Structural characteristics of the graphite intercalation compounds of metal chlorides

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Autoren

  • P. Behrens
  • W. Metz

Externe Organisationen

  • Universität Hamburg
Forschungs-netzwerk anzeigen

Details

OriginalspracheEnglisch
Seiten (von - bis)223-230
Seitenumfang8
FachzeitschriftSynthetic metals
Jahrgang34
Ausgabenummer1-3
PublikationsstatusVeröffentlicht - 1989
Extern publiziertJa

Abstract

An overview over the structural characteristics of the in-plane structures of metal chloride GICs+ is given. After a classification according to the topology of the structure of the intercalate layer (i. e. according to whether the guest-guest interactions are strong in zero, one or two dimensions) is proposed, several special questions are treated. These include the influence of the structure of the pristine chloride on the structure of the intercalated chloride, the variability of the in-plane arrangement as a function of the preparation conditions and of temperature of pressure and the structural effects of the charge, that is transferred from graphite to the intercalate during the intercalation reaction. A very interesting feature, the orientational locking of intercalate lattices which are incommensurate with respect to the graphite in-plane lattice, is addressed at the end of the paper.

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Structural characteristics of the graphite intercalation compounds of metal chlorides. / Behrens, P.; Metz, W.
in: Synthetic metals, Jahrgang 34, Nr. 1-3, 1989, S. 223-230.

Publikation: Beitrag in FachzeitschriftArtikelForschungPeer-Review

Behrens P, Metz W. Structural characteristics of the graphite intercalation compounds of metal chlorides. Synthetic metals. 1989;34(1-3):223-230. doi: 10.1016/0379-6779(89)90389-5
Behrens, P. ; Metz, W. / Structural characteristics of the graphite intercalation compounds of metal chlorides. in: Synthetic metals. 1989 ; Jahrgang 34, Nr. 1-3. S. 223-230.
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Download

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