Cl)X]-complexes (LBr,Cl is the dianionic penta-N3O2-dentate Schiff base ligand N,N′-bis(2’-hydroxy-3-bromo-5-chlorobenzylidene)-1,6-diamino-3-azahexane; X: Cl−, N3−, NCO−, NCS−, NCSe−, CN−) were synthesized and their structures, magnetic and electrochemical properties studied. Structure analysis and magnetic measurements showed that [FeIII(LBr,Cl)CN] is in the low spin state and the other five complexes are in high spin states. Furthermore, the trinuclear mixed valent cobalt complex {[CoIII(LH,H)CN]2[CoII(1-methylimidazole)3(H2O)]} was prepared and its magnetic behavior studied.
AB - Six new mononuclear [FeIII(LBr,Cl)X]-complexes (LBr,Cl is the dianionic penta-N3O2-dentate Schiff base ligand N,N′-bis(2’-hydroxy-3-bromo-5-chlorobenzylidene)-1,6-diamino-3-azahexane; X: Cl−, N3−, NCO−, NCS−, NCSe−, CN−) were synthesized and their structures, magnetic and electrochemical properties studied. Structure analysis and magnetic measurements showed that [FeIII(LBr,Cl)CN] is in the low spin state and the other five complexes are in high spin states. Furthermore, the trinuclear mixed valent cobalt complex {[CoIII(LH,H)CN]2[CoII(1-methylimidazole)3(H2O)]} was prepared and its magnetic behavior studied.
KW - Cobalt
KW - Iron
KW - Magnetic properties
KW - Mixed valance
KW - Redox chemistry
KW - Schiff base complexes
UR - http://www.scopus.com/inward/record.url?scp=85103194130&partnerID=8YFLogxK
U2 - 10.1002/ejic.202100081
DO - 10.1002/ejic.202100081
M3 - Article
AN - SCOPUS:85103194130
VL - 2021
SP - 1498
EP - 1504
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
SN - 1434-1948
IS - 15
ER -