Structural investigations of the graphite intercalation compounds of the dichlorides of the IIB-elements (Zn, Cd, Hg)

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • P. Behrens
  • H. Beuthien
  • H. P. Eickhoff
  • W. Metz
  • W. Niemann

Externe Organisationen

  • Universität Hamburg
  • Haldor Topsoe AS
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)95-100
Seitenumfang6
FachzeitschriftSynthetic metals
Jahrgang23
Ausgabenummer1-4
PublikationsstatusVeröffentlicht - März 1988
Extern publiziertJa

Abstract

An account of our structural investigations of the Graphite Intercalation Compounds of ZnCl2, CdCl2 and HgCl2 is given. In the case of zinc chloride-graphite X-ray absorption spectra show that the Zn atoms in the intercalated layers are coordinated tetrahedrally. For cadmium chloride-graphite hk0 diffraction patterns clearly show that the sandwich structure of a layer as it is observed in pure CdCl2 is conserved. For mercuric chloride-graphite, monochromatic Laue photographs show an oblique in-plane unit cell of the intercalate.

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Structural investigations of the graphite intercalation compounds of the dichlorides of the IIB-elements (Zn, Cd, Hg). / Behrens, P.; Beuthien, H.; Eickhoff, H. P. et al.
in: Synthetic metals, Jahrgang 23, Nr. 1-4, 03.1988, S. 95-100.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Behrens P, Beuthien H, Eickhoff HP, Metz W, Niemann W. Structural investigations of the graphite intercalation compounds of the dichlorides of the IIB-elements (Zn, Cd, Hg). Synthetic metals. 1988 Mär;23(1-4):95-100. doi: 10.1016/0379-6779(88)90467-5
Behrens, P. ; Beuthien, H. ; Eickhoff, H. P. et al. / Structural investigations of the graphite intercalation compounds of the dichlorides of the IIB-elements (Zn, Cd, Hg). in: Synthetic metals. 1988 ; Jahrgang 23, Nr. 1-4. S. 95-100.
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AU - Behrens, P.

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AU - Eickhoff, H. P.

AU - Metz, W.

AU - Niemann, W.

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N2 - An account of our structural investigations of the Graphite Intercalation Compounds of ZnCl2, CdCl2 and HgCl2 is given. In the case of zinc chloride-graphite X-ray absorption spectra show that the Zn atoms in the intercalated layers are coordinated tetrahedrally. For cadmium chloride-graphite hk0 diffraction patterns clearly show that the sandwich structure of a layer as it is observed in pure CdCl2 is conserved. For mercuric chloride-graphite, monochromatic Laue photographs show an oblique in-plane unit cell of the intercalate.

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